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http://dx.doi.org/10.9713/kcer.2013.51.4.470

Sonochemical Synthesis of UiO-66 for CO2 Adsorption and Xylene Isomer Separation  

Kim, Hee-Young (Department of Chemical Engineering, Inha University)
Kim, Se-Na (Department of Chemical Engineering, Inha University)
Kim, Jun (Department of Chemical Engineering, Inha University)
Ahn, Wha-Seung (Department of Chemical Engineering, Inha University)
Publication Information
Korean Chemical Engineering Research / v.51, no.4, 2013 , pp. 470-475 More about this Journal
Abstract
Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.
Keywords
Metal Organic Frameworks (MOFs); UiO-66; Sonochemical Synthesis; $CO_2$ Adsorption; Xylene Isomer Separation;
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