• The Korean Journal of Ceramics
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• 제6권3호
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• pp.219-223
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• 2000

The ferroelectric SBT films were deposited on Pt/Ti/SiO$_2$/Si substrates by liquid injection metalorganic chemical vapor deposition (MOCVD) with single-mixture solution of Sr[Ta(OEt)$_5$(dmae)]$_2$and Bi(C$_6$ 6/H$_5$)$_3$. The Sr/Ta and Bi/Ta ratio in SBT films depended on deposition temperature and mol ratio of precursor in the single-mixture solution. At the substrate temperature of 40$0^{\circ}C$, Sr/Ta and Bi/Ta ratio were close to 0.4 and 1 at precursor mol ratio of 0.5~1.0, respectively. As-deposited film was amorphous. However, after annealing at 75$0^{\circ}C$ for 30 min in oxygen atmosphere, the diffraction patterns indicated polycrystalline SBT phase. The remanent polarization (Pr) and coercive field (Ec) of SBT film annealed at 75$0^{\circ}C$ were 4.7$\mu$C/$\textrm{cm}^2$ and 115.7kV/cm at an applied voltage of 5V, respectively. The SBT films annealed at 75$0^{\circ}C$ showed practically no polarization fatigue up to 10$^10$ switching cycles.

• 대한기계학회논문집B
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• 제33권6호
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• pp.454-460
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• 2009

To analyze the mixture formation process of evaporating diesel spray is important for emissions reduction in actual engines. Then the effects of change in density of ambient gas on spray structure in high temperature and pressure field have been investigated in this study. The ambient gas density was changed from ${\rho}_a=5.0kg/m^3$ to ${\rho}_a=12.3kg/m^3$ with CVC(Constant Volume Chamber). Also, simulation study by modified KIVA-II code was conducted and compared with experimental results. The ambient temperature and injection pressure are kept as 700K and 72MPa, respectively. The images of liquid and vapor phase in the evaporating free spray were simultaneously taken by exciplex fluorescence method. As experimental results, with increasing ambient gas density, the tip penetration of the evaporating free spray decreases due to the increase in the drag force from ambient gas. The spatial structure of a diesel spray can be verified as 2-regions consisted of liquid with momentum decrease and vapor with large-scale vortex. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

• Advanced Composite Materials
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• 제18권3호
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• pp.221-232
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• 2009

The allylamine plasma treatment is used to modify the surface properties of vapor grown carbon fibers (VGCF). It is to improve the interfacial bonding between the VGCF and epoxy matrix. The allylamine plasma process was performed by batch process in a vacuum chamber, using gas injection followed by plasma discharge for the durations of 20, 40 and 60 min. The interdependence of mechanical properties on the VGCF contents, treatment time and interfacial bonding between VGCF/ep was investigated. The interfacial bonding between VGCF and epoxy matrix was observed by scanning electron microscopy (SEM) micrographs of nanocomposites fracture surfaces. The changes in the mechanical properties of VGCF/ep, such as the tensile modulus and strength were discussed. The mechanical properties of allylamine plasma treated (AAPT) VGCF/ep were compared with those of raw VGCF/ep. The tensile strength and modulus of allyamine plasma treated VGCF40 (40 min treatment)/ep demonstrated a higher value than those of other samples. The mechanical properties were increased with the allyamine plasma treatment due to the improved adhesion at VGCF/ep interface. The modification of the carbon nanofibers surface was observed by transmission electron microscopy (TEM). SEM micrographs showed an excellent dispersion of VGCF in epoxy matrix by ultrasonic method.

• Journal of Mechanical Science and Technology
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• 제19권12호
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• pp.2253-2262
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• 2005

The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.

• 한국진공학회지
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• 제18권6호
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• pp.481-487
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• 2009

탄소나노필라멘트의 직경크기를 조절하기 위하여 증착 반응초기에 $SF_6$를 증착원료기체($C_2H_2$, $H_2$)에 주입하였다. 증착 원료 기체와 $SF_6$를 열화학기상증착시스템에서 시간에 따라 싸이클릭 유량 변조시켰다. 싸이클릭 유량 변조 프로세스와 기판의 온도에 따라 기판위에 증착된 탄소나노필라멘트들의 특성을 조사하였다. 싸이클릭 에칭기간에 $SF_6$를 투입하자 탄소나노필라멘트의 직경크기는 급격히 감소하였다. 이러한 탄소나노필라멘트 직경의 크기 감소 원인은 $SF_6$ 기체의 주입에 따른 에칭능력 향상에 기인하는 것으로 이해되었다.

• International Journal of Automotive Technology
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• 제5권4호
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• pp.221-238
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• 2004

Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

• 한국진공학회지
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• 제21권3호
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• pp.178-184
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• 2012

니켈촉매 막을 증착시킨 산화규산 기판 위에 아세틸렌기체와 수소기체를 원료기체로 육불화황기체를 첨가기체로 사용하여 열화학기상증착 방법으로 탄소코일을 합성하였다. 첨가기체의 유량과 아세틸렌/육불화황 기체들의 싸이클릭 on/off 유량 변조에 따라 성장된 탄소코일의 특성(형성 밀도, 형상)을 조사하였다. 육불화황의 기체 유량이 가장 낮은 경우(5 sccm)에서, 2분동안 육불화황을 주입하여 아세틸렌/육불화황 기체를 싸이클릭 on/off 유량 변조시킴에 따라 탄소코일을 형성시켰다. 반면 육불화황을 5분 동안 연속적으로 주입한 경우에서는 탄소나노필라멘트 형상이 나타나지 않았다. 육불화황의 유량이 5 sccm에서 30 sccm으로 증가함에 따라 아세틸렌/육불화황 기체들의 싸이클릭 on/off 유량 변조는 탄소코일의 형상을 나노크기의 형태로만 제한시켰다. 육불화황 기체의 플로린 종에 의한 에칭 특성이 이러한 효과를 주게 하는 것으로 이해되었다.

• 한국분무공학회지
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• 제4권2호
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• pp.19-32
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• 1999

The present study investigated the forms and behaviors of fuel during intake and compression process, and the initial flame stability in a lean burn engine modified as a single cylinder engine equipped with quartz windows for visualization. PLIF(Planar Laser Induced Fluorescence) method with KrF Excimer laser was used for measuring the fuel distributions. The principal design concept of the lean burn nin in this study is the axial stratification in the fuel distribution via fuel injection during intake process and different shapes of intake ports; helical and straight. The experiments showed that fuel flowed in as a vapor state in the early part of intake process and lots of this mixture mated down along the intake valve side cylinder wall, but in the latter part, a lot of fuel flowed in as a liquid state and this fuel stayed in the upper part of cylinder, after that the dense fuel cloud moved upward in the early of part compression process. It became clear that the fuel flowed in via straight port had a important role in the axial fuel stratification.

• Tribology and Lubricants
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• 제34권5호
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• pp.175-182
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• 2018

Accumulation of coal ash at the boiler wall reduces combustion and fuel efficiency. The design of a wall blower is important to effectively remove coal ash. We present numerical results for the removal of coal ash from boiler walls of domestic coal-fired power plants, associated with the computational fluid dynamics for the flow from spray nozzle to boiler wall. The numerical model simulates an erosion process in which the multiphase fluid comprising saturated vapor and fluid water is sprayed from the nozzle, and the water particles impact the boiler wall. We adopt the Finnie erosion model for water particles. We obtain the erosion rate density as a function of nozzle angle and its injection angle. As excessive coal ash removal usually induces damage to the boiler wall, the removal operation typically focuses on a large area with uniform depth rather than the maximum removal of coal ash at a specific location. In order to estimate the removal performance of the wall blower nozzle considering several functionality and reliability factors, we evaluate the optimal injection and nozzle angles with respect to the biggest cumulative and highest erosion rates, as well as the widest range and lowest standard deviation of the erosion rate distribution.

• International Journal of Automotive Technology
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• 제5권3호
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• pp.155-164
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• 2004

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and double-spark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray. Vapor phase appears at both ambient and elevated temperature conditions, particularly in the toroidal vortex and impingement plume. More rapid impingement and faster horizontal spread after impingement are observed for elevated temperature conditions. Droplet rebounding and film break-up are clearly observed. Post-impingement droplets are significantly smaller than pre-impingement droplets with a more horizontal velocity component regardless of the wall temperature and impingement angle condition.