• Carbon letters
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• v.12 no.4
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• pp.236-242
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• 2011

The oxyfluorination effects of activated carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Electrospun CFs were prepared from a polyacrylonitrile/N,N-dimethylformamide solution via electrospinning and heat treatment. The electrospun CFs were chemically activated in order to generate the pore structure, and then oxyfluorination was used to modify the surface. The samples were labeled CF (electrospun CF), ACF (activated CF), OFACF-1 ($O_2:F_2$ = 7:3), OFACF-2 ($O_2:F_2$ = 5:5) and OFACF-3 ($O_2:F_2$ = 3:7). The functional group of OFACFs was investigated using X-ray photoelectron spectroscopy analysis. The C-F bonds formed on surface of ACFs. The intensities of the C-O peaks increased after oxyfluorination and increased the oxygen content in the reaction gas. The specific surface area, pore volume and pore size of OFACFs were calculated by the Brunauer-Emmett-Teller and density functional theory equation. Through the $N_2$ adsorption isotherm, the specific surface area and pore volume slightly decreased as a result of oxyfluorination treatment. Nevertheless, the $CO_2$ adsorption efficiency of oxyfluorinated ACF improved around 16 wt% due to the semi-ionic interaction effect of surface modificated oxygen functional groups and $CO_2$ molecules.

• Journal of Ocean Engineering and Technology
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• v.26 no.6
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• pp.7-13
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• 2012

This paper presents a numerical study of the wave loads acting on offshore structures using a Cartesian-grid-based flow simulation method. Finite volume discretization with a volume-of-fluid (VOF) method is adopted to solve two-phase Navier-Stokes equations. Among the many variations of the VOF method, the CICSAM scheme is applied. The body boundary conditions are satisfied using a porosity function, and wave generation is carried out by using transient (wave or damping) zone approaches. In order to validate the present numerical method, three different basic offshore structures, including a sphere, Pinkster barge, and Wigley model, are numerically investigated. First, diffraction and radiation problems are solved using the present numerical method. The wave exciting and drift forces from the diffraction problems are compared with potential-based solutions. The added mass and wave damping forces from the radiation problems are also compared with the potential results. Next, the wave-induced motion responses of the structures are calculated and compared with the existing experimental data. The comparison results are fairly good, showing the validity of the present numerical method.

• Imaging Science in Dentistry
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• v.52 no.3
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• pp.303-308
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• 2022

Purpose: This technical report aims to describe and detail the use of micro-computed tomography for a reliable evaluation of the bulk-fill composite/tooth interface. Materials and Methods: Bulk-fill composite restorations in tooth cavities were scanned using micro-computed tomography to obtain qualitatively and quantitatively valuable information. Two-dimensional information was processed using specific algorithms, and ultimately a 3-dimensional (3D) specimen reconstruction was generated. The 3D rendering allowed the visualization of voids inside bulk-fill composite materials and provided quantitative measurements. The 3D analysis software VG Studio MAX was used to perform image analysis and assess gap formation within the tooth-restoration interface. In particular, to evaluate internal adaptation, the Defect Analysis addon module of VG Studio Max was used. Results: The data, obtained with the processing software, highlighted the presence and the shape of gaps in different colours, representing the volume of porosity within a chromatic scale in which each colour quantitatively represents a well-defined volume. Conclusion: Micro-computed tomography makes it possible to obtain several quantitative parameters, providing fundamental information on defect shape and complexity. However, this technique has the limit of not discriminating materials without radiopacity and with low or no filler content, such as dental adhesives, and hence, they are difficult to visualise through software reconstruction.

• Structural Engineering and Mechanics
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• v.88 no.1
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• pp.1-12
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• 2023

In this study, forced vibration behavior of a piezo magneto electric sandwich Timoshenko beam is investigated. It is assumed a sandwich beam with porous core and graphene platelet reinforced composite (GPLRC) in facesheets subjected to magneto-electro-elastic and temperature-dependent material properties. The magneto electro platelets are under linear function along with the thickness that includes a cosine function and magnetic and electric constant potentials. The governing equations of motion are derived using modified strain gradient theory for microstructures. The effects of material length scale parameters, temperature change, different distributions of porous, various patterns of graphene platelets, and the core to face sheets thickness ratio on the natural frequency and excited frequency of a sandwich Timoshenko beam are scrutinized. Various size-dependent methods effects such as MSGT, MCST, and CT on the natural frequency is considered. Moreover, the final results affirm that the increase in porosity coefficient and volume fractions lead to an increase in the amount of natural frequency; while vice versa for the increment in the aspect ratio. From forced vibration analysis, it is understood that by increasing the values of volume fraction and the length thickness of GPL, the maximum deflection of a sandwich beam decreases. Also, it is concluded that increasing the temperature, the thickness of GPL, and the initial force leads to a decrease in the maximum deflection of GPL. It is also shown that resonance phenomenon occurs when the natural and excitation frequencies become equal to each other. Outcomes also reveal that the third natural frequency owns the minimum value of both deflection and frequency ratio and the first natural frequency has the maximum.

• Carbon letters
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• v.12 no.3
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• pp.171-176
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• 2011

Polyacrylonitrile-based carbon nanofibers (CNFs) containing Ti and Mn were prepared by electrospinning. The effect of metal content on the hydrogen storage capacity of the nanofibers was evaluated. The nanofibers containing Ti and Mn exhibited maximum hydrogen adsorption capacities of 1.6 and 1.1 wt%, respectively, at 303 K and 9 MPa. Toward the development of an improved hydrogen storage system, the optimum conditions for the production of metalized CNFs were investigated by characterizing the specific surface areas, pore volumes, sizes, and shapes of the fibers. According to the results of Brunauer-Emmett-Teller analysis, the activation of the CNFs using potassium hydroxide resulted in a large pore volume and specific surface area in the samples. This is attributable to the optimized pore structure of the metal-containing polyacrylonitrile-based electrospun CNFs, which may provide better sites for hydrogen adsorption than do current adsorbates.

• Journal of the Korea Institute of Military Science and Technology
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• v.23 no.5
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• pp.435-443
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• 2020

Thermal barrier coating(TBC) applied to fighter and turbine engines is a technology that improves the durability of core parts by lowering the surface temperature of base material. The thermal stress caused by mis-match of the coefficient of thermal expansion between the top coating and the TGO interface is the main cause of TBC breakage. Since the thermal stress is dependent on the microstructure of the TBC, designing microstructure of TBC can improve the durability as well as lower the thermal stress. In this study, the effect of coating thickness, volume of porosity and vertical cracking on the thermal stress was analyzed through finite element analysis. Through the analysis results, a design range of a microstructure that can improve the durability of thermal barrier coating by lowering thermal stress is proposed.

• Computers and Concrete
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• v.2 no.3
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• pp.189-202
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• 2005

This paper presents an analysis of some experimental results concerning micro-structural tests, permeability measurements and strain-stress tests of four types of High-Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$). These experimental results, obtained within the "HITECO" research programme are discussed and interpreted in the context of a recently developed mathematical model of hygro-thermal behaviour and degradation of concrete at high temperature, which is briefly presented in the Part 2 paper (Gawin, et al. 2005). Correlations between concrete permeability and porosity micro-structure, as well as between damage and cracks' volume, are found. An approximate decomposition of the thermally induced material damage into two parts, a chemical one related to cement dehydration process, and a thermal one due to micro-cracks' development caused by thermal strains at micro- and meso-scale, is performed. Constitutive relationships describing influence of temperature and material damage upon its intrinsic permeability at high temperature for 4 types of HPC are deduced. In the Part II of this paper (Gawin, et al. 2005) effect of two different damage-permeability coupling formulations on the results of computer simulations concerning hygro-thermo-mechanical performance of concrete wall during standard fire, is numerically analysed.

• Computers and Concrete
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• v.20 no.2
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• pp.119-127
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• 2017

Time-dependent buckling of embedded straight concrete columns armed with Silicon dioxide($SiO_2$) nano-particles exposed to fire is investigated in the present study for the fire time. The column is simulated mathematically with Timoshenko beam model. The governing mass conservation equations to describe heat and moisture transport in concrete containing free water, water vapor, and dry air in conjunction with the conversion of energy are considered. The characteristics of the equivalent composite are determined using Mori-Tanaka approach. The foundation around the column is simulated with spring and shear layer. Employing nonlinear strains-displacements, energy methods and Hamilton's principal, the governing equations are derived. Differential quadrature method (DQM) is used in order to obtain the critical buckling load and critical buckling time of structure. The influences of volume percent of $SiO_2nano-particles$, geometrical parameters, elastic foundation and concrete porosity are investigated on the time-dependent buckling behaviours of structure. Numerical results indicate that reinforcing the concrete column with $SiO_2nano-particles$, the structure becomes stiffer and the critical buckling load and time increase.

• Steel and Composite Structures
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• v.27 no.1
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• pp.109-122
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• 2018

In This work an analysis of the propagation of waves of functionally graduated plates is presented by using a high order hyperbolic (HSDT) shear deformation theory. This theory has only four variables, which is less than the theory of first order shear deformation (FSDT). Therefore, a shear correction coefficient is not required. Unlike other conventional shear deformation theories, the present work includes a new field of displacement which introduces indeterminate integral variables. The properties of materials are supposed classified in the direction of the thickness according to two simple distributions of a power law in terms of volume fractions of constituents. The governing equations of the wave propagation in the functionally graded plate are derived by employing the Hamilton's principle. The analytical dispersion relation of the functionally graded plate is obtained by solving an eigenvalue problem. The convergence and the validation of the proposed theoretical numerical model are performed to demonstrate the efficacy of the model.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.393-400
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• 1996

The conducting polymer composites were prepared by imbibing the porous particle with an $FeCl_3$ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore. The conductivity of the porous composite particles, was higher than that of nonporous particles. Also, the conductivity of composite was increased with increasing specific surface area and pore specific volume of the host porous particles since the degree of formation of conducting polymer in the pore increased.