• 대한가정학회지
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• 제11권2호
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• pp.139-146
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• 1973

The level of serum cholesterol was successively determined for 4 weeks after the basic diet feeding for 8 weeks in the rabbits. It was observed that the individual serum cholesterol levels were highly elevated by the oral administration of cholesterol for 18 days, and then the rabbit were fed by sesame and rape seed oils for 11 weeks to survey the effect of the oils which was playing a role of decreasing factor for serum cholesterol values. The results were obtained as follows ; 1. The rabbit's serum cholesterol level was 128±29.0mg/dl in average, it was higher in female (162±50.6) than male(95±17.6). 2. It can be possible elevating experimentally the level of serum cholesterol by the cholesterol administration per os. 3. There were significant effect of the vegetable oils to decrease the experimental hypercholesteremia in the rabbits.

• Bulletin of the Korean Chemical Society
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• 제24권4호
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• pp.527-530
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• 2003

• Toxicological Research
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• 제31권3호
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• pp.307-312
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• 2015

Trans fat is a unsaturated fatty acid with trans configuration and separated double bonds. Analytical methods have been introduced to analyze trans fat content in foods including infrared (IR) spectroscopy, gas chromatography (GC), Fourier transform-infrared (FT-IR) spectroscopy, reverses-phase silver ion high performance liquid chromatography, and silver nitrate thin layer chromatography. Currently, FT-IR spectroscopy and GC are mostly used methods. Trans fat content in 6 vegetable oils were analyzed and processing effects including baking, stir-frying, pan-frying, and frying on the formation of trans fat in corn oil was evaluated by GC. Among tested vegetable oils, corn oil has 0.25 g trans fat/100 g, whereas other oils including rapeseed, soybean, olive, perilla, and sesame oils did not have detectable amount of trans fat content. Among cooking methods, stir-frying increased trans fat in corn oil whereas baking, pan-frying, and frying procedures did not make changes in trans fat content compared to untreated corn oils. However, the trans fat content was so low and food label can be declared as '0' trans based on the regulation of Ministry of Food ad Drug Safety (MFDS) (< 2 g/100 g edible oil).

• 한국식품과학회지
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• 제39권2호
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• pp.133-137
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• 2007

유지의 산화안정도 측정을 위해 개발된 DPPH법의 최적화를 위해 시료의 양에 따른 유지의 산화변화를 분석하였고, 결정도니 조건을 사용하여 시중에서 튀김유로 사용되는 4종류 식용유지의 열산화안정성을 측정하였다. CDA와 p-AV는 산화반응이 진행될수록 증가하였으며 시료간의 상대적인 산화안정성 차이를 확인할 수 있었다. 반면에 DPPH법은 유지의 산화라디칼과의 반응성을 이용하며 흡광도의 증가와 감소를 반복하는 경향을 나타냈고 이로부터 유지산화라디칼의 변화를 측정 할 수 있었다. 또한 유지의 초기 전자 혹은 수소공여능을 확인할 수 있었고, DPPH 흡광도 증가를 통해 산화방지물질의 소진속도 및 산화라디칼의 생성속도를 계산할 수 있었으며, 산화방지물질의 소진시점을 결정할 수 있었다. 따라서 DPPH법을 기존의 산화도 측정방법과 병용한다면 유지의 산화도는 물론 산화반응 단계를 측정 할 수 있고, 산화안정성을 예측하는데 도움이 될 것으로 기대된다.

• 공업화학
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• 제21권4호
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• pp.385-390
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• 2010

초음파를 에너지원으로 하는 에스테르 교환 반응에 의해 콩기름과 포도씨 기름, 옥수수 기름, 카놀라 오일 등 식물성 유지로부터 바이오디젤을 제조하였다. 초음파를 이용한 식물성 유지의 에스테르 교환 반응 특성과 생성된 바이오디젤의 생성물 분포 및 물리화학적 특성을 조사하였다. 또한, 초음파와 열에너지에 의한 에스테르 교환 반응의 반응속도도 비교하였다. 초음파를 이용한 에스테르 교환 반응에 의한 바이오디젤 수율은 산촉매보다 균일계 알칼리 촉매에서 높았다. 초음파를 이용한 식물성 유지의 에스테르 교환 반응에서 수산화칼륨 촉매를 식물성 유지에 대해 무게비로 1% 사용하고, 식물성 유지에 대한 메탄올의 몰 비가 6 : 1일 때 지방산 메틸에스테르의 수율이 가장 높았다. 초음파를 에스테르 교환 반응의 에너지원으로 사용하면 열에너지를 사용한 반응 결과 보다 반응속도가 빨랐다. 초음파를 이용한 식물성 유지의 에스테르 교환 반응에 의해 생성된 바이오디젤은 원료유지보다 산가가 30% 이상 낮아졌다.

• 오토저널
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• 제10권6호
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• pp.48-53
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• 1988

In a previous report, the properties of vegetable oils as diesel fuel substitutes were investigated and the basic load performance of a diesel engine was examined using vegetable oil. The results show that despite of the long term chain hydrocarbon structure and large droplet size due to high viscosity, vegetable oils have good basic performance and exhaust emissions, however they cause serious problems as carbon deposit buildup, they have poor durability, and also poor thermal efficiency. In this paper, the startability and engine durability with long term operation was tested by physical methods for reducing viscosity when vegetable oil was used as compared against diesel fuel. The results obtained in this investigation may be stated as follows; (1) There is no problem in startability when vegetable oil was used as diesel fuel substitutes as far as fuel temperature is higher than 30.deg. C (2) The carbon deposits were most extensive at lower loads and lower engine speeds, and deposit buildup more heavily on the cooler parts of the combustion chamber wall. (3) Blends with 25% diesel fuel and 20v-% ethanol are effective in reducing the carbon deposit buildups. (4) Significant improvement in carbon deposit and piston ring stick can be obtained by heating fuel(200.deg.).

• Food Science and Biotechnology
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• 제15권2호
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• pp.183-188
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• 2006

The tocopherol and tocotrienol contents of 39 vegetable oils, margarines, butters, and peanut butters typically consumed in the Korea diet were determined by direct solvent extraction method followed by normal phase liquid chromatography. All samples were locally obtained in the Cheongju area in 2003 and 2004. The study examined data on 19 vegetable oils, 10 margarines, 6 butters, and 4 peanut butters. ${\gamma}$-Tocopherol (${\gamma}$-T) and ${\alpha}$-tocopherol (${\alpha}$-T) were detectable in all products except butters and were usually present in the vitamin E form in greater quantity than the other isomers. Usually, ${\gamma}$-T content was higher than ${\alpha}$-T content in many samples. Tocotrienols were measurable in some samples but usually at levels less than the corresponding tocopherols. Three analytical method validation parameters, accuracy, precision, and specificity, were calculated to ensure the method's validity and were all confirmed to be reliable and satisfactory.

• 산업식품공학
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• 제21권1호
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• pp.49-56
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• 2017

Vegetable seed oils (VSOs) have been extracted and used not only as ingredients in food and as sources of dietary lipids, but also as sources of nutraceuticals used to overcome the various oxidative stresses that contribute to the development of diseases, including cancer and other chronic conditions. The chemical compositions and oxidative stabilities of various VSOs were therefore investigated; samples were stored for 35 d, with each oil having been tested under $O_2$ exposure, sealed from $O_2$ exposure and sealed from $O_2$ exposure while containing $O_2$ scavengers. Oxidative stability was evaluated by peroxide value (POV), p-anisidine value (p-AnV), iodine value (IV), and thiobarbituric acid (TBA) value. Perilla seed and flaxseed oil were mostly composed of linolenic acid (45.5% and 59.7%, respectively), whereas pine seed oil was mostly composed of linoleic acid (48.3%). Meanwhile, camellia seed and olive oils contained 80% oleic acid, which correlated strongly with oxidative stability. The POV, p-AnV, and TBA values were the highest under $O_2$ exposure, and the lowest in the presence of $O_2$ scavengers. These results indicate that VOS oxidative stability depends not only on storage conditions, but on unsaturated fatty acid profiles as well.

• 한국식품영양과학회지
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• 제28권5호
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• pp.980-983
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• 1999

The contents of sterols and stanols in vegetable oils and mist oil were analyzed by gas chromatography using a capillary column. The total sterol contents showed high values of 0.67~0.89g/100g in corn oil, rice bran oil, red pepper seed oil and sesame oil. Mist oil, a byproduct of soybean oil manufacture, was a suitable raw material for the production of stanol since it showed high sterol content (10.2g/100g). In the hydrogenation of sterol contained in mist oil using Pd catalyst, the effects saponification of oil were examined. The conversion of sterol to stanol was improved by a factor of 4~5 through saponification of oil, compared to the reaction without saponification.

• 한국식품과학회지
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• 제36권4호
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• pp.688-691
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• 2004

본 연구에서는 전국에서 유통되는 대두유, 참기름, 올리브유, 마아가린 등 식용유지 총 205건을 대상으로 대표적 PAHs 화합물인 benzo(a)pyrene 등 8개 PAHs 화합물에 대하여 분석하였다. 분석한 식용유지의 PAHs 평균 함량은 각각 benzo(a)anthracene $0.53{\mu}g/kg$, chrysene $0.82{\mu}g/kg$, benzo(b)fluoranthene $0.50{\mu}g/kg$, benzo(k)fluoranthene $0.18{\mu}g/kg$, benzo(a)pyrene $0.35{\mu}g/kg$, dibenzo(a,h)anthracene $0.16{\mu}g/kg$, benzo(g,h,i)perylene $0.31{\mu}g/kg$, indeno(1,2,3-c,d)pyrene $0.44{\mu}g/kg$이었다. 조사결과 우리나라에서 현재 유통되는 식용유지 중 benzo(a)pyrene 등 PAHs 함량은 외국의 모니터링 결과와 유사하거나 낮았다.