• Title/Summary/Keyword: a diffusion model

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Study on Anomalous Scaling Exponents for Molecular Thin Film Growth Using Surface Lateral Diffusion Model

  • Gong, Hye-Jin;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제32권7호
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    • pp.2237-2242
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    • 2011
  • Anomalous scaling behaviors such as significantly large growth exponent (${\beta}$) and small reciprocal of dynamic exponent (1/z) values for many molecular crystalline thin films have been reported. In this study, the variation of scaling exponent values and consequent growth behaviors of molecular thin films were more quantitatively analysed using a (1+1)-dimensional surface lateral diffusion model. From these simulations, influence of step edge barriers and grain boundaries of molecular thin films on the various scaling exponent values were elucidated. The simulation results for the scaling exponents were also well consistent with the experimental data for previously reported molecular thin film systems.

CMC model에 의한 near-extinction methane/air turbulent jet diffusion flame의 수치적 모사 (Numerical Study on Methane/Air Turbulent Jet Diffusion Flames Near-Extinction Using Conditional Moment Closure Model)

  • 강승탁;김승현;허강일
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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    • pp.11-17
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    • 2002
  • The first-order conditional moment closure (CMC) model is applied to $CH_4$/Air turbulent jet diffusion flames(Sandia Flame D, E and F). The flow and mixing fields are calculated by fast chemistry assumption and a beta function pdf for mixture fraction. Reacting scalar fields are calculated by elliptic CMC formulation. The results for Flame D show reasonable agreement with the measured conditional mean temperature and mass fractions of major species, although with discrepancy on the fuel rich side. The discrepancy tends to increase as the level of local extinction increases. Second-order CMC may be needed for better prediction of these near-extinction flames.

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EFFECT OF HEAT ABSORPTION ON UNSTEADY MHD FLOW PAST AN OSCILLATING VERTICAL PLATE WITH VARIABLE WALL TEMPERATURE AND MASS DIFFUSION IN THE PRESENCE OF HALL CURRENT

  • RAJPUT, US;KANAUJIA, NEETU
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제22권4호
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    • pp.241-251
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    • 2018
  • The present study is carried out to examine the combined effect of heat absorption on flow model. The model consists of unsteady flow of a viscous, incompressible and electrically conducting fluid. The flow is along an impulsively started oscillating vertical plate with variable mass diffusion. The magnetic field is applied perpendicular to the plate. The fluid model under consideration has been solved by Laplace transform technique. The numerical data obtained is discussed with the help of graphs and table. The numerical values obtained for skin-friction have been tabulated. To shorten the lengthy equations in the solution some symbols have been assumed, which are mentioned in appendix. The appendix is included in the article as the last section of the manuscript.

나노결정 재료의 상혼합모델과 유한요소법을 결합한 멀티스케일 모델링 (Multi-Scale Modelling of a Phase Mixture Model and the Finite Element Method for Nanocrystalline Materials)

  • 윤승채;서민홍;김형섭
    • 소성∙가공
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    • 제13권2호
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    • pp.174-179
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    • 2004
  • The effect of grain refinement on the plastic deformation behaviour of nanocrystalline metallic materials is investigated. A phase mixture model in which a single phase material is considered as an effectively two-phase one is discussed. A distinctive feature of the model is that grain boundaries are treated as a separate phase deforming by a diffusion mechanism. For the grain interior phase two concurrent mechanisms are considered: dislocation glide and mass transfer by diffusion. The proposed constitutive model was implemented into a finite element code (DEFORM) using a semicoupled approach. The finite element method was applied to simulating room temperature tensile deformation of Cu down to the nanoscale grain size in order to investigate the pre- and post-necking behaviour.

기대주기 분석을 활용한 수요예측 연구: 하이브리드 자동차의 사례를 중심으로 (An Study of Demand Forecasting Methodology Based on Hype Cycle: The Case Study on Hybrid Cars)

  • 전승표
    • 기술혁신학회지
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    • 제14권spc호
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    • pp.1232-1255
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    • 2011
  • 본 연구에서는 신제품 확산 모델 활용에 있어서 보다 적은 노력이 필요하지만 객관적이고 신속한 활용을 가능하게 만들어줄 모형을 제안한다. 기대주기 모델과 소비자 수용 모델이라는 이론적 배경을 바탕으로, 서지분석학과 초기 시장의 규모만으로 최대 잠재 시장을 추정해냄으로써 대표적인 확산 모형인 배스 모형(Bass model)에 필요한 주요 모수를 제공하는 방법을 제시했다. 모형의 예측력을 하이브리드자동차 사례를 통해 분석한 결과, 모형의 예측결과는 여러 가지 객관적인 정보를 통해 추정한 잠재 시장과 유사한 규모를 성공적으로 예측해 내어 모형의 활용 가능성을 확인할 수 있었다. 제안된 모형이 제공한 최대 잠재 시장은 다른 성장곡선모형에도 바로 적용 가능하다는 점을 볼 때 제안된 모형은 서지분석학을 통한 기술 확산 예측과 유망기술 탐색에 새로운 방향을 제시했다고 할 것이다.

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Numerical study of ITZ contribution on diffusion of chloride and induced rebar corrosion: A discussion of three-dimensional multiscale approach

  • Tu, Xi;Pang, Cunjun;Zhou, Xuhong;Chen, Airong
    • Computers and Concrete
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    • 제23권1호
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    • pp.69-80
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    • 2019
  • Modeling approach for mesoscopic model of concrete depicting mass transportation and physicochemical reaction is important since there is growing demand for accuracy and computational efficiency of numerical simulation. Mesoscopic numerical simulation considering binder, aggregate and Interfacial Transition Zone (ITZ) generally produces huge number of DOFs, which is inapplicable for full structure. In this paper, a three-dimensional multiscale approach describing three-phase structure of concrete was discussed numerically. An effective approach generating random aggregate in polygon based on checking centroid distance was introduced. Moreover, ITZ elements were built by parallel expanding the surface of aggregates on inner side. By combining mesoscopic model including full-graded aggregate and macroscopic model, cases related to diffusivity and thickness of ITZ, volume fraction and grade of aggregate were studied regarding the consideration of multiscale compensation. Results clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of, rebar diameter, concrete cover and exposure period.

Polyamide 역삼투막의 투과성능과 막 이동 모델의 해석 (Interpretation of Permeation Characteristics and Membrane Transport Models Through Polyamide Reverse Osmosis Membrane)

  • 김노원;김영길;이용택
    • 멤브레인
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    • 제14권1호
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    • pp.75-84
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    • 2004
  • 폴리아미드계 역삼투 분리막의 투과성능을 비교하기 위하여 NaCl과 NaOCl을 함유하는 혼합용액을 공급수로 사용하여 연속운전과 단속운전 하에서 실험하여 보았다. 이 결과를 가지고 막 이동 모델의 선택적 적용이 가능함을 제시하고자 하였으며 투과 성능 분석 결과, 용액 확산 모델과 선흡착-모세관이동 모델이 운전 모드에 따라 상대적으로 유용함을 볼수 있었다. 연속 운전에서는 선흡착-모세관이동 모델을, 단속 운전에서는 용액 확산 모델을 따름을 알 수 있었다 NaOCl에 의한 표면 변화를 SEM 사진을 통하여 확인 할 수 있었다. 연속운전 후의 막은 염소 투과 결과 표면에서 부분적인 ridge and valley 구조가 나타났으며 단속 운전 후의 막은 표면 전반에서 변성이 일어난 것을 볼 수 있었다.

Organisational Innovation Diffusion: the Case of Saudi Arabian Project-based Organisations

  • Alghadeer, Abdulaziz;Mohamed, Sherif
    • 국제학술발표논문집
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    • The 6th International Conference on Construction Engineering and Project Management
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    • pp.491-495
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    • 2015
  • This paper aims to provide some unique insights into the verification of organisational innovation diffusion through empirically identifying the major factors determining the level of organisational innovation diffusion. The paper presents a two-stage sequential mixed method analysis: structural equation modelling analysis and regression analysis. A questionnaire survey was administrated to a sample of 223 organisations operating in Saudi Arabia. The results suggest that participative culture and, technology availability and implementation would intensify organisational climate for innovation. The results revealed compelling evidence in support of the moderating role of technology on the relationship between country socio-culture and organisational climate for innovation. Equally important, organisational innovation characteristics could play a crucial role in the intention to adopt a particular innovation. Specifically, maintaining Saudi Arabian top management's status quo is an obstacle to organisational innovation diffusion. This paper expands and improves upon the current understanding of how organisational innovation diffusion, in particular the Project Management Office (PMO), can be accelerated. By focusing on the critical factors within the conceptual model, the paper depicts the crucial role of certain factors that could leverage improved organisational innovation diffusion outcomes.

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다변량 비대칭 라플라스 점프확산 모형의 베이지안 추론 (Bayesian inference on multivariate asymmetric jump-diffusion models)

  • 이영은;박태영
    • 응용통계연구
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    • 제29권1호
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    • pp.99-112
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    • 2016
  • 비대칭 점프확산 모형은 자산 가격의 비대칭적 변동을 효과적으로 설명하는 모형으로 활용되어 왔다. 그러나 다변량 모형으로 확장한 다변량 비대칭 라플라스 점프확산 모형은 가능도함수가 닫힌 해로 존재하지 않아 모형의 추론에 한계가 존재하였다. 본 논문에서는 이러한 한계점을 극복하기 위해 자료 확장 기법을 제안하고 새로운 베이지안 추론 방법을 개발한다. 본 논문에서 제안된 모형은 단일 점프와 공통 점프 뿐만 아니라 모든 가능한 조합으로 발생하는 점프를 반영한 확장된 다변량 비대칭 라플라스 점프확산 모형이다. 이러한 모형을 분석하기 위해 붕괴된 깁스 샘플러를 고안한 베이지안 방법을 개발하였다. 본 논문에서 제안된 모형과 방법을 모의실험 자료 및 2005년 1월 3일부터 2015년 9월 30일까지 관찰된 일별 KOSPI, S&P500, 그리고 Nikkei225에 적용하여 효율성을 검증하였다.

고온 환경하 응력 확산에 의한 금속시편내 격자결함 재분포 (Redistribution of Vacancy Concentration in Metal Specimens under Stress-induced Diffusion at a High Temperature)

  • 윤선진;조용무
    • Design & Manufacturing
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    • 제12권1호
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    • pp.1-6
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    • 2018
  • In this study, we calculated the redistribution of vacancy concentration in metal specimens induced by stress-induced diffusion at a high temperature. To deduce the governing equation, we associated the unit volume change equation of strains with a differential equation of vacancy concentration as a function of stress using the stress-strain relationship. In this governing equation, we considered stress as the only chemical potential parameter to stay in the scope of this study, which provided the vacancy concentration equation as of stress gradient in metals. The equation was then mathematically delineated to derive a analytical solution for a transient, one-dimensional diffusion case. With the help of Korhonen's approximation and the boundary conditions, we successfully deduced a general solution from the governing equation. To visualize the feasibility of our solutions, we applied the solution to two different stress-induced cases - a rod with fixed concentrated stresses at both ends and a rod with varying concentrated stresses at both ends. Although it is necessary to legitimatized the model in the future for improvement, our results showed that the model can be used to interpret the location of structural defects, the formation of vacancy, and furthermore the high temperature behavior of metals.