• Title/Summary/Keyword: W.C.C.

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Physical Property of W-C-N Diffusion Barrier through Stress-Strain curve (Stress-Strain curve를 이용한 W-C-N 확산방지막 물성 특성 연구)

  • Lee, Kyu-Young;Kim, Soo-In;Park, Sang-Jae;Lee, Dong-Kwan;Jeong, Yong-Rok;Jung, Jun;Lee, Jong-Rim;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.20 no.4
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    • pp.266-270
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    • 2011
  • This paper suggest tungsten (W)-carbon (C)-nitrogen (N) thin films for diffusion barrier that W is main material and C and N are additives. W-C-N thin films are deposited with fixed rates of W and C but with a variation of $N_2$ gas flow and W-C-N thin films are heated at $600^{\circ}C$. From the experimental results, the variation of elastoplastic region for W-C-N thin film measured by tribological property is larger than that of elastic region with a variation of $N_2$ gas flow. These results show that the $N_2$ gas flow is more directly related with the elastoplastic region of W-C-N thin film. Nanoindenting test executed 16 times consecutively and we got the stress-strain curve graphs and hardness datas at each sample. Through the stress-strain curve graphs, the standard diviation of stress-strain curve for $N_2$ gas flow rate of 2.0 sccm is smaller than that of 0, 0.5, 1.5 sccm. Consequently, the physical stability of W-C-N thin film depends on the flow rate of $N_2$ gas.

Ohmic contact characteristics of polycrystalline 3C-SiC for high-temperature MEMS applications (초고온 MEMS용 다결정 3C-SiC의 Ohmic Contact 특성)

  • Chung, Gwiy-Sang;Ohn, Chang-Min
    • Journal of Sensor Science and Technology
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    • v.15 no.6
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    • pp.386-390
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    • 2006
  • This paper describes the ohmic contact formation of polycrystalline 3C-SiC films deposited on thermally grown Si wafers. In this work, a TiW (titanium tungsten) film as a contact material was deposited by RF magnetron sputter and annealed with the vacuum process. The specific contact resistance (${\rho}_{c}$) of the TiW contact was measured by using the C-TLM (circular transmission line method). The contact phase and interfacial reaction between TiW and 3C-SiC at high-temperature as also analyzed by XRD (X-ray diffraction) and SEM (scanning electron microscope). All of the samples didn't show cracks of the TiW film and any interfacial reaction after annealing. Especially, when the sample was annealed at $800^{\circ}$ for 30 min., the lowest contact resistivity of $2.90{\times}10{\Omega}cm^{2}$ was obtained due to the improved interfacial adhesion. Therefore, the good ohmic contact of polycrystalline 3C-SiC films using the TiW film is very suitable for high-temperature MEMS applications.

Effect of Metallic Binder Composition on Microstructure and Hardness of (W,Ti)C Cemented Carbides ((W,Ti)C계 초경합급의 미세조직 및 경도에 미치는 금속 결합재 조성의 영향)

  • Daoush, Walid M.;Lee, Kyong-H.;Park, Hee-S.;Jang, Jong-J.;Hong, Soon-H.
    • Journal of Powder Materials
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    • v.14 no.3 s.62
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    • pp.208-214
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    • 2007
  • The microstructure and hardness of (W,Ti)C cemented carbides with a different metallic binder composition of Ni and Co fabricated by powder technology were investigated. The densifications of the prepared materials were accomplished by using vacuum sintering at $1450^{\circ}C$. Nearly full dense (W,Ti)C cemented carbides were obtained with a relative density of up to 99.7% with 30 wt.% Co and 99.9% with 30 wt.% Ni as a metallic binder. The average grain size of the (W,Ti)C-Co and the (W,Ti)C-Ni was decreased by increasing the metallic binder content. The hardness of the dense (W,Ti)C-15 wt%Co and (W,Ti)C-15 wt%Ni, was greater than that of the other related cemented carbides; in addition, the cobalt-based cemented carbides had greater hardness values than the nickel-based cemented carbides.

Soil Analysis on Prediction of Consolidation Settlement in Marine Clays (항만점토(港灣粘土)의 압밀심하량(壓密沈下量) 예측(預測)을 위(爲)한 토질분석(土質分析))

  • Kwon, Moo Nam;Son, Kwang Sik;Lee, Sang Ho
    • Current Research on Agriculture and Life Sciences
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    • v.4
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    • pp.87-94
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    • 1986
  • This study was performed in order to contemplate their correlations between physical and mechanical properties of the marine clays which were collected from main harbors in Korea. The results obtained are as follows: 1. Most of the soils in experimental districts consist of CH. CL. and ML. and they are considered to be still proceeding. 2. The equations of the relationship between compression index and liquid limit are as, follows: CH : $C_c=0.0137$ (LL-22.60) CL : $C_c=0.0123$ (LL-14.64) 3. The relationship between compression index and initial void ratio appears that the higher the plasticity, the easier the slope of the regression line. The equations are as follows : CH : $C_c=0.431$ ($e_o-0.504$) CH : $C_c=0.471$ ($e_o-0.235$) ML : $C_c=0.641$ ($e_o-0.393$) 4. The equations of the relationship between compression index and natural water content are as follows: CH : $C_c=0.0133$ ($W_n-28.27$) CL : $C_c=0.0225$ ($W_n-23.56$) ML : $C_c=0.0106$ ($W_n-16.42$) 5. The relationship between initial void ratio and natural water content, and compression index is highly positive correlation and the equations are as follows : CH : $C_c=0.301$ ($e_o+0.017W_n-1.05$) CL : $C_c=0.141$ ($e_o+0.0567W_n-1.054$) ML : $C_c=0.421$ ($e_o+0.0214W_n-1.121$) 6. The equations of the relationship between initial void ratio and liquid limit, and compression index are as follows : CH : $C_c=0.36$ ($e_o+0.08LL-0.819$) CL : $C_c=0.269$ ($e_o+0.026LL-0.929$) 7. The cohesion of marine clays is no concerned with the increment of depth. The equations of relationship between cohesion and unconfined compression strength are as follows. CH : qu=1.896C+0.0107 CL : qu=1.849C+0.04.

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Manufacturing and Properties of Low Vacuum Plasma Sprayed W-Carbide Hybrid Coating Layer (진공 플라즈마 스프레이 공정을 이용한 W계 복합 코팅층의 제조 및 특성 연구)

  • Cho, Jin-Hyeon;Jin, Young-Min;Ahn, Jee-Hoon;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.226-237
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    • 2011
  • W-ZrC and W-HfC composite powders were fabricated by the Plasma Alloying & Spheroidization (PAS) method and the powders were sprayed into hybrid coating layers by using Low Vacuum Plasma Spray (LVPS) process, respectively. Microstructure, mechanical properties, and ablation characteristics of the fabricated coating layers were investigated. The LVPS process led to successful production of W-Carbide hybrid coatings, approximately 400 ${\mu}M$ or above in thickness. As the substrate preheating temperature increased from $870^{\circ}C$ to $917^{\circ}C$, the hardness of the W-ZrC coating layer increased due to decreased porosity. Vickers hardness showed higher value (about 108.4 HV) in W-ZrC hybrid coating material compared to that of W-HfC while adhesive strength was found to be similar in both coating layers. The plasma torch test revealed good ablation resistance of the W-Carbide hybrid coating layers. The relatively high performance W-ZrC coating layer at the elevated temperature is thought to be attributed to both the strengthening effect of ZrC particle remained in the layer and the formation of ZrO2 phase with high temperature stability.

Fabrication of ACtA/$SiC_w$ composite by squeeze casting (I) (용탕 단조법에 의한 AC4A/Si$C_w$복합재료 제조에 관한 연구 (I))

  • Moon, Kyung-Cheol;Lee, Jun-Hee
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.461-467
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    • 1992
  • A fabrication process for SiC whisker preform reinforced AC4A Al composites is being developed. The Al alloy used as the matrix in this study is AC4A. SiC whisker preform made by Tokai Carbon Co. Ltd. Shizuoka, Japan were used. These consisted of $\beta$-type single crystals 0.1 ~ 10${\mu}$m in diameter and 20~10${\mu}$m in length. The most adequate fabrication condition was that whisker preform was preheated up to 750~80$0^{\circ}C$, set into a mould preheated to ~40$0^{\circ}C$, molten Al alloy heated to ~80$0^{\circ}C$ and applied pressure 75MPa. And Si$C_w$reinforced AC4A composite was advanced above twice than AC4AI/M. Also it was not large effect by pressure at Si$C_w$ 20v/o.

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An Experimental Study on the Thermal Performance of the Flat Roof in Proportion to Directional Changes (평지붕의 방위별 열성능에 관한 실험적 연구)

  • 박병규;황하진;이경희
    • Journal of the Korean housing association
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    • v.12 no.2
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    • pp.191-198
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    • 2001
  • The aim of this research was to examine the thermal performance of the flat roof in proportion to various directional changes, the results of which were drawn from the miniature model experiment. In this process, various thermal environmental factors were measured and compared with one another to research their aspects of changes. The brief results of this research are as follows: 1) The indoor temperature and load per hour in proportion to directional changes shows the same degree of changes. As for the results of the clear-sky and cloudy-sky experiments, both of them generally appear advantageous in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, despite slight differences in the indoor temperature and load per hour in proportion to directional changes. 2) As for the total load of degree day per direction of the clear-sky and cloudy-sky experiments, both of them shows their advantageous results in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, despite minor differences in their loads. 3) As for the peak load of degree hour, while the clear-sky experiment shows its advantage in the order of $S-30^{\cire}C$-E, S, $-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, the cloudy-sky experiment does so in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, E, $S-60^{\cire}C$-W, $S-60^{\cire}C$-E.

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Fabrication of AC4A/$SiC_w$composite by squeeze casting(II) (용탕단조법에 의한 AC4A/$SiC_w$복합재교 제조에 관한 연구(ll)-가압력 및 시효특성-)

  • Mun, Gyeong-Cheol;Lee, Chun-Hui
    • Korean Journal of Materials Research
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    • v.3 no.6
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    • pp.606-613
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    • 1993
  • This was studied about aging characteristic of AC4A/$SiC_{w}$ 10-30v/o reinforced composite. Aging hardenability was decreased $SiC_{w}$ 30% > 10% > 20%. Aging hardening of T6 treatmented composite was higher absolute value than AC4A I/M material. And this results indicated initial hardening phenomenon according to increase $SiC_{w}$ volume fraction. Reinforced effect by pressure was the same effect as before aging treatment and the best condition pressure at 75MPa. Similar to reinforced effect according to $SiC_{w}$ volume fraction was 30 % > 10 % > 20 %. In case of pressure is low, whisker is not break the same time press with base metal after wetting. After it is wetting with base metal, a part transformed or wetting part break and whisker maintain original shape or a part transformed on the otherhand, in case of pressure is high, whisker is break in same time it was not against pressure and whisker's shape is near a polygon or spherical shape.

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Characterization of Oil Degrading Bacterium Pseudomonas sp. BCK-1 Isolated from the Coastal Water of Yosu, Korea (여수주변해역에서 분리한 유류분해세균 Pseudomonas sp. BCK-1의 특성)

  • KOO Hoen-Seo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.2
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    • pp.145-150
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    • 2001
  • A marine bacterium having a high oil-degrading activity was isolated from the coastal water of Yosu, Korea, identified as Pseudomonas sp. and named Pseudomonas sp. BCK-1. The optimal temperature, pH and NaCl concentration for cell growth was $30^{\circ}C$, 7.0 and $3\%$ (w/v), respectively. After cultivation at $30^{\circ}C$, 180 rpm in 250 mL erlenmeyer flask for 72 and 168 hours, $2\%$ (w/v) arabian light crude oil (ACO) and bunker C oil (BCO) which are considered to be hardly biodegradable compounds were degraded $92\%$ (w/w) and $72\%$ (w/w), respectively.

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Study on the Characteristics of Conduction Heat Transfer According to the Heating Temperature of a Composite Wall in a Light-weight Partition (경량칸막이 복합벽체의 가열온도에 따른 전도 열전달 특성 연구)

  • Park, Sang-Min;Choi, Su-Gil;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.60-68
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    • 2019
  • The paper reports the characteristics of conduction heat transfer to the backside part according to the heating temperature of a composite wall in a lightweight partition used for indoor space compartments. Stud partitions, SGP partitions, sandwich panels, urethane foam panels, and glass wool panels. which are generally used as light-weight partition walls, were selected as experiment samples, and the characteristics of conduction heat transfer to the backside part as the top surface were analyzed by applying heating temperatures of $200^{\circ}C$, $300^{\circ}C$, $400^{\circ}C$, and $500^{\circ}C$ to the bottom surface for 1800 s. According to the experimental results, the maximum backside temperatures at the maximum heating temperature of $500^{\circ}C$ was $51.6^{\circ}C$, $63.6^{\circ}C$, $317.2^{\circ}C$, $124.9^{\circ}C$, and $42.2^{\circ}C$ for the stud partition, SGP partition, sandwich panel, urethane foam panel, and glass wool panel, respectively. The maximum conduction heat- transfer rates at $500^{\circ}C$ were 17.16 W, 18.39 W, 136.65 W, 14.34 W, and 5.57 W for the stud partition, SGP partition, sandwich panel, urethane foam, and glass wool panel, respectively.