• Title/Summary/Keyword: Xylene

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고농도 Indole 내성 Pseudomonas savastanoi BCNU 106에 의한 Indigo 및 Indirubin의 생산

  • Choe, Ri-Na;Cha, Mun-Jeong;Park, Jeong-Uk;Ju, U-Hong
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.470-473
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    • 2000
  • Since the biosynthetic production of indigo and indirubin normally reflects a difficult process including the toxicity of indole to microorganisms, only several bacterial strains have been exploited to produce indigo and indirubin from indole or its derivatives. P. savastanoi BCNU 106, which was a gram negative bacterium, was isolated and tolerant to 10% (v/v) toluene. The indole tolerance level of P. savastanoi BCNU 106 was as high as 160 mg/ml when toluene or p-xylene was added to the medium to 20% by volume. P. savastanoi BCNU 106 grown in a two-phase culture system containing indole(100 mg/ml) and P-xylene (0.2 ml/ml) produced P-xylene-soluble pigments, blue indigo and purple indirubin. Of the conditious tried, the production of indigo and indirubin was found only when P. savastanoi BCNU 106 was grown in the two-phase system overlaid with the organic solvents with appropriate polarity. This study may illustrate that the isolated extremophile P. savastanoi could be used in the microbial conversion process of the industrial potentials.

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On Exposure of Workers in Sections Handling Organic Solvents within Hospitals to Benzene, Xylene, and Toluene (병원 내 근로자 중 유기용제를 취급하는 부서에서 벤젠, 크실렌, 톨루엔의 노출 여부에 관한 연구)

  • Oh, Dong-Sun;Park, Mi-Suk
    • Korean Journal of Clinical Laboratory Science
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    • v.40 no.2
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    • pp.147-152
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    • 2008
  • Due to the development and expansion of industries and medical standards, the number of workers who handle organic solvents within hospitals is increasing. The authors in this study intended to investigate the actual conditions of the handling of the solvents and to encourage the recognition that the exposure to such solvents may be possible because of insensitivity to safety. In order to investigate the actual conditions of exposure of workers within hospitals, the experimental group included the three sections (Pathology department, Central Supply Room, and Operating Room), which handle organic solvents most frequently. Meanwhile, university interns were selected to be the control group. This study was conducted between May 1 to May 30, 2007, and urine was taken as samples. Hippuric acid, mandelic acid, methylhippuric acid, and phenylglyoxylic acid were analyzed through gas chromatography, and a total of 52 subjects of the experimental and the control groups were performed of the analysis. As for the results of the analysis of the experimental group, the exposure to benzene was $42.27{\pm}3.70mg/g$ creatinine, that of xylene was $1.30{\pm}0.18g/g$ creatinine, and that of toluene was $2.36{\pm}0.24g/g$ creatinine. Meanwhile, the results of the analysis of the control group showed that the exposure to benzene was $15.54{\pm}2.85mg/g$ creatinine, that of xylene was $0.52{\pm}0.02g/g$ creatinine, and that of toluene was $0.85{\pm}0.20g/g$ creatinine. The amount of exposure to benzene, xylene, and toluene was shown to be under the maximum permitted level, but as for Pathology department, it was required to educate on working conditions, to educate workers on prevention management about their health, and to install fume hood and exhaust system to improve the environments.

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Anti-Inflammatory Effect of Jungcheonhwadamgangki-tang ga Antler in Xylene-Application Mouse Ear Acute Inflammation Model (정천화담강기탕가녹용(定喘化痰降氣湯加鹿茸)이 Xylene으로 유발된 마우스의 급성 염증에 미치는 영향)

  • Cho, Dong-Hee;Son, Ji-Young;Lee, Yeon-Kyeong;Choi, Kyu-Ho;Park, Mee-Yeon;Choi, Hae-Yun;Kim, Jong-Dae
    • Herbal Formula Science
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    • v.15 no.2
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    • pp.99-111
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    • 2007
  • In the present study, the anti-inflammatory effect of "Jungcheonhwadamgangki-tang ga Antler" water extract was tested in Xylene-Application mouse ear acute inflammation model. The test articles were once dosed before Xylene-Application, and the changes on body weight and ear weights and histopathological observation of induced ear were conducted with ear histomorphometry. The obtained results were as follows. The increases of absolute and relative ear weight detected in vehicle control compared to that of sham, were significantly and dose-dependently inhibited by Jungcheonhwadamgangki-tang ga Antler in the present study. A classic acute inflammatory histological changes such as subcutaneous edema, thickness and infiltration of inflammatory cells, was detected in vehicle control. However, these histological changes were significantly and dose-dependently inhibited by Jungcheonhwadamgangki-tang ga Antler. In addition, the increases of ear thickness half and thickness full detected in the vehicle control were also dose-dependently decreased in the all Jungcheonhwadamgangki-tang ga Antler-dosing groups. Base on these results, it is concluded that Jungcheonhwadamgangki-tang ga Antler extracts has clear anti-inflammatory effect on the acute inflammation such as bronchial asthma.

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Effect of Surfactant on Solvent Extraction for Light Hydrocarbon from Soils (토양중 Light Hydrocarbon의 용매추출에 미치는 계면활성제의 영향)

  • Hwang, Keon-Joong;Atalay, Asmare
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.74-79
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    • 1998
  • This study was conducted to evaluate the surfactant solutions which influence solvent extraction from light hydrocarbon contaminated soils. Nine characteristic compounds were studied: benzene, toluene, ethylbenzene, o-xylene, mxylene, p-xylene, n-propylbenzene, 1,2,4-trimethylbenzene, and n-butylbenzene which were found in gasoline. Adsee-799 and Witbreak DRA-22 showed some extractive capacity for light hydrocarbons from soil. There was no added advantage obtained by using other surfactants in this study. No removal of contaminants from soil was observed when the surfactant concentration was 0.5 percent or below. When the surfactant concentration was 4 percent, the average recovery for some hydrocarbons was 10.8 percent, which was the best obtained at these levels. There was 10 percent surfactant contribution for methanol extraction from soil with the Witbreak DPG-482 and Witbreak DRA-22. This study provided a useful screening technique for procedures that can be used to remediate soils contaminated with light hydrocarbons.

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Stability of $4-Chloro-{\alpha}-(4-chlorophenyl)-{\alpha}-(trichloromethyl)$ Benzyl Alcohol(Dicofol) in Various Organic Solvents ($4-Chloro-{\alpha}-(4-chlorophenyl)-{\alpha}-(trichloromethyl)$ Benzyl Alcohol(Dicofol)의 각종유기용매중(各種有機溶媒中)에서의 안정성(安定性))

  • Shin, Hyeon-Hwa;Hong, Jong-Uck
    • Applied Biological Chemistry
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    • v.25 no.3
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    • pp.177-181
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    • 1982
  • This experiment was carried out to investigate the stability of Dicofol solutions which were prepared with various organic solvents such as xylene, toluene, methylisobutyl ketone (M.I.B.K.), cyclohexanone, N.N.-dimetyl formamide (N.N.-D.M.F.) and isophorone under different temperature and storage period. The decomposition rate of Dicofol was increased in the order of cyclohexanone> N.N.-D.M.F.>W.P.>toluene, xylene, M.I.B.K. and isophorone. However, it was shown that precipitation was found in Dicofol solutions such as xylene, toluene and M.I..B.K. except isophorone. Therefore, isophorone was recognized as the best of organic solvents tested for Dicofol in the case of emulsifiable concentrate formulation with it.

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The Measurement and Estimation of the Lower Flash Points for tert-Pentanol + Propionic Acid and p-Xylene + Propionic Acid Systems Using Open-Cup Apparatus (개방식 장치를 이용한 tert-Pentanol + Propionic Acid 및 p-Xylene + Propionic Acid 계의 하부인화점 측정 및 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.161-166
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    • 2009
  • The lower flash points for the tert-pentanol + propionic acid and p-xylene + propionic acid systems were measured by Tag open-cup apparatus. The experimental data were compared with the values calculated by the Raoult's law, the van Laar equation and the NRTL equation. The calculated values based on the van Laar and NRTL equations were found to be better than those based on the Raoult's law. It was concluded that the van Laar and NRTL equations were more effective than the Raoult' law at describing the activity coefficients for non-ideal solution such as the tert-pentanol + propionic acid and p-xylene + propionic acid systems. The predictive curve of the flash point prediction model based on the NRTL equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the van Laar equation.

Sonochemical Synthesis of UiO-66 for CO2 Adsorption and Xylene Isomer Separation (초음파 합성법을 이용한 UiO-66의 합성 및 이산화탄소 흡착/자일렌 이성체 분리 연구)

  • Kim, Hee-Young;Kim, Se-Na;Kim, Jun;Ahn, Wha-Seung
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.470-475
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    • 2013
  • Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.

Characteristics of Source and Concentration of VOCs in Daegu (대구지역 대기 중 VOCs 농도 및 발생원 특성)

  • Gu Min-Jung;Choi Sung-Woo
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.543-553
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    • 2005
  • In recent days, photochemical smog due to the rapid industry development and vehicle increasement has become a critical pollutant in the metropolitan area and the number of ozone alarm signal has increased every year. This research was performed to evaluate VOCs emission source characteristics and concentration of VOCs in Daegu. The site average concentration was observed in the following order: industrial area > commercial area > residential area. Most of the VOCs species except toluene showed variations with higher concentration during nighttime, and lower concentration during the daytime. The major VOCs of stationary emission source were BTEX(benzene, toluene, ethylbenzene. xylene) and methylene chloride, trichloroethene and styrene. Also, those of automobile exhaust were toluene and benzene. Also, the major VOCs concentration emited by the vehicle fuel was observed in the following order: gasoline > light oil > liquefied petroleum gas (L.P.G). Correlation coefficients values were estimated between major VOCs such as toluene, ethylbenzene, m,p-xylene, o-xylene. Results showed that correlation coefficient values were significant magnitude above 0.76. Also, there showed highly significant correlations among ethyl benzene, m,p-xylene, and o-xylene concentration(Pearson correlation coefficients, r=0.868-0.982). Calculated correlation coefficients among commercial area,industrial area and residential area were 0.934-0.981, they showed high correlation. There showed highly correlation between stationary emission source and industrial area, compared with commercial area and residential area. Also, calculated correlation coefficients among commercial area, industrial area, residential area and automobile exhaust were 0.732, 0.725, 0.777, respectively.

Anti-Inflammatory Effect of Haepyoejin-tang plus Antler water extract in Xylene-Application Mouse Ear Acute Inflammation Model (해표이진탕가녹용(解表二陳湯加鹿茸)이 Xylene으로 유발된 마우스의 급성 염증에 미치는 영향)

  • Jung, Bong-Gyun;Jeon, Kwi-Ok;Park, Mee-Yeon;Choi, Hae-Yun;Kim, Jong-Dae;Cho, Dong-Hee
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.4
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    • pp.985-991
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    • 2006
  • In the present study, the anti-inflammatory effect of Haepyoeiin-tang plus Antler water extract water extract was tested in Xylene-Application mouse ear acute inflammation model. The test articles were once dosed before Xylene-Application, and the changes on Dody weight and weights and histopathological observation of induced ear were conducted with ear histomorphometry, The increases of absolute and relative ear weight detected in vehicle control compared to that of sham, were significantly and dose-dependently inhibited by Haepyoejin-tang plus Antler in the present study, A classic acute inflammatory histological changes such as subcutaneous edema, hypertrophy and infiltration of inflammatory cells, was detected in vehicle control. However, these histological changes were significantly and dose-dependently inhibited by Haepyoeiin-tang plus Antler. In addition, the increases of ear thickness half and thickness full detected in the vehicle control, were also dose-dependently decreased in the all Haepyoeiin-tang plus Antler-dosing groups. Base on these results, it is concluded that Haepyoeiin-tang plus Antler water extracts have a clear anti-inflammatory effect on the acute inflammation. However, somewhat lower anti-inflammatory effects were detected in Haepyoeiin-tang plus Antler water extracts compare to that of Dethamethason and Dicrofenac. About 500 mg/kg of Haepyoeiin-tang plus Antler water extracts have similar effect compared to that of Dicrofenac 15 mg/kg.

Anti-Inflammatory Effect of 'Jungcheonhwadamgangki-tang'in Xylene-Application Mouse Ear Acute Inflammation Model (정서화담강기탕(定瑞化痰降氣湯)이 Xylene으로 유발된 마우스의 급성 염증에 미치는 영향)

  • Song, Muh-Sik;Jeon, Kwi-Ok;Park, Mee-Yeon;Choi, Hae-Yun;Kim, Jong-Dae;Cho, Dong-Hee
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.4
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    • pp.875-881
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    • 2006
  • In the present study, the anti-inflammatory effect of 'Jungcheonhwadamgangki -tang' water extract was tested in Xylene-Application mouse ear acute inflammation model. The test articles were once dosed before Xylene-Application, and the changes on body weight and ear weights and histopathological observation of induced ear were conducted with ear histomorphometry. The increases of absolute and relative ear weight detected in vehicle control compared to that of sham , were significantly and dose-dependently inhibited by Jungcheonhwadarn -gangki-tang in the present study. A classic acute inflammatory histological changes such as subcutaneous edema, hypertrophy and infiltration of inflammatory cells, was detected in vehicle control. However, these histological changes were significantly and dose-dependently inhibited by Jungcheonhwadam-gangki-tang. In addition, the increases of ear thickness half and thickness full detected in the vehicle control, were also dose-dependently decreased in the all Jungcheonhwadamgangki-tang-dosing groups. Base on these results, it is concluded that Jungcheonhwadamgangki-tang water extracts have clear anti-inflammatory effect on the acute inflammation, and about 500 mg/kg of Jungcheonhwadamgangki-tang water extracts have similar effect compared to that of Dicrofenac 15 mg/kg.