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Effects of Aectic Acid-Water Solvents on the Organic Acid pulping of Wood (아세트산(酸)-물 용매계(溶媒系)에 의한 목재(木材)의 유기산(有機酸) 증해효과(蒸解效果))

  • Lee, Sun-Ho;Jo, Byoung-Muk
    • Journal of Forest and Environmental Science
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    • v.9 no.1
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    • pp.67-80
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    • 1993
  • There are a lot of serious problums associated with conventional pulping processes, such as kraft and sulfite. In order to tackle these difficulties, organic acid pulping of Populus tomentiglandulosa T. Lee and Pinus densiflora S. et Z. have been investigated as on alternative method. The acetic acid cooking of Populus tomentiglandulosa T. Lee achieved good delignification with pulp yields of 55-65% under almost all cooking conditions. In the acetic acid cooking of Pinus densiflora S. et Z., it was not cooked at a low temperature. The strength properties of the acetic acid pulps from Pinus tomentiglandulosa T. Lee showed the optimum with 95% acetic acid concentration at $185^{\circ}C$ maximum cooking temperature for 0.5hr cooking time. The strength properties of the acetic acid pulps from Pinus densiflora S. et Z. displayed excellent tear strength in comparison with those of the other softwoods. In the process of acetic acid cooking, glucose has been removed a little, but other sugars have been eliminated. The elemental compositions and $C_9$ formulas of acetosolv lignins from Populus tomentiglandulosa T. Lee were 63.88% carbon, 5.45% hydrogen and 30.67% oxygen and $C_9H_{9.15}O_{3.24}$ The elemental compositions and $C_9$ formulas of acetosolv lignins from Pinus densiflora S. et Z. were 61.85% carbon, 6.14% hydrogen and 32.01% oxygen and $C_9H_{9.15}O_{3.50}$ The Wt. av. MWT's of the acetosolv lignins from Pinus tomentiglandulosa T. Lee and Pinus densiflora S. et Z. were 731 and 725.

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Photodegradation of some Organophosphorous Pesticides (일부 유기인계 농약의 광분해성)

  • 민경진;차춘근
    • Journal of Food Hygiene and Safety
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    • v.14 no.4
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    • pp.339-345
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    • 1999
  • The present study was performed to investigate photodegradation rate constants and degradation products of dichlorvos and methidathion by the USEPA method. The two pesticides were very stable in sunlight for 16 days from September 2 to 18, 1998 and humic acid had no sensitizing effect on the photolysis of each pesticide in sunlight. The photolysis rate was fast-est for methidathion, followed by dichlorvos in the presence of UV irradiation. Photodegradation rate constant and half-life of dichlorvos were 0.0208 and 33.3 min, respectively. Photodegradation rate constant and half-life of methidathion were 0.6789 and 1.0min, respectively. The two pesticides were degraded completely in the presence of UV irradiation and UV irradiation with TiO$_2$in about 3 hours. Therefore, it is suggested that UV treatment will be effective for the degradation of pesticides in the process of drinking water purification. In case of dichlorvos and methidathion, UV irradiation with TiO$_2$was more effective for degradation than W irradiation. In order to identify photolysis products, the extracts of degradation products were analyzed by GC/ MS. The mass spectrum of photolysis products of dichlorvos was at m/z 153, those of the photolysis of methidathion were at m/z 198 and 214, respectively. Photolysis products of dichlorvos was Ο, Ο-dimethyl phosphate(DMP), those of methidathion were Ο, Ο-dimethyl phosphorothioate(DMTP) and Ο, Ο-dimethyl phosphorodithioate (DMDTP).

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Effect of Temperature, pH and Sugars on Kinetic Property of Maillard reaction (당의 종류, pH 및 온도가 마이야르 반응속도에 미치는 영향)

  • Chun, Young-Hye;Kim, Chong-Kun;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.55-60
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    • 1986
  • The effects of temperature (70-$100^{\circ}C$), pH (3-8) and various sugars were investigated on the reaction rate, activation energy and z-value of Maillard reaction of 0.8m sugar and 0.8m glycine mixture. The sugars compared were glucose, fructose, lactose and sucrose, and the reaction was evaluated by absorbances at 278nm for pyrazine compounds and at 400nm for brown pigments. Fructose-glycine mixture showed a faster initial reaction rate than that of glucose-glycine, which was reversed by the order of glucose > fructose > lactose > sucrose after 10 hrs of reaction at pH 5.8 and $100^{\circ}C$. Generally, higher activation energy was required for forming pyrazines than that of brown pigment development. The highest z-value was obtained for lactose-glycine mixture, followed by glucose or fructose-glycine which had almost same z-value. The reaction rate was little affected by the pH change in the range of 4-6, while pH < 3 and pH 6-8 caused a significant increase in the rates.

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THE MICROHARDNESS AND THE DEGREE OF CONVERSION OF LIGHT CURED COMPOSITE RESIN AND DUAL CURED RESIN CEMENTS UNDER PORCELAIN INLAY (도재인레이 하방에서 광중합형 복합레진과 이중중합형 복합레진시멘트의 미세경도와 중합률에 관한 연구)

  • Kim, Seung-Soo;Cho, Sung-Sik;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.25 no.1
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    • pp.17-40
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    • 2000
  • Resin cements are used for cementing indirect esthetic restorations such as resin or porcelain inlays. Because of its limitations in curing of purely light cured resin cements due to attenuation of the curing light by intervening materials, dual cured resin cements are recommended for cementing restorations. The physical properties of resin cements are greatly influenced by the extent to which a resin cures and the degree of cure is an important factor in the success of the inlay. The purpose of this study was to evaluate the influence of porcelain thickness and exposure time on the polymerization of resin cements by measuring the microhardness and the degree of conversion, to investigate the nature of the correlation between two methods mentioned above, and to determine the exposure time needed to harden resin cements through various thickness of porcelain. The degree of resin cure was evaluated by the measurements of microhardness [Vickers Hardness Number(VHN)] and degree of conversion(DC), as determined by Fourier Transform Infrared Spectroscopy(FTIR) on one light cured composite resin [Z-100(Z)] and three dual cured resin cements [Duo cement(D), 3M Resin cement(R), and Dual cement(DA)] which were cured under porcelain discs thickness of 0mm, 1mm, 2mm, 3mm with light exposure time of 40sec, 80sec, 120sec, and regression analysis was performed to determine the correlation between VHN and DC. In addition, to determine the exposure time needed to harden resin cements under various thickness of porcelain discs, the changes of the intensity of light attenuated by 1mm, 2mm, and 3mm thickness of porcelain discs were measured using the curing radiometer. The results were obtained as follows ; 1. The values of microhardness and the degree of conversion of resin cements without intervening porcelain discs were 31~109VHN and 51~63%, respectively. In the microhardness Z was the highest, followed by R, D, DA. In the degree of conversion, D and DA was significantly greater than Z and R(p<0.05). 2. The microhardness and the degree of conversion of the resin cements decreased with increasing thickness of porcelain discs, and increased with increasing exposure time, D and R showed great variation with inlay thickness and exposure time, whereas, DA showed a little variation. 3. The intensity of light through 1mm, 2mm, and 3mm porcelain inlays decreased by 0.43, 0.25, and 0.14 times compared to direct illumination, and the respective needed exposure times are 53 sec, 70 sec, and 93 sec. In D and R, 40 sec of light irradiation through 2mm porcelain disc and 80 sec of light irradiation through 3mm porcelain disc were not enough to complete curing. 4. The microhardness and the degree of conversion of the resin cements showed a positive correlationship(R=0.791~0.965) in the order of R, D, Z, DA. As the thickness of porcelain discs increased, the decreasing pattern of microhardness was different from that of the degree of conversion, however.

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A Study on the Development of Computer Aided Design System for Fixed Offshore Structures (고정식 해양구조물의 전산기 지원 설계시스템 개발에 관한 연구)

  • Sin, Hyeon-Gyeong;Park, Gyu-Won
    • Journal of Ocean Engineering and Technology
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    • v.9 no.2
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    • pp.83-88
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    • 1995
  • In this paper, the solid modeller suitable for PC was developed for Top-down 3-D representation and analysis of fixed offshore structures. Also solid modelling and hidden line removal were conducted in order to visualize the offshore structures based on the scan line z-buffer algorithm.

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A Study on the Endpoint Detection Algorithm (끝점 검출 알고리즘에 관한 연구)

  • 양진우
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1984.12a
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    • pp.66-69
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    • 1984
  • This paper is a study on the Endpoint Detection for Korean Speech Recognition. In speech signal process, analysis parameter was classification from Zero Crossing Rate(Z.C.R), Log Energy(L.E), Energy in the predictive error(Ep) and fundamental Korean Speech digits, /영/-/구/ are selected as date for the Recognition of Speech. The main goal of this paper is to develop techniques and system for Speech input ot machine. In order to detect the Endpoint, this paper makes choice of Log Energy(L.E) from various parameters analysis, and the Log Energy is very effective parameter in classifying speech and nonspeech segments. The error rate of 1.43% result from the analysis.

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BRAUER GROUP OVER A KRULL DOMAIN

  • Lee, Heisook
    • Bulletin of the Korean Mathematical Society
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    • v.26 no.2
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    • pp.135-137
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    • 1989
  • Let R be a Krull domain with field of fractions K. By Br(R) we denote the Brauer group of R. Studying the Kernel of the homomorphism Br(R).rarw.Br(K), Orzech defined Brauer groups Br(M) for different categories M of R-modules [4]. In this paper we show that an algebra A in Br(D) is a maximal order in A K and that the map Br(D).rarw. Br(K) is one to one. We note here few conventions. All rings are Krull domains and all modules will be unitary. By Z we donote the set of height one prime ideals of a Krull domain.

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ON ZEROS OF THE BOUBAKER POLYNOMIALS

  • Kim, Seon-Hong
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.2
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    • pp.547-553
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    • 2014
  • The Boubaker polynomials arose from the discretization of the equations of heat transfer in pyrolysis starting from an assumed solution of the form $$\frac{1}{N}e^{\frac{A}{H/z+1}}\sum_{k=0}^{\infty}{\xi}_kJ_k(t),$$ where $J_k$ is the k-th order Bessel function of the first kind. In this paper, we investigate the distribution of zeros of the Boubaker polynomials.

Lp SOLUTIONS FOR GENERAL TIME INTERVAL MULTIDIMENSIONAL BSDES WITH WEAK MONOTONICITY AND GENERAL GROWTH GENERATORS

  • Dong, Yongpeng;Fan, Shengjun
    • Communications of the Korean Mathematical Society
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    • v.33 no.3
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    • pp.985-999
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    • 2018
  • This paper is devoted to the existence and uniqueness of $L^p$ (p > 1) solutions for general time interval multidimensional backward stochastic differential equations (BSDEs for short), where the generator g satisfies a ($p{\wedge}2$)-order weak monotonicity condition in y and a Lipschitz continuity condition in z, both non-uniformly in t. The corresponding stability theorem and comparison theorem are also proved.

A study on the application of finite element method to analysis of the magnetic flux distribution characteristics of the tubular motor (Tubular motor의 자속분포 특성 해석을 위한 유한요소법 적용연구)

  • 임달호;임태빈
    • 전기의세계
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    • v.30 no.12
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    • pp.811-816
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    • 1981
  • In this paper, the finite element method is applied to find the flux distribution of the magnetic field in the end region of the tubular motor. In order to analyze two-dimensional flux distribution, the r-z domain to be analyzed is subdivided into 56 nodes, 84 elements. In the case of wt=O and .pi./2, the flux distribution is shifted to the edge with frequency (w) and time (t) increase in the edge and the air gap. It is proved that this study does fit the actual phenomena.

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