• Journal of the Korean Wood Science and Technology
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• 제46권5호
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• pp.449-470
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• 2018

본 총설에서는 외부에 사용되는 목재를 풍화인자로부터 보호하기 위해 실행되고 있는 최근의 연구동향에 대해 조사 분석하였다. 주요 기상열화 인자로부터 목재의 표면 보호를 위한 연구 동향에 대하여 조사한 결과 다음과 같은 결론을 얻었다. 목재보존제로 사용된 크롬, 구리 등의 무기화합물이 목재를 기상열화로부터 보호할 수 있는 것으로 보고되었다. 또한 ACQ처리 목재의 표면에 wax나 oil같은 소수성물질과 UV 흡수제, HALS(Hindered Amine Light Stabilizers) 등을 방부목재 표면에 precoating하면 기상열화 저항성을 강화할 수 있다고 보고되었다. 또한 방부목재 표면에 불투명 도막형성의 페인트/스테인 및 반투명스테인등이 기상열화방지에 대한 시너지 효과가 높힐수 있다는 보고들이 다수 있었다. 또한 방부목재의 표면보호를 위한 재도장 처리의 필요성이 시사되었다. 투명성의 도막에 UV방지를 위한 첨가물로서 미세입자의 ZnO 또는 $TiO_2$, Co, Cr, Fe, Mn, Ni과 Ti 등의 금속이온, Tris-resorcinol triazine derivatives, triazine 및 Benzotriazole과 같은 UV흡수제 등이 소개되었다. Methylation, acetylation 또는 alkylation 등과 같이 화학적으로 개질된 경우에는 이로 인한 중량증가가 높은 경우 기상열화 방지효과가 상승된다는 연구들이 소개되었다, 열처리목재의 기상열화 저항성에 대해서는 여러 가지 상반되는 연구보고 들이 있었고, UV저항성을 지닌 도장의 필요성이 강조된 보고가 있어 보다 심도 있는 연구의 필요성이 시사되었다.

• 한국지형학회지
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• 제18권3호
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• pp.21-36
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• 2011

암석의 풍화작용은 지형발달에 있어 물질의 준비과정으로서 역할을 한다. 이 중 동결-융해작용은 한대지역이나 주빙하 지역뿐만 아니라 심지어 온대지역에서도 암석을 파괴시키는데 효과적인 프로세스로 여겨져 왔다. 화강암(생암, 반풍화층), 편마암, 석회암, 돌로마이트의 슬랩시편 각각 10개를 -25℃~+30℃의 조건으로 동결-융해를 180회 반복하고 이들의 풍화양상과 물리적 특성변화를 검토한 결과, 파쇄는 대기와 토양조건보다는 침수조건에서 좀 더 활발히 진전되었으며 공극률이 높은 석회암과 돌로마이트가 가장 심하게 파쇄되었다. 편마암은 표면에 crack, joint, fissure들이 발달해 있고 암석강도(SHV)가 가장 낮았음에도, 어떠한 물리적 변화나 풍화산물들이 생성되지 않아 풍화에 저항력이 매우 높은 암석으로 나타나고 있다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.151-154
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• 2002

The durability of two kinds of CFRP plates, carbon/UP and carbon/V, was studied under severe environmental conditions. Immersion into the chemical solutions and accelerated weathering were executed on the CFRP plates and the weight change under each condition was measured. After those treatments, the plates were tested by tensile testing machine to measure the mechanical properties and observed by SEM to find the damage behaviour of the surface. Comparing the virgin plates and the chemically exposed plates, both plates show severe deterioration of the mechanical properties. But, the plates subjected to alkali solution show much larger reduction than those of acidic solution and carbon/V has better chemical resistance than carbon/UP. The material properties of CFRP plate exposed to the weathering were deteriorated linearly proportional to the exposure time.

• 한국재료학회지
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• 제13권9호
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• pp.625-630
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• 2003

Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as Polyaniline(PANI). Polyaniline films were electrosynthesized by oxidation of aniline on cold rolled and weathering sheets using the potentiostatic mode from an aqueous oxalic acid medium. Potentiodynamic polarization curves were obtained for cold rolled and weathering sheets in the aqueous solution of 3% sodium chloride. The structure and properties of polyaniline film were elucidated using SEM, DSC, SST. A high corrosion resistance of polyaniline films were observed with a gain of the corrosion potential around 600-900 mV positive in the substrate covered with polyaniline than in the case without it.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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• pp.243-247
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• 2003

The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1999년도 춘계학술발표회 초록집
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• pp.25-26
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• 1999

• 한국강구조학회 논문집
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• 제20권5호
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• pp.591-599
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• 2008

내후성강은 자연대기환경에 대하여 무도장 상태로 사용되고, 강재표면에 도막의 역할을 하는 밀실한 녹층은 자연환경에 의해 수년간 에 걸쳐 형성되며, 그 녹 층으로 강재의 부식 진행을 억제한다. 내후성강의 녹상태는 부식환경에 의존한다. 내후성강의 유지관리측면에서 녹상태가 어느정도 인가를 판단하는 것은 중요하다. 따라서, 국내에 있는 건축용 내후성 외장재의 외관조사결과를 바탕으로, 다변량해석에 의한 부식량(녹의 상태)과 외장재 주변환경과의 상관을 분석하고자 한다. 본 논문에서, 외장재의 지리적 데이터, 기상데이터를 이용한 다변량 분석이 수행되었고, 부식 량과 환경요인에 대한 예측식이 제안되었다. 부가적으로, 제안된 부식량 예측식을 이용하여 기호지역(서울, 경기 및 충청)에 적용한 건축용 내후성강 외장재의 부식량 추이를 평가하였다.

• 보존과학연구
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• 통권29호
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• pp.199-220
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• 2008

Hobun(Oyster shell White) is a traditional material used as extender and white pigment from ancient times. The production method of it, however, has been discontinued. We have studied the traditional production method of Hobun by weathering oyster shell, which is one of the traditional ways for preparing Hobun. Reproduction study of manufacturing method of the discontinued traditional material is an important accomplishment of our research. Also this study provides solid background knowledge to stabilize the production and supply of Hobun for the cultural asset repairing materials. The result can be summarized as follows: The production process of Hobun by weathering method takes 5 steps - (1) weathering shells ${\rightarrow}$ (2) washing ${\rightarrow}$ (3) pulverization ${\rightarrow}$ (4) separating fine powder by submerging in water ${\rightarrow}$ (5) drying. The major aim in step (1) is to eliminate organic impurities. In the step (4), the fine particles smaller than $25{\mu}m$ are separated by extracting the supernatant from stirred suspension after heavy particles are submerged. Also, the soluble inorganic impurities can be eliminated through the powder submerge in 15 times water and stirring the suspension 6 hours and changing the water 3~4 times. The final products have high quality with 94.03, 0.52, 2.05 for L, a, b, less than $25{\mu}m$ particle size, fine resistance for discoloration by light and environmental pollution and good workability.

• Steel and Composite Structures
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• 제47권2호
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• pp.269-287
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• 2023

The WGJ420 fire-resistant weathering (FRW) steel is developed and manufactured with standard yield strength of 420 MPa at room temperature, which is expected to significantly enhance the performance of steel structures with excellent fire and corrosion resistances, strong seismic capacity, high strength and ductility, good resilience and robustness. In this paper, the mechanical properties of FRW steel plates and buckling behavior of columns are investigated through tests at elevated temperatures. The stress-strain curves, mechanical properties of FRW steel such as modulus of elasticity, proof strength, tensile strength, as well as corresponding reduction factors are obtained and discussed. The recommended constitutive model based on the Ramberg-Osgood relationship, as well as the relevant formulas for mechanical properties are proposed, which provide fundamental mechanical parameters and references. A total of 12 FRW steel welded I-section columns with different slenderness ratios and buckling load ratios are tested under standard fire to understand the global buckling behavior in-depth. The influences of boundary conditions on the buckling failure modes as well as the critical temperatures are also investigated. In addition, the temperature distributions at different sections/locations of the columns are obtained. It is found that the buckling deformation curve can be divided into four stages: initial expansion stage, stable stage, compression stage and failure stage. The fire test results concluded that the residual buckling capacities of FRW steel columns are substantially higher than the conventional steel columns at elevated temperatures. Furthermore, the numerical results show good agreement with the fire test results in terms of the critical temperature and maximum axial elongation. Finally, the critical temperatures between the numerical results and various code/standard curves (GB 51249, Eurocode 3, AS 4100, BS 5950 and AISC) are compared and verified both in the buckling resistance domain and in the temperature domain. It is demonstrated that the FRW steel columns have sufficient safety redundancy for fire resistance when they are designed according to current codes or standards.

• Corrosion Science and Technology
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• 제23권1호
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• pp.11-19
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• 2024

A Fe-Ni Bainitic steel as a weathering steel application was developed by combining its excellent mechanical properties and corrosion resistance in maritime environments. Nickel concentration (0.4-3 wt%) and inverted austempering multi-step (IAM) process were primary determinants of the microstructure of the Fe-Ni Bainitic steel. The initial austempering steel was performed at 300 ℃ for 600 seconds to obtain a partly bainitic transformation. The steel was heated again for 1800 s at 450 ℃. The microstructure was comprised of ferrite, a blocky martensite/austenite island, and a homogeneous lath-shape bainite structure with widths ranging from 4.67 to 6.89 ㎛. The maximum strength, 1480 MPa, was obtained with 3 wt% nickel. In this study, corrosion behavior was investigated utilizing potentiodynamic and electrochemical impedance spectroscopy (EIS) tests. A higher nickel content in Fe-Ni Bainitic steel refined the grain size, improved the bainite fraction, lowered the corrosion rate to 0.0257 mmpy, and increased the charge transfer of film resistance to 1369 Ω.