• Title/Summary/Keyword: Volatile compound

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Test Method Using VOC Analyzer to Measure VOC Emission of Paints for Wood-based Panel (VOC Analyzer를 이용한 목재용 도료의 휘발성유기화합물의 간이측정)

  • Eom, Young Geun;Kim, Ki-Wook;An, Jae-Yun;Kim, Hyun-Joong;Moon, Suck-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.65-72
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    • 2007
  • The VOC (volatile organic compound) analyzer is devised to measure the four main aromatic hydrocarbon gases: toluene, ethylbenzene, xylene and styfene. It is not affected by ambient temperature and humidity. In addition, standby and measuring time of VOC Analyzer is a short as below 30 min and 8 min, respectively. Since the semiconductor gas sensor is supersensitive to gas components, it is not necessary to use a conventional gas concentrator or other complicated equipment. In this study, VOC emission behavior from 4 types paints (lacquer, urethane vanish, water-base paint, enamel paint) for wood-based panel was investigated using VOC Analyzer. After a specimen was spreaded on aluminum foil ($6.32{\times}6.32cm$) in $3{\ell}$ polyester bag, after 24 hours we could measure maximum VOC emission level that is a stabilized VOC value. Xylene of VOCs was high emitted from lacquer, urethane vanish and water-based paint, and TVOC (Toluene + Ethylbenzene + Xylene + Styrene) of lacquer was the highest emission concentration than another.

Effects of Additives on the Quality Improvement of Minced Ginger (Zingiber officinale Roscoe) During Storage (생강(Zingiber officinale Roscoe) 다대기의 저장 중 품질개선을 위한 첨가물 효과)

  • Lee, Myung-Hee;Lee, Kyoung-Hae;Cho, Chang-Won;Kim, Kyung-Tack
    • Journal of Food Hygiene and Safety
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    • v.25 no.1
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    • pp.59-64
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    • 2010
  • The effects of vinegar, alcohol and ascorbic acid on the color, microorganism, sensory properties and flavor pattern of minced ginger (MG) were investigated during storage for 28 days at $30^{\circ}C$. The values of L (lightness), a (redness) and b (yellowness) of the control (T-0) and all the treatments changed slightly at the initial stage of storage, however the elapse of time accelerated the changes. The total bacterial counts of T-0 showed $5.37{\times}10^7\;CFU/g$ at the initial stage, but the MG-treatments decreased the bacteria above 4 log compared to T-0. It was showed that the additives were effective for inhibition of the growth of microorganism. Sensory properties of flavor intensity test showed no significant difference between T-0 and MG-treatments (p < 0.05). The result of volatile flavor contents of electronic nose analyzer (ENZ) showed that MG-treatments (T-I, T-II, T-III) was recognized stronger than non-treatment at the initial stage, but the change of flavor compound were stabilized soon regardless of type or quantity of additives during total storage period at $30^{\circ}C$.

Effect of Natural Antimicrobial Extracts on Shelf-life Extension and Quality Improvement of the Flounder Sikhe (천연 항균 추출물의 첨가가 가자미 식해의 품질 및 저장성에 미치는 영향)

  • Han, Ho Jun;Kim, Deog Gi;Han, Dae Won;Cho, Soon Yeong
    • Korean Journal of Food Science and Technology
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    • v.46 no.6
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    • pp.689-693
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    • 2014
  • Flounder sikhe is one of the traditional Korean fermented foods. Because honey, fucoidan, propolis, aronia berry, and horseradish are well known to have natural antimicrobial properties, we investigated their antimicrobial effects on improving the quality of flounder sikhe. Ethanol extracts of propolis inhibited the growth of Bacillus cereus, Staphylococcus aureus, and Listeria monocytogenes. The extracts of aronia berry showed similar effects against Salmonella Typhimurium. We also assessed the total polyphenol and total flavonoid content and 2,2-diphenyl-2-picrythydrazyl (DPPH) radical scavenging activity in the extracts obtained from these natural materials. The contents of polyphenols and flavonoids were the highest in propolis, which also showed a high DPPH radical scavenging activity. Therefore, addition of propolis 0.5% to flounder sikhe showed optimal improvement, with a storage stability of 15 days at pH 5.39, volatile basic nitrogen (VBN) content at 24.73 mg/100 g, and total bacterial count at $1.81{\times}10$ colony forming unit (CFU)/g.

Characteristics of Fermentation and Aging by Different Adding of Brewing Water in Korean Traditional Cheongju (가수량을 달리한 전통 청주의 발효 및 숙성 특성 연구)

  • Moon, Jin-Seok;Kong, Tae-In;Cheong, Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.8
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    • pp.5468-5475
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    • 2015
  • This present work was aimed to analyse characteristics of fermentation and aging of Korean traditional cheongju prepared by adding of different brewing water. The three different mashes were used for fermentation and maturation. The cheongju(A) was prepared without adding of brewing water in two stage mashing. Cheongju(B) and cheongju(C) were made with adding of 1 liter and 2 liter brewing water in two stage mashing respectively whereas the cheongju(B) and cheongju(C) showed higher fermentation ability than that of cheongju(A) regarding to pH, ethanol, specific gravity and sugar concentration(brix). In terms of volatile compounds content after six months aging, cheongju(A and B) prepared by adding brewing water showed the higher content of ethyl acetate than that of cheong(C) and the concentrations were maintained during the aging period. In addition, the content of fusel oil(n-propanol, i-butanol, n-butanol, i-bmyl alcohol, n-bmyl alcohol)indicated similar pattern as ethyl acetate. The organic acid of cheongju B(4873.46 mg/l) and C(4963.12 mg/l) also indicated the higher content than that of cheongju A(4661.47 mg/l). In conclusion, cheongju B and C prepared by adding brewing water in two stage mashing showed better quality and taste than that of cheongju A.

Human Health Risk Assessment of Benzene from Industrial Complexes of Chungcheong and Jeonla Province (충청·전라지역 산업단지 주변지역에서의 벤젠 인체 위해성 평가)

  • Jang, Yong-Chul;Lee, Sungwoo;Shin, YongSeung;Kim, Heekap;Lee, Jonghyun
    • Journal of Environmental Impact Assessment
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    • v.20 no.4
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    • pp.497-507
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    • 2011
  • This research studied human health risk assessment of benzene from industrial complexes of Chungcheong Province (Seosan industrial complex) and Jeonla Province (Iksan industrial complex and Yeosoo industrial complex). The residents near the industrial complexes areas can be often exposed to volatile organic compounds (e.g., benzene, toluene, xylenes) through a number of exposure pathways, including inhalation of the organic pollutant via various environmental matrices (air, water and soil), contaminated water, and soil intake. Benzene is well known to be a common carcinogenic and toxic compound that is produced from industrial and oil refinery complexes. In this study, a number of samples from water, air, and soil were taken from the residential settings and public school zones located near the industrial complex sites. Based on the carcinogenic risk assessment, the risk estimates were slightly above $10{\times}10^{-6}$ at all three industrial sites. According to deterministic risk assessment, inhalation was the most important route. The distribution of benzene in the environment would be dependent on vapor pressure, and the physical property influencing the extent of the potential risks. Non-carcinogenic risk assessment of benzene shows that the values of Hazard Index(HI) were much lower than 1.0 at all industrial complexes. Therefore, benzene was not a cause of concern in terms of non-carcinogenic risk posed to the residents near the sites. When compared to probabilistic risk assessment, the CTE(central tendency exposure) cancer risk values of deterministic risk assessment were close to the mean values predicted by the probabilistic risk assessment. The RME(reasonable maximum exposure) values fell within the range of 95% to 99.9% estimated by the probabilistic risk assessment. Since the values of carcinogenic risk assessment were higher than $10{\times}10^{-6}$, further detailed monitoring and refined risk assessment for benzene may be warranted to estimate more reliable and potential inhalation risks to receptors near the industrial complexes.

Biofilter Model for Robust Biofilter Design: 2. Dynamic Biofilter Model (강인한 바이오필터설계를 위한 바이오필터모델: 2. 동적 바이오필터모델)

  • Lee, Eun Ju;Song, Hae Jin;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.155-161
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    • 2012
  • A dynamic biofilter model was suggested to integrate the effect of biofilter-medium adsorption capacity on the removal efficiency of volatile organic compound (VOC) contained in waste air. In particular, the suggested biofilter model is composed of four components such as biofilm, gas phase, sorption volume and adsorption phase and is capable of predicting the unsteady behavior of biofilter-operation. The process-lumping model previously suggested was limited in the application for the treatment of waste air since it was derived under the assumption that the adsorbed amount of VOC equilibrated with biofilter-media would be proportional to the concentration of dissolved VOC in the sorption volume of biofilter-media. Therefore a Freundlich adsorption isotherm was integrated into a robust biofilter process-lumping model applicable to a wide range of VOC concentration. The values of model parameters related to biofilter-medium adsorption were obtained from the dynamic adsorption column experiments in the preceding article and literature survey. Furthermore a separate biofilter experiment was conducted to treat waste air containing ethanol and the experimental result was compared with the model predictions with various values of Thiele modulus (${\phi}$). The obtained value of Thiele modulus (${\phi}$) was close to 0.03.

Physiological Characteristics of Actinomycetes Isolated from Turfgrass Rhizosphere (잔디 근권에서 분리된 Actinomycetes균주의 생리학적 특성)

  • Lee, Jung Han;Min, Gyu Young;Shim, Gyu Yul;Jeon, Chang Wook;Kwak, Youn-Sig
    • Weed & Turfgrass Science
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    • v.4 no.4
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    • pp.348-359
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    • 2015
  • Total 443 isolates of actinomycetes were isolated from turfgrass rhizosphere as potential biological control agents. The two isolates (S11 and S4) showed highest cellulase activity with compared to the other isolates that exhibited a clear zone of 1.2 mm around the colony on cellulose agar medium. S12 strain appeared the most active chitin degrading, which exhibited a 1.2 mm of clear zone. The highest proteolytic activity on skim milk agar was which exhibited a 7.5 mm of clear zone by S2 strain. S1 strain from the soli showed siderophore production ability, which exhibited a 0.6 mm of large clear zone on chrome azurol S agar. The antifungal activity of the volatile compound producing by 4 selected actinomycetes was investigated that inhibition rate against Rhizoctonia solani AG2-2 and Sclerotinia homoeocarpa. Growth inhibition effect of S8 isolate against S. homoeocarpa was appeared to 94.8%, S2 to 76.9%, S5 to 46.1% and S12 to 43.5%. The significant inhibition effects on mycelial growth of S. homoeocarpa were shown on media with four strains. The inhibition effect was the highest with S8 strain treatment at 94.8%.

Bioactive Foam Reactors for the Enhanced Biological Degradation of Toluene (계면활성제 거품을 이용한 미생물반응기에서의 기체상 톨루엔 분해)

  • Kim, Yong-Sik;Son, Young-Kyu;Khim, Jee-Hyung;Song, Ji-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.468-475
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    • 2005
  • Biofilters packed with various materials have emerged as a sustainable technology for the treatment of volatile organic compounds (VOCs); however, problems including low performance and clogging are commonly encountered. Recently, a bioactive foam reactor (BFR) using surfactants has been suggested to ensure efficient and stable VOCs removal performance. This study was mainly conducted to investigate the feasibility of BFRs using toluene as a model compound. Prior to bioreactor studies, a series of bottle tests were used to select a suitable surfactant for the BFR application. Experimental results of the batch bottle tests indicated that TritonX-100 was the most appropriate one among the surfactants tested, since it showed a minimal effect on the toluene biodegradation rate while the other surfactants lowered the toluene biodegradation rate significantly. Using the selected surfactant, the BFR performance was determined by changing operating parameters including gas residence time and toluene loading. As the gas residence time increased from 0.5 minutes to 2 minutes, the toluene removal efficiency increased from approximately 50% to 80%. In addition, an increase of the toluene loading from $38\;g/m^3/hr$ to $454\;g/m^3/hr$ resulted in a decrease of toluene removal efficiency from approximately 70% to 20%. The BFR had a maximum elimination capacity of $108\;g/m^3/hr$ for toluene, which was much higher than those generally reported in the literature. The high toluene-elimination performance indicates that the BFR be a potential alternative to the conventional, packed-type biofilters. However, the limitation of toluene solubilization and foam stability at either high or low gas flow rate are still problems to be challenged.

Analyses of Essential Oil and Headspace Compositions of Capsella bursa-pastoris Medicus by SDE and SPME Methods (SDE 및 SPME에 의한 냉이(Capsella bursa-pastoris Medicus)정유 및 Headspace 성분 분석)

  • Choi Hyang-Sook;Kang Eun-Jin;Kim Kun-Hee
    • Food Science and Preservation
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    • v.13 no.1
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    • pp.108-114
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    • 2006
  • This study was conducted to determine the volatile flavor compositions of the essential oil and the headspace of Capsella bursa-pastoris Medicus. Essential oil and headspace from the plant were extracted by simultaneous steam distillation extraction (SDE), and solid-phase microextraction(SPME) methods, respectively. Seventy-two compounds including 28 hydrocarbons, 4 aldehydes, 6 ketones, 16 alcohols, 4 esters, 8 acids, and 6 miscellaneous ones were identified in the leaf essential oil extracted by SDE method Sixty-eight compounds including 26 hydrocarbons, 2 aldehydes, 6 ketones, 17 alcohols, 4 esters, 6 acids, and 7 miscellaneous ones were identified in the root essential oil. According to the instrumental analyses the essential oil, phytol ($21.12\%$ in leaves, $20.94\%$ in roots) was the most abundant compound Alcohols, esters, and acids were main groups of the essential oil. On the other hand, thirty-eight compounds including 18 hydrocarbons, 3 aldehydes, 3 ketones, 9 alcohols, 2 esters, 3 miscellaneous ones were identified in the leaf headspace by SPME. In root headspace, thirty-three compounds including 16 hydrocarbons, 2 aldehydes, 1 ketone, 9 alcohols, 3 esten;, and 2 miscellaneous ones were identified. Hydrocarbons($44.02\%$ in leaves, $56.98\%$ in roots) were the main components of the headspace of Capsella bursa-pastoris Medicus.

Comparison of Active Ingredients between Field Grown and In Vitro Cultured Rhizome of Korean Native Ginger (Zingiber officinale Roscoe) (조직배양생강과 한국재래종 생강의 유효성분 비교)

  • Jo, Man-Hyun;Ham, In-Ki;Lee, Gyu-Hee;Lee, Jong-Kug;Lee, Ga-Soon;Park, Sang-Kyu;Kim, Tae-Il;Lee, Eun-Mo
    • Korean Journal of Plant Resources
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    • v.24 no.4
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    • pp.404-412
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    • 2011
  • This study was carried out to compare and analyze the active ingredients of Korean native ginger and rhizome derived from in vitro shoot-tip culture of Korean native ginger. Proximate compositions, mineral nutrients, free sugars, fatty acids, volatile components, 6-gingerol, and 6-shogaol were analysed and evaluated. Korean native ginger was proved to have a little more contents than in vitro rhizome in proximate compositions (crude ash, crude lipid, crude protein, carbohydrate). Mineral nutrient contents (Cu, Fe, Mn, Zn) of in vitro rhizome were higher than those of Korean native ginger. Among the mineral nutrients, the quantity of K was the highest, followed by P, Mg, Na, and Ca. Free sugar contents (fructose, glucose, sucrose) of in vitro rhizome were higher than those of Korean native ginger. Fatty acids containing less than C14 was the major among the fatty acids in ginger. Citral ingredient of the unique aromatic compound of Korean native ginger was stronger than that of the rhizome derived from in vitro shoot-tip culture. Gingerol concentration was increased by shoot-tip culture.