• Title/Summary/Keyword: ZnBO

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Sorption of Heavy Metals from the Wastewater by the Artificial Zeolite (인공 제올라이트에 의한 폐수중 중금속 흡착)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Lee, Sang-Bok;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.61-66
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    • 1998
  • An artificial zeolite was synthesized from bituminous coal fly ash by thermo-alkali treatment, $100{\pm}3^{\circ}C$ and 3.5 N NaOH solution for 24 hours, to develope new useful material in waste water treatment system. The artificial zeolite had much higher cation exchange capacity, $299cmol^+\;kg^{-1}$ and lower concentration of extractable heavy metals than bituminous coal fly ash. The higher the temperature and the longer the shaking time, the more Zn, Cu, Cd and Pb were sorbed chemically by the artificial zeolite. Shaking artificial zeolite and wastewater at $35^{\circ}C$ for 9 hours, the amount of sorbed heavy metals were $123.5g\;kg^{-1}$ for Zn, $164.7g\;kg^{-1}$ for Cu, $184.4g\;kg^{-1}$ for Cd and $350.6g\;kg^{-1}$ for Pb, respectively.

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A study on the zinc oxide crystalline powder synthesized by zinc chloride solution and sodium-based alkali precipitants (염화아연 수용액과 나트륨계 알칼리 침전제 종류에 따라 합성한 산화아연 결정 분말에 대한 연구)

  • Dae-Weon Kim;Dae-Hwan Jang;Bo-Ram Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.15-21
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    • 2023
  • To prepare zinc oxide powder, three types of sodium-based alkali precipitants such as NaOH, Na2CO3, NaOH/NaHCO3 were compared to the differences in the manufacturing process of zinc oxide powder from zinc precipitate products like intermediates with the consideration of thermodynamic reaction. The prepared zinc precipitate products by the reaction with the sodium-based alkali precipitant were confirmed to respectively hydroxy zinc chloride (Zn5(OH)8Cl2·H2O) and zinc carbonate hydroxide (Zn5(OH)6(CO3)2·H2O) from XRD analysis. Zinc oxide particles were compared in heat treatment at 800℃ according to sodium-based alkali precipitants. The mixed NaOH and NaHCO3 of alkali precipitant reaction was contributed to synthesize the more uniform zinc oxide particles.

Nutritional Assessment and Mineral Content of Wild and Cultured Catfish Silurus asotus (자연산 및 양식산 메기의 미네랄 함량 및 영양평가)

  • GYE, Hyeon-Jin;SHIM, Kil-Bo;LIM, Chi-Won;SONG, Mi-Young;KIM, Dae-Hee;KIM, Bo-Kyoung;CHO, Young-Je
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.5
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    • pp.1364-1368
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    • 2015
  • This study was performed to evaluate mineral contents of catfish Silurus asotus. As a result of mineral content, the mean content of the macro mineral was (in descending order): K (310.36-412.66 mg/100 g), P (186.42-223.02 mg/100 g), Na (35.32-57.87 mg/100 g), Mg (22.88-31.87 mg/100 g), Ca (9.05-13.07 mg/100 g). In comparison, the mean content of the micro mineral was (in descending order): Fe (0.26-0.95 mg/100 g), Zn (0.26-1.02 mg/100 g), Cu (ND-0.08 mg/100 g), Mn (0.01-0.03 mg/100 g). A proportion of mineral intakes with the dietary reference intakes for Koreans (KDRIs) set by the Korean Nutrition Society. Nutrient uptake proportion of mineral intakes was (in descending order): P (62.16%), K (20.71%), Mg (16.82%), Fe (13.02%), Zn (11.38%) Cu (10.94%), Na (6.59%), Ca (3.09%), Mn (0.96%). The mineral content was compared with the major protein food sources according to the Korea Health Statistics (2013) such as polished rice, pork, chicken, beef, eggs and milk. The calcium content contains; lower level of milk and eggs, chicken whereas higher levels of rice, pork and beef. Catfish has less iron content than major protein food source. Phosphorus and potassium contain higher level of major protein food sources.

Investigation of photon, neutron and proton shielding features of H3BO3-ZnO-Na2O-BaO glass system

  • Mhareb, M.H.A.;Alajerami, Y.S.M.;Dwaikat, Nidal;Al-Buriahi, M.S.;Alqahtani, Muna;Alshahri, Fatimh;Saleh, Noha;Alonizan, N.;Saleh, M.A.;Sayyed, M.I.
    • Nuclear Engineering and Technology
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    • v.53 no.3
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    • pp.949-959
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    • 2021
  • The current study aims to explore the shielding properties of multi-component borate-based glass series. Seven glass-samples with composition of (80-y)H3BO3-10ZnO-10Na2O-yBaO where (y = 0, 5, 10, 15, 20, 25 and 30 mol.%) were synthesized by melt-quench method. Various shielding features for photons, neutrons, and protons were determined for all prepared samples. XCOM, Phy-X program, and SRIM code were performed to determine and explain several shielding properties such as equivalent atomic number, exposure build-up factor, specific gamma-ray constants, effective removal cross-section (ΣR), neutron scattering and absorption, Mass Stopping Power (MSP) and projected range. The energy ranges for photons and protons were 0.015-15 MeV and 0.01-10 MeV, respectively. The mass attenuation coefficient (μ/ρ) was also determined experimentally by utilizing two radioactive sources (166Ho and 137Cs). Consistent results were obtained between experimental and XCOM values in determining μ/ρ of the new glasses. The addition of BaO to the glass matrix led to enhance the μ/ρ and specific gamma-ray constants of glasses. Whereas the remarkable reductions in ΣR, MSP, and projected range values were reported with increasing BaO concentrations. The acquired results nominate the use of these glasses in different radiation shielding purposes.

Temperature dependency of the ZnO nanostructures grown by metalorganic chemical vapor deposition (MOCVD법으로 성장한 ZnO 나노구조의 온도 의존성)

  • Choi, Mi-Kyung;Kim, Dong-Chan;Kong, Bo-Hyun;Kim, Young-Yi;Ahn, Chel-Hyun;Han, Won-Suk;Mohanta, Sanjay Kumar;Cho, Hyung-Koun;Lee, Ju-Young;Lee, Jong-Hoon;Kim, Hong-Seung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.20-20
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    • 2008
  • 최근 LEDs가 동일 효율의 전구에 비해 에너지 절감 효과 크며 신뢰성이 뛰어나다기 때문에 기존 광원을 빠르게 대체해 나가고 있다. 특히 자외선 파장을 가지는 LEDs는 발열이 낮아 냉각장치가 필요 없으며, 수명이 길어 기존 UV lamp에 비해 많은 장점을 가지고 있기 때문에 많은 관심을 밭고 있다. 그럼에도 불구하고 자외선 LEDs는 제조 단가가 높고 power가 낮아 소요량이 많은 등 아직 해결해야 할 부분이 많기 때문에 이를 해결하기 위해 여러가지 재료와 다양한 구조가 고려되고 있다. 그 중 ZnO는 II-VI족 화합물 반도체로써 UV영역의 넓은 밴드갭(3.37eV)을 가지는 투명한 재료이다. 특히 ZnO는 60meV의 큰 엑시톤 결합에너지를 가지며, 가시광 영역에서 높은 투과율을 가지고, 상온에서 물리적, 화학적으로 안정하기 때문에 UV sensor, UV laser, UV converter, UV LEDs 등 광소자 분야에서 연구가 활발히 진행되고 있다. ZnO가 광소자의 발광재료로써 높은 효율을 얻기 위해서는 결정성을 높여 내부 결함을 감소시키며, 발광 면적을 높일 수 있는 구조가 요구된다. 특히 MOCVD 법으로 성장한 나노막대는 에피성장되어 높은 결정성을 기대할 수 있으며, 성장 조건을 조절함으로써 나노막대의 aspect ratio와 밀도 제어할 수 있기 때문에 표면적을 효과적으로 넓혀 높은 발광효율을 얻을 수 있다. 본 실험에서는 MOCVD 법으로 실리콘과 사파이어 기판 위에 다양한 성장 온도를 가진 나노구조를 성장 시키고 온도에 따른 형상 변화와 특성을 평가하였다. ZnO 의 성장온도가 약 $360^{\circ}C$ 일 때, 밀도가 조밀하고 기판에 수직 배열한 균일한 나노막대가 성장되었으며 우수한 결정성, 광학적 특성이 나타남을 SEM, TEM, PL, XRD를 사용하여 확인하였다.

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Protective Effects of Antoxidant Enzymes of Candida albicans against Oxidative Killing by Macrophages

  • Kim, Hye-Jin;Na, Byoung-Kuk;Kim, Moon-Bo;Park, Duk-Young;Song, Chul-Yong
    • Journal of Microbiology
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    • v.37 no.2
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    • pp.117-122
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    • 1999
  • Protective roles of antioxidant enzymes, copper-zinc superoxide dismutase (CuZnSOD), manganese superoxide dismutase (MnSOD), and catalase of Candida albicans against exogenous reactive oxygens and oxidative killing by macrophages were investigated. The initial growth of C. albicans was inhibited by reactive, oxygen-producing chemicals such as hydrogen peroxide, pyrogallol, and paraquat, but it was restored as the production of antioxidant enzymes were increased. The growth inhibition of C. albicans by reactive, oxygen-producing chemicals was reduced by treating the purified candidal SOD and catalase. Also, in the presence of SOD and catalase, the oxidative killing of C. albicans by macrophages was significantly inhibited. These results suggest that antioxidant enzymes, CuZnSOD, MnSOD, and catalase of C. albicans may play important roles in the protection of C. albicans not only from exogenous oxidative stress but also from oxidative killing by macrophages.

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Process and Performance Analysis of a-Si:H/c-Si Hetero-junction Solar Sells Prepared by Low Temperature Processes (저온 공정에 의한 a-Si:H/c-Si 이종접합 태양전지 제조 및 동작특성 분석)

  • Lim, Chung-Hyun;Lee, Jeong-Chul;Jeon, Sang-Won;Kim, Sang-Kyun;Kim, Seok-Ki;Kim, Dong-Seop;Yang-Sumi;Kang-Hee-Bok;Lee, Bo-young;Song-Jinsoo;Yoon-Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.196-200
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    • 2005
  • In this work, we investigated simple Aㅣ/TCO/a-Si:H(n)/c-Si(p)/Al hetero-junction solar cells prepared by low temperature processes, unlike conventional thermal diffused c-Si solar cells. a-Si:H/c-Si hetero-junction solar cells are processed by low temperature deposition of n-type hydrogenated amorphous silicon (a-Si:H) films by plasma-enhanced chemical vapor deposition on textured and flat p-type silicon substrate. A detailed investigation was carried out to acquire optimization and compatibility of amorphous layer, TCO (ZnO:Al) layer depositions by changing the plasma process parameters. As front TCO and back contact, ZnO:Al and AI were deposited by rf magnetron sputtering and e-beam evaporation, respectively. The photovoltaic conversion efficiency under AMI.5 and the quantum efficiency on $1cm^2$ sample have been reported. An efficiency of $12.5\%$ is achieved on hetero-structure solar cells based on p-type crystalline silicon.

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Correlation Analysis of General Parameters and Metals in the Lake Sediments of Geum River Basin

  • Lee, Jun-Bae;Cho, Yoon-Hae;Huh, In-Ae;Khan, Jong-Beom;Oh, Da-Yeon;Yang, Yoon-Mo;Gil, Gi-Beom;Lee, Soo-Hyung;Cheon, Se-Yeok;Lee, Bo-Mi
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.684-696
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    • 2017
  • An investigation of grain size, organic compounds and metal distribution in lakes from Geum river basin (Republic of Korea) was conducted in two years (2014 and 2015). The samples of sediment were collected from the 3 lakes (12 sites). The samples were analyzed the concentration of metals (Pb, Zn, Cu, Cr, Ni, As, Cd, Hg, Al, and Li) and general indices including grain size. Spearman correlation coefficients were determined using general indices and metal concentrations respectively. The organic qualities of sediments were improved in 2015 compared with 2014. The concentrations of metals were lower than Sediment Criteria of Lakes in Korea. The significant Spearman correlation coefficients were presented only sand-clay, clay-water content, COD-TOC, Cu-Ni, Cd-Li, Zn-Li, and Cr-Ni of general and metal parameters in 2014, 2015 and both of two years.

Image Tracking Interference Minimize of Electro Optical Tracking System by MgF2 Nano Structure Antireflective Coating Films (MgF2 나노구조 반사방지막을 통한 함정용 전자광학추적장비 영상추적간섭 최소화)

  • Shim, Bo-Hyun;Jo, Hee-Jin
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.5
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    • pp.206-213
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    • 2015
  • An omni-directional, graded-index and textured ZnO nanorods with $MgF_2$ anti-reflective(AR) coating films for the electro optical tracking system(EOTS) by e-beam evaporation method are presented. we achieved that the graded index structure can minimize image tracking interference of EOTS which is comparable to a general AR coating films. Optimized ZnO nanorods with $MgF_2$ AR coating films lead to decreasing Fresnel reflection by gradient refractive index. According to our experiment results, ZnO nanorods with $MgF_2$ AR coating films can be used for various electro optical system to improve the optical performance.

Study on operating characteristics of Ferrite cores for Flat TR in high frequency (Flat TR용 페라이트 코아의 고주파 동작 특성)

  • Han, Se-Won;Cho, Han-Goo;Ryu, Dong-Uk;Choi, Kwang-Bo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1168-1171
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    • 2003
  • In contrast to a conventional transformer, the flat transformer is made using a number of small ferrite cores. Two cores for transformer and one core for inductor, which composed one module. Many modules can be connected together to form a flat matrix transformer. This structural arrangement eliminates the single hot spot problem in conventional transformers and permits high current density pertains at high frequency. In this study, the ferrite magnetic cores of Mn-Zn system for the Flat transformer were manufactured and the electrical and magnetic characteristics of its tested. The power loss of sample FO2(Mn-Zn ferrite) sintered at $1350^{\circ}C$ was $350kW/m^3$ in test conditions of 250kHz, 200mT and $100^{\circ}C$, which showed the good power loss property in high frequency. The power loss of FO2 samples has been studied as a function of magnetic flux density and frequency. Steinmetz exponent was 2.82 at 250kHz and 2.73 at 500kHz. These results illustrated the switching of power loss mechanism in ferrite core from hysteresis losses to eddy current losses or others.

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