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Flux Melting Route to 2-and 3-dimensional Fibrous Potassium Titanates, K$_2Ti_{2n}O_{4n+1}$ (n = 2 and 3) (Flux 용융법에 의한 2차원 및 3 차원 구조의 티탄산칼륨 섬유의 합성)

  • Jin-Ho Choy;Yang Su Han;Seung Wan Song
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.765-772
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    • 1993
  • Two-dimensional potassium tetratitanate ($K_2Ti_4O_9$) and three-dimensional potassium hexatitanate ($K_2Ti_6O_{13}$) fibers have been prepared by the combined method consisting of the flux melting (1150$^{\circ}C$)-slow cooling (cooling rate = 5$^{\circ}C$/h) process from the starting raw materials of $K_2CO_3$, and $TiO_2$ with the flux of $K_2MoO_4$. It was found that the fiber growth reaction is strongly dependent upon the mole ratio of flux (F) to raw material (R), which is 7 : 3 (F : R) as for the optimum growth condition. Relatively long fibers (average length ${\thickapprox}$ 4 mm) with a mixture of $K_2Ti_4O_9$ (major) and $K_2Ti_6O_{13}$ (minor) could be obtained when the reaction was carried out for the $K_2MoO_4-$K_2O{\cdot}4TiO_2$ (F : R = 7 : 3) system, but for the $K_2$MoO_4$-$K_2O{\cdot}6TiO_2$ (F : R = 7: 3) one, only the short fibers with ${\thickapprox}$ 2 mm long could be grown as the mixed phase of $K_2Ti_6O_{13}$ and $K_2Ti_4O_9$.

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Cytogenetic Analysis of Seven Angelica Species (Angelica속 식물 7종의 세포유전학적 분석)

  • Choi, Hae-Woon;Koo, Dal-Hoe;Lee, Woo-Kyu;Kim, Soo-Young;Sung, Jung-Sook;Seong, Nak-Sul;Suh, Young-Bae;Bang, Jae-Wook
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.3
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    • pp.118-121
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    • 2005
  • Karyotypes were established in seven Angelica species cultivated in Korea. The somatic chromosome numbers were 2n = 2x = 22 with the basic number of x = 11 in all Angelica plants examined. Their metaphase chromosomes ranged from 3.56 ${\mu}M$. to 8.91 x. in length. Distinctive Karyotypes were found in two species, A. tenuissima with all metacentries, K(2n) = 2x = 22m, and A. genuflexa with all subtelocentrics, K(2n) = 2x = 22st. Karyotype formulas of A. gigas, A. acutiloha, A. sinensis, A. decursiva and A. dahurica were K(2n) = 2x = 20m + 2sm, K(2n) = 2x = 12m + 10sm, K(2n) = 2x = 16m + 6sm, K(2n) = 2x = 18m + 4sm and K(2n) = 2x = 10m + 10sm + 2st, respectively. Cytological data showed that chromosomal polymorphisms within species were observed in Angelica plants compare to other regions.

Crystal Structures of Fully Dehydrated $Ca^{2+}$-Exchanged Zeolite X, $Ca_{46}-X$, and $Ca^{2+}$ and $K^+$-Exchanged Zeolite X, $Ca_{32}K_{28}-X$ ($Ca^{2+}$ 이온으로 완전히 치환된 제올라이트 X, $Ca_{46}-X$$Ca^{2+}$ 이온과 $K^+$ 이온으로 치환된 제올라이트 X, $Ca_{32}K_{28}-X$를 완전히 진공 탈수한 결정구조)

  • Jang, Se Bok;Song, Seong Hwan;Kim, Yang
    • Journal of the Korean Chemical Society
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    • v.39 no.1
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    • pp.7-13
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    • 1995
  • The crystal sructures of $X(Ca_{46}Al_{92}Si_{100}O_{384})$ and $Ca_{32}K_{28}-X(Ca_{32}K_{28}Al_{92}Si_{100}O_{384})$ dehydrated at $360^{\circ}C$ and $2{\times}10^{-6}$ Torr have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at $21(1)^{\circ}C.$ Their structures were refined to the final error indices, R_1=0.096,\;and\;R_2=0.068$ with 166 reflections, and R_1=0.078\;and\;R_2=0.056$ with 130 reflections, respectively, for which I > $3\sigma(I).$ In dehydrated $Ca_{48}-X,\;Ca^{2+}$ ions are located at two different sites opf high occupancies. Sixteen $Ca^{2+}$ ions are located at site I, the centers of the double six rings $(Ca(1)-O(3)=2.51(2)\AA$ and thirty $Ca^{2+}$ ions are located at site II, the six-membered ring faces of sodalite units in the supercage. Latter $Ca^{2+}$ ions are recessed $0.44\AA$ into the supercage from the three O(2) oxygen plane (Ca(2)-O(2)= $2.24(2)\AA$ and $O(2)-Ca(2)-O(2)=119(l)^{\circ}).$ In the structure of $Ca_{32}K_{28}-X$, all $Ca^{2+}$ ions and $K^+$ ions are located at the four different crystallographic sites: 16 $Ca^{2+}$ ions are located in the centers of the double six rings, another sixteen $Ca^{2+}$ ions and sixteen $K^+$ ions are located at the site II in the supercage. These $Ca^{2+}$ ions adn $K^+$ ions are recessed $0.56\AA$ and $1.54\AA$, respectively, into the supercage from their three O(2) oxygen planes $(Ca(2)-O(2)=2.29(2)\AA$, $O(2)-Ca(2)-O(2)=119(1)^{\circ}$, $K(1)-O(2)=2.59(2)\AA$, and $O(2)-K(1)-O(2)=99.2(8)^{\circ}).$ Twelve $K^+$ ions lie at the site III, twofold axis of edge of the four-membered ring ladders inside the supercage $(K(2)-O(4)=3.11(6)\AA$ and $O(1)-K(2)-O(1)=128(2)^{\circ}).$

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The Synthesis of Potassium Hexatitanate Whisker by the Flux Process (융제법에 의한 육티탄산칼륨 Whisker의 합성)

  • Lee, Chul-Tae;Kim, Sung-Weon;Lee, Jin-Sik;Kim, Young-Myoung;Kwon, Kung-Taek
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.478-500
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    • 1994
  • The preparation of potassium hexatitanate whisker by flux method was investigated. In this study, 8 types synthesis of flux such as $V_2O_5$, $Bi_2O_3$, $B_2O_3$, $Pb_3O_4$, KCl, $K_4P_2O_7$, $K_2WO_4$ and $K_2MoO_4$ were tested to find a suitable flux for the synthesis of potassium hexatitanate whisker. Effects of various reaction variables such as reaction temperature, time, $TiO_2$ mole ratio to $K_2CO_3$, flux mole ratio to the mixture of $K_2CO_3$ and $TiO_2$, and slow-cooling treatment on the crystallization of potassium hexatitanate whisker were investigated. $K_2MoO_4$ and $K_2WO_4$ were better flux than others tested for the synthesis of potassium hexatitanate. In the presence of $K_2MoO_4$ or $K_2WO_4$ flux, the optimum condition for the synthesis of potassium hexatitanate whisker was that reaction temperature of $1000{\sim}1100^{\circ}C$, reaction time of 5 hours, $TiO_2$ mole ratio to $K_2CO_3$ of 6.0, and flux mole ratio to mixture ($K_2O+nTiO_2$) of 4.0. Slow-cooling treatment showed good effect on the growth of long fibrous potassium hexatitanate.

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SELF-RECIPROCAL POLYNOMIALS WITH RELATED MAXIMAL ZEROS

  • Bae, Jaegug;Kim, Seon-Hong
    • Bulletin of the Korean Mathematical Society
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    • v.50 no.3
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    • pp.983-991
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    • 2013
  • For each real number $n$ > 6, we prove that there is a sequence $\{pk(n,z)\}^{\infty}_{k=1}$ of fourth degree self-reciprocal polynomials such that the zeros of $p_k(n,z)$ are all simple and real, and every $p_{k+1}(n,z)$ has the largest (in modulus) zero ${\alpha}{\beta}$ where ${\alpha}$ and ${\beta}$ are the first and the second largest (in modulus) zeros of $p_k(n,z)$, respectively. One such sequence is given by $p_k(n,z)$ so that $$p_k(n,z)=z^4-q_{k-1}(n)z^3+(q_k(n)+2)z^2-q_{k-1}(n)z+1$$, where $q_0(n)=1$ and other $q_k(n)^{\prime}s$ are polynomials in n defined by the severely nonlinear recurrence $$4q_{2m-1}(n)=q^2_{2m-2}(n)-(4n+1)\prod_{j=0}^{m-2}\;q^2_{2j}(n),\\4q_{2m}(n)=q^2_{2m-1}(n)-(n-2)(n-6)\prod_{j=0}^{m-2}\;q^2_{2j+1}(n)$$ for $m{\geq}1$, with the usual empty product conventions, i.e., ${\prod}_{j=0}^{-1}\;b_j=1$.

Identification of Streptomyces species antagonistic to Fusarium solani or Cylindrocarpon destructans causing ginseng root rots (인삼근부(人蔘根腐) 병원균(病原菌), Fusarium solani 및 Cylindrocarpon destructans에 길항적(拮抗的)인 Streptomyces species의 분류동정(分類同定))

  • Shim, Jae-Ouk;Lee, Min-Woong
    • The Korean Journal of Mycology
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    • v.19 no.1
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    • pp.66-73
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    • 1991
  • Among 110 isolates of actinomycetes isolated from ginseng pathogen-suppressive soils, the three actinomycetes showing the effective controls to Fusarium solani or Cylindrocarpon destruc­tans causing ginseng root rots were identified according to their morphological, cultural and physio­logical characteristics on various culture media. Spore chains of K 6-2, S 2-1 and Y 2-2 were Spira (S), Retinaculum-apertum (RA) and Rectus-flexibilis (RF), respectively. Spore surfaces of K 6-2 were spiny, whereas S 2-1 and Y 2-2 were all smooth. Aerial mass colors of 3 isolates were gray series. As a result of various tests, they were identified as Streptomyces variabilis, Streptomyces virgi­niae and Streptomyces griseo/us, respectively.

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Embedding Algorithm of 2$^{2n-k}$$\times$2$^{k}$ Torus on HCN(n,n) (2$^{2n-k}$$\times$2$^{k}$ 토러스의 HCN(n,n)에 대한 임베딩 알고리즘)

  • 강민식;김종석;이형옥;허영남
    • Proceedings of the Korean Information Science Society Conference
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    • 2002.04a
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    • pp.697-699
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    • 2002
  • 임베딩은 어떤 연결망이 다른 연결망 구조에 포함 흑은 어떻게 연관되어 있는지를 알아보기 위해 어떤 특정한 연결망을 다른 연결망에 사상하는 것으로, 특정한 연결망에서 사용하던 여러 가지 알고리즘을 다른 연결망에서 효율적으로 이용할 수 있도록 한다. 본 논문에서는 2$^{2n-k}$ $\times$2$^{k}$ 토러스를 HCN(n,n)에 연장율 3에 임베딩 가능함을 보인다.

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VARIOUS CONTINUITIES OF A MAP f ; (X, k, TnX) → (Y, 2, TY) IN COMPUTER TOPOLOGY

  • HAN, SANG-EON
    • Honam Mathematical Journal
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    • v.28 no.4
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    • pp.591-603
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    • 2006
  • For a set $X{\subset}{\mathbb{Z}}^n$ let $(X,\;T^n_X)$ be the subspace of the Khalimsky n-dimensional space $({\mathbb{Z}}^n,\;T^n)$, $n{\in}N$. Considering a k-adjacency of $(X,\;T^n_X)$, we use the notation $(X,\;k,\;T^n_X)$. In this paper for a map $$f:(X,\;k,\;T^n_X){\rightarrow}(Y,\;2\;T_Y)$$, we find the condition that weak (k, 2)-continuity of the map f implies strong (k, 2)-continuity of f.

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PRECISE RATES IN THE LAW OF THE LOGARITHM FOR THE MOMENT CONVERGENCE OF I.I.D. RANDOM VARIABLES

  • Pang, Tian-Xiao;Lin, Zheng-Yan;Jiang, Ye;Hwang, Kyo-Shin
    • Journal of the Korean Mathematical Society
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    • v.45 no.4
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    • pp.993-1005
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    • 2008
  • Let {$X,\;X_n;n{\geq}1$} be a sequence of i.i.d. random variables. Set $S_n=X_1+X_2+{\cdots}+X_n,\;M_n=\max_{k{\leq}n}|S_k|,\;n{\geq}1$. Then we obtain that for any -1$\lim\limits_{{\varepsilon}{\searrow}0}\;{\varepsilon}^{2b+2}\sum\limits_{n=1}^\infty\;{\frac {(log\;n)^b}{n^{3/2}}\;E\{M_n-{\varepsilon}{\sigma}\sqrt{n\;log\;n\}+=\frac{2\sigma}{(b+1)(2b+3)}\;E|N|^{2b+3}\sum\limits_{k=0}^\infty\;{\frac{(-1)^k}{(2k+1)^{2b+3}$ if and only if EX=0 and $EX^2={\sigma}^2<{\infty}$.

LOCALLY CONFORMAL KÄHLER MANIFOLDS AND CONFORMAL SCALAR CURVATURE

  • Kim, Jae-Man
    • Communications of the Korean Mathematical Society
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    • v.25 no.2
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    • pp.245-249
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    • 2010
  • We show that on a compact locally conformal K$\ddot{a}$hler manifold $M^{2n}$ (dim $M^{2n}\;=\;2n\;{\geq}\;4$), $M^{2n}$ is K$\ddot{a}$hler if and only if its conformal scalar curvature k is not smaller than the scalar curvature s of $M^{2n}$ everywhere. As a consequence, if a compact locally conformal K$\ddot{a}$hler manifold $M^{2n}$ is both conformally flat and scalar flat, then $M^{2n}$ is K$\ddot{a}$hler. In contrast with the compact case, we show that there exists a locally conformal K$\ddot{a}$hler manifold with k equal to s, which is not K$\ddot{a}$hler.