• Title/Summary/Keyword: X-선 구조분석

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GaAs 기반의 텐덤형 태양전지 연구

  • Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.2-2
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    • 2010
  • 텐덤형 태양전지는 다양한 에너지 대역을 동시에 흡수할 수 있도록 제작할 수 있어 단일접합 태양전지에 비해 높은 에너지변환효율을 기대할 수 있다. 본 연구에서는 GaAs를 기반으로 양자점 혹은 양자우물 구조를 이용한 고효율 텐덤형 태양전지를 설계하고, 완충층 및 활성층의 특성을 분석하였다. 분자선 단결정 성장 장비를 이용하여 GaAs 기판 위에 메타모픽 (metamorphic)성장법을 이용하여 convex, linear, concave 형태로 조성을 변화시켜 $In_xAl_1-_xAs$ 경사형 완충층을 성장한 후 그 특성을 비교하였다. 또한, 최적화된 경사형 완충층 위에 1.1 eV와 1.3 eV의 에너지 대역을 각각 흡수할 수 있는 적층 (5, 10, 15 층)된 InAs 양자점 구조 또는 InGaAs 양자우물구조를 삽입하여 p-n 접합을 성장하였다. 그리고 GaAs/AlGaAs층을 이용한 터널접합에서는 GaAs층의 두께 (20, 30, 50 nm)에 따른 터널링 효과를 평가하였다. 그 결과, 경사형 완충층을 통해 조성 변화로 인한 결함을 최소화하여 다양하게 조성 변화가 가능한 고품위의 구조를 선택적으로 성장할 수 있었으며, 적층의 양자점 구조 및 양자우물 구조를 이용해 고효율 텐덤형 태양전지의 구현 가능성을 확인하였다.

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Characterization of Tussah (Antheraea pernyi) Silk Fibroin Powder Prepared by HCI and NaOH (작잠견피브로인 분말의 제조와 그 특성)

  • Kweon, Hae-Yong;Lee, Kwang-Gill;Lee, Yong-Woo
    • Journal of Sericultural and Entomological Science
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    • v.41 no.1
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    • pp.54-60
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    • 1999
  • Antheraea pernyi silk powder was prepared by treatment with HCl and NaOH. The degree of hydrolysis of Antheraea pernyi silk fiber was examined. The morphology and structural characteristics of Antheraea pernyi silk powder were investigated by using SEM, FTIR and X-ray diffractometer. As the concentration of HCl and NaOH and tratment temperature increased, in general, the degree of hydrolysis of Antheraea pernyi silk fiber increased. On the other hand, the degree of hydrolysis of Antheraea pernyi treated with 3 N NaOH at 120$^{\circ}C$ for 24 hr was 70 wt%, which was lower than that of 90$^{\circ}C$(83 wt%). The morphology of acid/alkali resistance fraction of Antheraea pernyi silk fibroin was transformed from fiber form to powered one with an increase of hydrolysis. The conformation of Antheraea pernyi silk powder characterized by FT-IR spectrometer and X-ray diffractometer ${\beta}$-sheet and ${\alpha}$-helix structure.

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Effect of Co Interlayer on the Interfacial Reliability of SiNx/Co/Cu Thin Film Structure for Advanced Cu Interconnects (미세 Cu 배선 적용을 위한 SiNx/Co/Cu 박막구조에서 Co층이 계면 신뢰성에 미치는 영향 분석)

  • Lee, Hyeonchul;Jeong, Minsu;Kim, Gahui;Son, Kirak;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.41-47
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    • 2020
  • The effect of Co interlayer on the interfacial reliability of SiNx/Co/Cu thin film structure for advanced Cu interconnects was systematically evaluated by using a double cantilever beam test. The interfacial adhesion energy of the SiNx/Cu thin film structure was 0.90 J/㎡. This value of the SiNx/Co/Cu thin film structure increased to 9.59 J/㎡.Measured interfacial adhesion energy of SiNx/Co/Cu structure was around 10 times higher than SiNx/Cu structure due to CoSi2 reaction layer formation at SiNx/Co interface, which was confirmed by X-ray photoelectron spectroscopy analysis. The interfacial adhesion energy of SiNx/Co/Cu structure decreased sharply after post-annealing at 200℃ for 24 h due to Co oxidation at SiNx/Co interface. Therefore, it is required to control the CoO and Co3O4 formation during the environmental storage of the SiNx/Co/Cu thin film to achieve interfacial reliability for advanced Cu interconnections.

Manufacture of Yellow Ocher Polystyrene-Based Hybrid Nanoparticles for High-Performance PET Applications (고성능 페트 생산용 폴리스티렌 기반 하이브리드형 나노구조체 생산)

  • Choi, Jae Bong;Kim, Sanghee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.8
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    • pp.701-707
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    • 2014
  • The ecofriendly yellow ocher is used in the manufacturing of cosmetics, construction, and food packaging. The polyethylene terephthalate (PET) used for manufacturing food containers has a microporous structure that causes aeration. Hydrophilic yellow ocher may be applied to hydrophobic PET by surface modification to overcome this issue. The aim of this study is to fabricate a yellow ocher polystyrene hybrid structure in the form of nanoparticles using an optimizing molar ratio of styrene, divinylbenzene, and potassium peroxodisulfate for use in emulsion polymerization. The polymerization was conducted in a yellow ocher suspension that was prepared by dispersing mechanically ground yellow ocher in DI water. The prepared hybrid structure was measured using scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. The measurement revealed the spherical morphology and Si component that resulted from the yellow ocher in the polystyrene particles. We expect that this hybrid structure would be used as platform material to minimize aeration in PET.

Properties of Polyacene Anode Derived from Phenolic Resin (페놀 수지로부터 유도된 Polyacene계 부극의 특성)

  • Oh, Won-Chun;Kim, Bum-Soo;Hwang, In-Soo;Lee, Young-Hoon;Lee, Byung-Eui
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.504-508
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    • 1999
  • We have studied structural charecterization, electrical charge and discharge, and impedence properties for polyacene anode material derived from phenolic resin of novolak type. From the X-ray diffraction results, diffraction patterns for compounds of the three kinds of P-700, P-850, P-1000 were observed for semiirregular structural transition. A electrical charge and discharge data showed that the properties of p-850 was much better than any other samples. From the impedence properties for finding the effect of ions and electron transfer of battery, P-1000 and P-850 of high frequency of real number showed good electrical impedence properties.

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High-Resolution X-Ray Photoelectron Spectroscopy Study of a Sb2Te3 Thin Film with the Polycrystalline Phase (고해상도 엑스선 광전자 분광법을 이용한 다결정구조의 안티몬-테레니움 박막 연구)

  • Lee, Y.M.;Kim, K.;Shin, H.J.;Jung, M.C.;Qi, Y.
    • Journal of the Korean Vacuum Society
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    • v.21 no.6
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    • pp.348-353
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    • 2012
  • We investigated chemical states of a $Sb_2Te_3$ thin film with the polycrystalline phase by using high-resolution x-ray photoelectron spectroscopy with synchrotron radiation. The $Sb_2Te_3$ thin film was formed by sputtering. The rhombohedral phase was confirmed by x-ray diffraction. To remove the surface oxide, we performed $Ne^+$ ion sputtering for 1 hour with the beam energy of 1 kV and post-annealing at $100^{\circ}C$ for 5 min in ultra-high vacuum. We obtained the Te and Sb 4d core-levels spectra with the peaks at the binding energies of 40.4 and 33.0 eV, respectively. The full-width of half maximum of both the Te and Sb $4d_{5/2}$ core-levels is 0.9 eV. The Te and Sb core-levels only show a single chemical state, and we also confirmed the stoichiometry of approximately 2 : 3.

Three-dimensional structure analysis of mouse nails using synchrotron radiation (방사광 X-선을 이용한 마우스 조갑의 3차원적 구조 분석)

  • Jung, Yong-Ju;Hong, Gee-Yun;Moon, Cho-I;Yoo, Hyun-Jong;Lee, On-Seok
    • Proceedings of the Korea Information Processing Society Conference
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    • 2018.10a
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    • pp.790-791
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    • 2018
  • 방사광 X-ray 이미징 기술은 샘플의 고감도 및 고해상도 3차원 해부구조를 규명하는데 매우 유용하다는 장점이 있다. 따라서 이러한 방사광을 이용해 사람의 조갑병변 연구를 위한 동물모델로서 마우스 조갑의 내부 미세구조를 관찰하였고 상대적으로 구분이 명확하고 의학적으로 의미론적인 구조물을 3D로 가시화하여 조갑 구조 해석에 새로이 활용될 가능성을 확인하고자 하였다.

The Multiferroic Properties Study of YMn2-xFexO5 (x=0.00, 0.01) by Neutron Diffraction (고 분해능 중성자 회절 실험에 의한 YMn2-xFexO5 (x = 0.00, 0.01)의 다강체 특성 연구)

  • Kim, Dong-Hyun;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.183-187
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    • 2007
  • Compounds of multiferroic materials $YMn_{2-x}Fe_xO_5$ (x = 0.00, 0.01) were prepared using the sol-gel method. The crystallographic, magnetic and electric properties are studied using x-ray diffraction (XRD), neutron diffraction, vibrating sample magnetometer (VSM) and physical property measurement system (PPMS). The crystalline structure of $YMn_2O_5$ was found to be orthorhombic (Pbam) at room temperature. The lattice constants of $YMn_2O_5$ were determined to be $a_0=7.275\;{\AA},\;b_0=8.487\;{\AA},\;c_0=5.674\;{\AA}$. The lattice constants not changed with Fe concentrations. Our data demonstrate the correlation of magnetic and electric properties in $YMn_2O_5$ materials.

Structural and optical properties of ZnO nanostructures with various distance condition by vapor phase transport (기상이동법으로 간격 변화에 따라 성장한 산화아연 나노구조의 구조적, 광학적 특성)

  • Kim, So-A-Ram;Kim, Min-Su;Nam, Gi-Ung;Park, Hyeong-Gil;Yun, Hyeon-Sik;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.243-244
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    • 2012
  • 산화아연 나노구조를 금을 금속촉매로 사용하여 실리콘 기판위에 기상이동법으로 성장하였다. 성장할 때 소스(source)와 기판 사이의 거리는 5에서 50 mm로 변화를 주며 아르곤과 산소 분위기에서 $900^{\circ}C$로 성장하였다. 산화아연 나노구조의 구조적 및 광학적 특성을 조사하기 위해 field-emission scanning electron microscopy, X-ray diffraction (XRD), 그리고 photoluminescence (PL)를 이용하였다. 산화아연 나노구조는 나노선과 나노입자의 형태로 성장하였다. 산화아연 나노구조의 광학적 특성은 소스와 기판사이의 거리가 가까울수록 향상되었다. 특히, 소스와 기판사이의 거리가 5 mm 일 때, 산화아연 나노선이 관찰되었으며 XRD 와 PL 분석에서 나타난 반가폭 (full width at half maximum)은 $0.061^{\circ}$ 와 96 meV로써 가장 작았다. 산화아연 나노선은 산화아연 나노입자와 비교하여, 결정성 및 광학적 특성이 우수하였다.

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