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http://dx.doi.org/10.5012/jkcs.2017.61.2.57

The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film  

Park, Heesun (Department of Chemistry, Pukyong National University)
Kim, Jongmin (Department of Chemistry, Pukyong National University)
Jung, Young Hee (Research Laboratory, Mapro, Inc. Hanlim)
Kim, Yeong Il (Department of Chemistry, Pukyong National University)
Publication Information
Journal of the Korean Chemical Society / v.61, no.2, 2017 , pp. 57-64 More about this Journal
Abstract
Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.
Keywords
Monoclinic $VO_2$; Thermochromic; Semiconductor-to-metal phase transition; W/Mg-codoping; NIR switching efficiency;
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