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A study fo Al/W(110) surface structure at various annealing temperature and coverage

  • Choe, Dae-Seon;Park, Min-Geol;Park, Mi-Mi;Lee, Jeong-Hwan;Kim, Ju-Hwan;Kim, Do-Hyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.344-344
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    • 2011
  • W(110)면에 흡착원자인 Al원자의 coverage와 annealing과정에서의 온도를 변화시켜, 여러 조건에서의 Al/W(110)계의 흡착구조를 저에너지 전자회절(LEED)과 이온산란분광법(ISS-TOF)을 이용하여 연구하였다. 여러 결과 중, annealing 온도가 900K인 1.0ML Al/W(110)면은 double domain의 p($1{\times}1$)의 흡착구조로 W(110)면의 center of hollow site에서 $0.55{\AA}$ 벗어난 위치에 흡착되었으며, W(110) 표면원자로부터 Al 원자까지의 높이는 $2.13{\pm}0.15{\AA}$이다. 또한 annealing 온도가 1100K인 0.5ML Al/W(110)면은 double domain의 p($2{\times}1$)의 흡착구조로 W(110)면의 center of bridge site에 흡착되었으며, W(110) 표면원자로부터 Al 원자까지의 높이는 $2.18{\pm}0.15{\AA}$이다.

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Effects of W-N/Pt Bottom Electrode on the Ferroelectric Degradation of $Sr_{0.8}Bi_{2.4}Ta_2O_9/Pt/Si$ Structure due to the Hydrogen Annealing ($Sr_{0.8}Bi_{2.4}Ta_2O_9/Pt/Si$ 구조의 수소열처리에 의한 강유전특성 열화에 미치는 W-N/Pt 전극효과)

  • Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.87-91
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    • 2004
  • We have investigated the effects of W-N/Pt bottom electrode on the ferroelectric degradation of $Sr_{0.8}Bi_{2.4}Ta_2O_9(SBT)/Pt$ due to hydrogen annealing at $350^{\circ}C$ in $N_2$ gas atmosphere containing $5{\%}\;H_2$ gas for 1hr. As a result, inserting the W-N thin films between SBT and Pt, this W-N thin film prevents hydrogen molecules to be chemisorbed at the Pt electrode surface of at the electrode/ferroelectric interface during hydrogen annealing. These hydrogen atoms can diffuse into the SBT and react with the oxide causing the oxygen deficiency in the SBT film, which will result in the ferroelectric degradation. Experimental results show that W-N thin film is a good diffusion barrier during the hydrogen annealing.

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Optimization of Conditions for the Double Layer Microencapsulation of Lactic Acid Bacteria (유산균 함유 이중층 미세캡슐화를 위한 조건 최적화)

  • Park, Byung-Gye;Lee, Jong-Hyuk;Shin, Hye-Kyoung;Lee, Jae-Hwan;Chang, Phan-Shik
    • Korean Journal of Food Science and Technology
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    • v.38 no.6
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    • pp.767-772
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    • 2006
  • In this study, we sought to produce a double layer microcapsule containing Lactobacillus sp. as the core material. The conditions for this microencapsulation process were optimized for the formation of a microcapsule with high storage stability. The effects of the ratio of[core material] to [wall material], the type and concentration of emulsifier used, the stirring rate(dispersibility) and the temperature of the dispersion fluid on the microencapsulation yield were studied. The optimal concentration and type of emulsifier required in order to allow for the stable formation of a W/O type emulsion (a primary process in double layer microencapsulation) were 1.00% (w/w) and polyglycerol polyricinileate (PGPR, HLB 0.6). However, the optimal concentration and type of emulsifier required to construct a W/O/W type emulsion (a secondary process in double layer microencapsulation), were 0.65% (w/w) and polyoxyethylene sorbitan monolaurate (PSML, HLB 16.7). Finally, we obtained a maximum yield of microencapsulation with a dispersion fluid stirring rate of 270rpm and a dispersion fluid temperature of 10$^{\circ}C$ after spraying a W/O/W type emulsion into the dispersion fluid.

The Effect of $\textrm{WO}_3$, on the Microstructure and Electrical Properties of ZNR (ZNR의 미세구조 및 전기적 특성에 $\textrm{WO}_3$가 미치는 영향)

  • Nam, Chun-U;Jeong, Sun-Cheol;Park, Chun-Hyeon
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.753-759
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    • 1999
  • The microstructure and electrical properties of ZNR that W $O_3$ is added in the range 0.5~4.0mol%, were investigated. The major part of W $O_3$ were segregated at the nodal point and W-rich phase was formed. Three crystalline phases, such as W-rich phase (W $O_3$), Bi-rich phase (B $i_2$W $O_{6}$ ), and spinel phase (Z $n_{2.33}$S $b_{0.67}$ $O_4$) were confirmed to be co-existed at the nodal point The average grain size increased in the range 15.5~29.9$\mu\textrm{m}$ with increasing W $O_3$ additive content. Consequently. W $O_3$ acted as a promotion additive of grain growth. As the W $O_3$ additive content increases. the varistor voltage and the nonlinear exponent decreased in the range 186.82~35.87V/mm and 20.90~3.34, respectively, and the leakage current increased in the range of 22.39~83.01 uh. With increasing W $O_3$ additive content, the barrier height and the density of interface states decreased in the range 1.93~0.43eV and (4.38~1.22)$\times$10$^{12}$ $\textrm{cm}^2$, respectively. W $O_3$ acted as an acceptor additive due to the donor concentration increasing in the range (1.06~0.38)$\times$10$^{18}$ /㎤with increasing W $O_3$ additive content.t.t.

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Relationship Between the Body Dimension of Sea Eel , Astroconger Myriaster and the Mesh Size of Fishing Gears (붕장어의 어체제원과 어구강목과의 관계)

  • 장충식
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.23 no.4
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    • pp.184-188
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    • 1987
  • The author studied to analyse the relationship between the body dimension of sea eel, Astroconger myriaster and the mesh size of fishing gears. The samples were caught by traps and pots during September, 1987 in the Southern Sea of Korea. The results obtained can be summarized as follows: 1. The relationship between total length L, body weight W and diameter D may be expressed as: W=3.58$\times$10 super(-4) L super(3.38) (r=0.99). D=0.07 L-0.59 (r=0.99). W=10.38 D super(2.76) (r=1.00). W=1/2$\times$D super(2).L. 2. The mesh size of traps and the hole diameter of post must be more than 29.2 mm and 18.6 mm, respectively.

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CYCLIC CODES OVER THE RING 𝔽p[u, v, w]/〈u2, v2, w2, uv - vu, vw - wv, uw - wu〉

  • Kewat, Pramod Kumar;Kushwaha, Sarika
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.1
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    • pp.115-137
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    • 2018
  • Let $R_{u{^2},v^2,w^2,p}$ be a finite non chain ring ${\mathbb{F}}_p[u,v,w]{\langle}u^2,\;v^2,\;w^2,\;uv-vu,\;vw-wv,\;uw-wu{\rangle}$, where p is a prime number. This ring is a part of family of Frobenius rings. In this paper, we explore the structures of cyclic codes over the ring $R_{u{^2},v^2,w^2,p}$ of arbitrary length. We obtain a unique set of generators for these codes and also characterize free cyclic codes. We show that Gray images of cyclic codes are 8-quasicyclic binary linear codes of length 8n over ${\mathbb{F}}_p$. We also determine the rank and the Hamming distance for these codes. At last, we have given some examples.

MODULES SATISFYING CERTAIN CHAIN CONDITIONS AND THEIR ENDOMORPHISMS

  • Wang, Fanggui;Kim, Hwankoo
    • Bulletin of the Korean Mathematical Society
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    • v.52 no.2
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    • pp.549-556
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    • 2015
  • In this paper, we characterize w-Noetherian modules in terms of polynomial modules and w-Nagata modules. Then it is shown that for a finite type w-module M, every w-epimorphism of M onto itself is an isomorphism. We also define and study the concepts of w-Artinian modules and w-simple modules. By using these concepts, it is shown that for a w-Artinian module M, every w-monomorphism of M onto itself is an isomorphism and that for a w-simple module M, $End_RM$ is a division ring.

Effect of Current Density on the Crystal Structure of Ni-W Alloys Prepared by Electrodeposition (Ni-W 합금도금의 결정구조에 미치는 전류밀도의 영향)

  • Kim, Won-Baek;Lee, Cheol-Gyeong;Lee, Jae-Cheon;Seo, Chang-Yeol
    • Korean Journal of Materials Research
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    • v.8 no.10
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    • pp.898-904
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    • 1998
  • Ni-W alloys containing 10 to 50wt% W were prepared by electrodeposition. Tungsten content in the alloy increased with current density. X-ray diffraction analysis revealed that the alloy was crystalline phase when deposited at current densities lower than 50mA/${cm}^2$. Their crystal structure transformed to amorphous at higher current densities. In terms of tungsten content, the crystal -+ amorphous transition occurred at 40-46wt% which was identified by the 3 fold increase in the width of a diffraction peak. The lattice parameter of crystalline phase increased with W upto 40wt% which is higher than the solubility limit of W (about 30wt%) in Ni. Therefore, the alloys are considered to be Ni solid solution supersaturated with W. The amorphous Ni-W alloys were recrystallized by annealing them at temperatures over $400^{\circ}C$. This was evidenced by the appearance a strong [ 11 11 annealing texture. The supersaturated W was precipitated during the annealing at over $800^{\circ}C$. The current-density dependence of W content and crystallinity was utilized to produce alternating layers of crystalline (30wt% W) and amorphous (50wt%) phases which may exhibit unique mechanical and corrosion properties.

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Effect of Tungsten on PtRuW/C Catalysts for Promoting Methanol Electro-oxidation (메탄올 전기산화반응 증진을 위한 PtRuW/C 촉매에서 텅스텐의 효과에 관한 연구)

  • Noh, Chang Soo;Sohn, Jung Min;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.561-566
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    • 2012
  • PtRuW/C catalysts were prepared with the different molar ratios of Pt : Ru : W and their compositions were analyzed by energy dispersive X-ray (EDX). The uniform distribution of particles was observed using transmission electron microscopy (TEM). An average crystalline size of 3.5~5.5 nm was calculated based on x-ray diffraction (XRD) data. The electrochemical properties such as electrochemically active surface areas, current densities, specific activities and poisoning rates, were analyzed via CO stripping, linear sweep voltammetry and chronoamperometry. From the analysis, we observed that ternary alloy catalysts, except $PtRu_2W_2/C$, have higher current densities, specific activities and stabilities than those of commercial binary catalysts. Among all in-house catalysts, Pt5Ru4W/C showed the highest specific activity of $121.05mA{\cdot}m^{-2}$ and the lowest poisoning rate of $0.01%{\cdot}s^{-1}$.

The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film

  • Park, Heesun;Kim, Jongmin;Jung, Young Hee;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.61 no.2
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    • pp.57-64
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    • 2017
  • Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.