• Title/Summary/Keyword: Volatile Organic compounds

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Adsorption and Removal of Volatile Organic Compounds from Fabrics with β-Cyclodextrin Finish (직물의 β-cyclodextrin 가공에 따른 휘발성 유기성분의 흡착과 제거)

  • Chung, Haewon;Hwang, Nawon;Kim, Joo-Yeon;Shin, Seung-Yeop
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.1
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    • pp.113-123
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    • 2013
  • Clothes that retain and emanate body odor feel uncomfortable and unclean; subsequently, the adsorption, desorption and removal amounts of malodorous compounds from fabrics with different polarities were examined. 1-Octen-3-one, octanal and isovaleric acid, which are important malodor compounds from the body, were used as volatile organic compounds (VOC). Samples were prepared with unfinished and ${\beta}$-CD finished cotton, nylon and PET fabrics. The amounts of VOCs retained on the fabrics were measured using headspace GC-MS; in addition, the odor intensity of the samples were evaluated by 10 trained panelists. The amounts adsorbed were estimated by weight gain; however, moisture was found to have a larger effect on the increase in weight than VOCs. The polarity of the VOCs decreased in the order of isovaleric acid, octanal and 1-octen-3-one. Despite the exceptionally large amounts of octanal adsorbed on the nylon sample, the amounts of malodorous compounds adsorbed on fabrics increased with the decreasing VOC molecular weight. The unfinished PET sample adsorbed more VOCs than the unfinished-fabric samples. The odor intensity was mostly weaker in the ${\beta}$-CD finished fabrics than in the unfinished fabrics. The odor intensity of the ${\beta}$-CD finished fabrics was lower than unfinished fabrics. The amount of VOCs that remained on the soiled fabric samples after storing in air for 24 hrs decreased with the increasing VOC vapor pressure. Most VOCs were removed by washing; however, more VOCs were left on the ${\beta}$-CD finished fabrics than unfinished fabrics. The intensity of the odor from the unfinished PET and ${\beta}$-CD finished fabrics was stronger and weaker, respectively, than that of other fabrics, even when the same amounts of VOCs remained.

Alcohols and Volatile Organic Acids as Stimulants of Rhizomorph Production by Armillaria mellea (알코올 및 휘발성 유기산류가 뽕나무버섯의 균사속 생산에 미치는 영향)

  • Hong, Jai-Sik;Kim, Myung-Kon;Lee, Jai-Hong;Kim, Hyung-Moo
    • The Korean Journal of Mycology
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    • v.18 no.3
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    • pp.158-163
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    • 1990
  • To investigate symbiotic relationship of 'Chunma (Gastrodia elata) and the rhizomorph of Armillaria mellea, volatile organic acids and alcoholic compounds which were considered to be contained in Gastrodia elata were tested to determine stimulatory effects on rhizomorph growth on a chemically defined medium. Also, volatile organic acids were isolated from Gastrodia elata and analyzed by gas chromatography. The growth of rhizomorph was stimulated by the presence of alcohols and volatile organic acids, but acetic acid and methanol were ineffective. In the presence of valeric acid and ethanol, Armillaria mellea produced abundant rhizomorph at concentrations of 0.1 and 1%, respectively. Ethanol and valeric acid supplemented at regular intervals of 3 days as lower concentrations in the medium stimulated the growth of Armillaria mellea. The concentrations of ethanol and valeric acid as low at 0.01% added 3 days intervals for 15 days were more effective than initial concentrations of 0.1 and 1% in stimulating rhizomorph development of Armillaria mellea. Eight kinds of volatile organic acids were identified and quantified by gas chromatography. The major compounds were n-propionic, valeric, iso-carproic and caproic acids, and the minor compounds were iso-butyric, butyric, iso-valeric and hepatanoic acids. Valeric acid was the most abundant among them.

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Distribution characteristics on volatile organic compounds at the forest of Mt. mudeung and downtown (무등산 숲과 도심에서 휘발성유기화합물질의 분포 특성)

  • Lee, Dae-haeng;Park, Kang-soo;Lee, Se-hang;Song, Hyeong-myeong;Lee, Ki-won;Jeong, Hee-yoon;Seo, Gwang-yeob;Cho, Young-gwan;Kim, Eun-sun
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.246-254
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    • 2015
  • From 2013 to 2014, volatile organic compounds (VOCs) were analyzed to determine biogenic volatile organic compounds (BVOCs) and anthropogenic volatile organic compounds (AVOCs) at eight sites in Mt. Mudeung and one site in downtown, by using a GC/Mass-ATD (automatic thermal desorber). The concentration of terpene noted as biogenic volatile organic compounds at Pungamjeong (PA), in a forest of Chamaecyparis obtusa, was 821 pptv, which was the highest among the eight sites. This value was followed by Wonhyogyegok (WH: 785 pptv), Norritzae (NZ, coniferous forest: 679 pptv), Dongjeokgol (DJ, mixed species forest: 513 pptv), Jangbuljae (JB, Abies koreana: 476 pptv), and Seinbongsamgerri (SS, pine trees: 464 pptv). 11~15 species of terpene was detected in the forest depending on the site. At PA in May, α-pinene showed the highest value, occupied 20% of terpene followed by coumarin, sabinene, phellandrene, myrcene, borneol, eucalyptol, β-pinene, cymene, δ-limonene, γ-terpinene, camphor, camphene, and mentol in the order. The mean concentrations of AVOCs were 0.74~2.52 ppbv in the forests and 3.14 ppbv in the downtown area. From May to July, the AVOCs ratios of the downtown to each forest were 1.9~4.0. Among 10 species of AVOCs, the sum of toluene and benzene was 2.34 ppbv and occupied 75%. In June, the ratios of toluene were 44.1% at DJ site and 53.1% at JW site (downtown). The BVOCs showed a positive correlation with the AVOCs at the forest sites (r = 0.328), which was statistically insignificant (p = 0.184).

Promises and Risks of Unsaturated Volatile Organic Compounds: Limonene, Pinene, and Isoprene

  • Jin, Kyong-Suk;Jun, Mi-Ra;Park, Min-Ji;Ok, Seon;Jeong, Jae-Han;Kang, Hye-Sook;Jo, Wan-Keun;Lim, Ho-Jin;Jeong, Woo-Sik
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.447-456
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    • 2008
  • Limonene, pinene, and isoprene are abundant and ubiquitous volatile organic compounds (VOCs) which are found in various natural products and also produced from various manufacture processes. Limonene and pinene are major components of food additives and household products for enrichment of good flavors and elimination of malodors, and isoprene is a basal motif of monoterpenes such as limonene and pinene. They have shown many beneficial effects such as chemopreventive, chemotherapeutic, and antioxidant activities. Upon certain conditions, however, adverse effects of these compounds on human health have also been reported. Although they do not seem to have acute and severe toxicity to human, they can easily generate secondary organic aerosols (SOAs) when they react with oxygen and/or ozone, which have shown certain toxic effects on experimental animal models as well as on humans. Numerous household and scented products containing limonene, pinene, and isoprene are widely used in these days. However, biological consequences upon exposure to these products are largely unknown. The aim of this review is to summarize and analyze the current understanding on the biological effects of VOCs, in particular limonene, pinene, and isoprene, as well as their SOAs.

Genotoxic Effects of Volatile Organic Compounds in Water (물속 휘발성 유기화합물이 염색체 돌연변이에 미치는 영향)

  • Jung Kyu Saeng;Lee Chae Yang;Shin Heuyn Kil;Lee Ki Nam;Jeung Jae Yeal;Lee Jong Young
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.5
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    • pp.899-904
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    • 2002
  • For determination of the genotoxicity of VOCs(Volatile Organic Compounds) in water, in vitro Comet assay was performed using 3T3 cells. The selected 5 VOCs; Trichloroethylene(TCE), Tetrachloroethylene(PCE), Carbontetrachloride (CteC), Dichloromethane(DCM) and Chlorofrom(Chl) and mixed solvent(Mix), are the test items for drinking water quality. Author analyzed the genotoxicity of these solvents through their tail length (TL) values. Mix, PCE, Chl, TCE in order had cytotoxicity at the highest concentration, and CCl₄ and DCM had no cytotoxic effect. TCE, CCl₄, Chl, PCE, Mix, DCM had genotoxicity, Chl, PCE, Mix had both cytotoxicity and genotoxicity simultaneously, Cytotoxic effect of mixed organic solvents, compared with that of single component, at each concentration, was influenced by the synergistic effect of the interaction of each organic component.

Characterization of Volatile Organic Compounds concentrations in the ambient air of the Kumi industrial complex (구미산업단지 대기중 휘발성유기화합물(VOCs)의 농도특성)

  • Choe, U Geon;Bae, Sang Ho;Park, Deok Sin;Jeong, Yeon Gu;Kim, Tae O
    • Journal of Environmental Science International
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    • v.13 no.3
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    • pp.205-214
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    • 2004
  • This study focuses on the measurement of airborne Volatile Organic Compounds (VOCs) in the Kumi electronic industrial complex during the time periods of August and September, 2002 and January and February, 2003. This study was based on the US-EPA method TO-14 while the VOCs were analyzed with GC/MSD. The toluene level revealed high concentration at all measurement sites. The areal rank of average concentrations of VOCs is as follows: industry1 > industry2 > urban > middle > residential. Concentrations of VOCs in Kumi electronic industrial ones were generally higher than at Yeochon and Ulsan industrial complexes. Dichloromethane and trichloroethylene, which are used as a cleaner in the process of electronic industries, were observed 4 to 8 times higher than those of other areas. Among the aromatic compounds, toluene showed the highest level, while the concentrations of dichloromethane and trichloroethylene were higher than those of other halogen compounds. In Kumi, toluene, trichloroethylene, and dichloromethane were confirmed as the major compounds of VOCs by this research.