• Title/Summary/Keyword: VI

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Removal of hexavalent chromium Cr (VI) by adsorption in blended lateritic soil

  • Sunil, B.M.;Faziludeen, Saifiya
    • Advances in environmental research
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    • v.4 no.3
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    • pp.197-210
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    • 2015
  • Hexavalent chromium [Cr (VI)] adsorption on lateritic soil and lateritic soil blended with black cotton (BC) soil, marine clay and bentonite clay were studied in the laboratory using batch adsorption techniques. In the present investigation the natural laterite soil was blended with 10%, 20% and 30% BC soil, marine clay and bentonite clay separately. The interactions on test soils have been studied with respect to the linear, Freundlich and Langmuir isotherms. The linear isotherm parameter, Freundlich and Langmuir isotherm parameters were determined from the batch adsorption tests. The adsorption of Cr (VI) on natural laterite soil and blended laterite soil was determined using double beam spectrophotometer. The distribution coefficients obtained were 1.251, 1.359 and 2.622 L/kg for lateritic soil blended with 10%, 20% and 30% BC soil; 5.396, 12.973 and 48.641 L/kg for lateritic soil blended with marine clay and 5.093, 8.148 and 12.179 L/kg for lateritic soil blended with bentonite clay respectively. The experimental data fitted well to the Langmuir model as observed from the higher value of correlation coefficient. Soil pH and iron content in soil(s) has greater influence on Cr (VI) adsorption. From the study it is concluded that laterite soil can be blended with clayey soils for removing Cr (VI) by adsorption.

A Design of Framework for Efficient Development of Instrument Control and Monitoring Software (제어 및 모니터링 소프트웨어의 효율적인 개발을 위한 프레임워크 설계)

  • Yoo, Dea-Sung;Sim, Min-Suck;Park, Sung-Ghue;Kim, Jong-Hwan;Yi, Myoung-Jae
    • Annual Conference of KIPS
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    • 2003.05b
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    • pp.1177-1180
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    • 2003
  • 본 논문에서는 자동화 장비들의 제어 및 모니터링 소프트웨어에 대한 쉬운 개발과 유지보수성을 향상시킬 수 있는 프레임워크를 제안한다. 본 논문에서 제안하는 프레임워크는 XML기반의 세 가지 표준 문서 형식(IID, MAP. CMIML), VI Wizard, Generator로 구성된다. VI Wizard는 표준문서형식(IID, MAP, CMIML)을 내장하고. 입력받은 IID와 MAP파일을 이용해서 GUI기반으로 VI(Virtual Instrument)를 구성한다. 새롭게 구성된 VI를 이용하여 장비의 제어정보, 사용자 인터페이스 정보 모니터링 정보, 통신 방법 등에 대한 정보를 기술하는 CMIML을 생성한다. Generator는 VI Wizard에서 생성한 CMIML문서와 실제 장비 드라이버에 대한 API를 입력으로 장비에 대한 제어 및 모니터링 소프트웨어를 자동 생성하게 된다.

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Chromium(VI) Adsorption Behavior of Silk Sericin Beads

  • Kwak, Hyo Won;Yang, Ye Sol;Kim, Moo Kon;Lee, Jeong Yun;Yun, Haesung;Kim, Min Hwa;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.26 no.1
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    • pp.47-53
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    • 2013
  • Silk sericin (SS) has been fabricated into beads using a 1 M LiCl/DMSO solvent and utilized as a heavy metal adsorbent. Among the various heavy metals, we targeted Cr(VI) for adsorption using SS beads and found that its adsorption depended on the coagulant used for the fabrication of the SS beads. When methanol was used as a coagulant, the beads had a better adsorption capacity than when ethanol was used except at pH 1. The adsorption behavior of Cr(VI) on the SS beads followed the BET isotherm. The maximum adsorption capacity was 33.76 mg/g at pH 2. The adsorption of Cr(VI) was confirmed by FT-IR and EDS analyses. Finally, the desorption was carried out using NaOH solution, and it was found that 73.19% of the adsorbed Cr(VI) could be detached.

Anodization of $TiO_2$ with Seawater Electrolyte; Evaluation of Hydrogen Production in PEG and Photocatalytic Cr(VI) Reduction (해수전해질을 이용한 양극산화 $TiO_2$ 제조; 광전기화학적 수소제조 및 Cr(VI) 환원처리 연구)

  • Shim, Eun-Jung;Park, Min-Sung;Her, A-Young;Joo, Hyun-Ku;Yoon, Jae-Kyung
    • Journal of Hydrogen and New Energy
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    • v.20 no.5
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    • pp.404-409
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    • 2009
  • The present works were performed that titanium foil was anodized in various dilution ratios of seawater and distilled water with 10V external voltage applied, then annealed at $450^{\circ}C$ to obtain $TiO_2$ on the Ti substrate. The prepared samples were characterized by instruments (XRD, SEM, and photocurrent) and used to investigate rate of hydrogen production in photoelectrochemical cell as well as Cr(VI) reduction. As the results of experiments, the anodized $TiO_2$ in seawater electrolytes, which are ranged from 15 to 50 times dilution of seawater, was showed a relatively higher hydrogen production (ca. 97~110 umol/hr-$cm^2$) and Cr(VI) reduction (ca. 95% reduction).

Cloning of hexavalent chromium reductase gene from E.coli ATCC 33456

  • Lee, Han-Ki;Ahn, Min-Jung;Bae, Woo-Chul;Jeong, Byeong-Chul
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.672-675
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    • 2000
  • E.coli ATCC 33456 has relatively higher activity of Cr(VI) reduction than other microorganism. The purpose of this research is cloning of Cr(V) reductase from E.coli ATCC 33456. Using colony and southern hybridization, we selected two condidates. Among candidates, pNCR9 is higher Cr(VI) reduction activity than E.coli ATCC 33456. Purified Cr(VI) reductase antibody was reacted at estimated 42Kda protein band of candidate's crude extract on 12% SDS-PAGE. This results showed cloned gene's product is very similar to purified Cr(VI) reductase from E.coli ATCC 33456.

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Laser pose calibration of ViSP for precise 6-DOF structural displacement monitoring

  • Shin, Jae-Uk;Jeon, Haemin;Choi, Suyoung;Kim, Youngjae;Myung, Hyun
    • Smart Structures and Systems
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    • v.18 no.4
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    • pp.801-818
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    • 2016
  • To estimate structural displacement, a visually servoed paired structured light system (ViSP) was proposed in previous studies. The ViSP is composed of two sides facing each other, each with one or two laser pointers, a 2-DOF manipulator, a camera, and a screen. By calculating the positions of the laser beams projected onto the screens and rotation angles of the manipulators, relative 6-DOF displacement between two sides can be estimated. Although the performance of the system has been verified through various simulations and experimental tests, it has a limitation that the accuracy of the displacement measurement depends on the alignment of the laser pointers. In deriving the kinematic equation of the ViSP, the laser pointers were assumed to be installed perfectly normal to the same side screen. In reality, however, this is very difficult to achieve due to installation errors. In other words, the pose of laser pointers should be calibrated carefully before measuring the displacement. To calibrate the initial pose of the laser pointers, a specially designed jig device is made and employed. Experimental tests have been performed to validate the performance of the proposed calibration method and the results show that the estimated displacement with the initial pose calibration increases the accuracy of the 6-DOF displacement estimation.

Application of in situ Liquid Ferrate(VI) for 2-Bromophenol Removal (2-브로모페놀 제거를 위한 액상 페레이트 적용 연구)

  • Laksono, Fajar Budi;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.6
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    • pp.685-692
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    • 2015
  • The concern over the risk of environmental exposure to brominated phenols has been increased and has led the researchers to focus their attention on the study of bromophenol treatment. In this study, the effects of pH and ferrate(VI) dose on the degradation of 2-bromophenol were investigated. The results indicated that the oxidation of 2-bromophenol by liquid ferrate(VI) was found to be highly sensitive to the pH condition. Furthermore, the highest removal efficiency was observed at the neutral condition with the removal efficiency of 94.2%. In addition, experimental results showed that 2-bromophenol removal efficiency increased with increasing of ferrate dosage. Ferrate(VI) dose of 0.23 mM was sufficient to remove most of the 2-bromophenol with the efficiency of 99.73% and kapp value of $2982M^{-1}s^{-1}$. Seven compounds were identified as the intermediate products by the GC/MS analysis.

Cr (VI) separation by PolyHIPE membrane immobilized with Aliquat 336 by solvent-nonsolvent method

  • Chen, Jyh-Herng;Mai, Le Thi Tuyet;Hsu, Kai-Chung
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.575-590
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    • 2017
  • PolyHIPEs membrane prepared with styrene (St), divinylbenzene (DVB), and ethylhexyl acrylate (EHA) can yield a unique pore structure provided by large voids highly interconnected by many small window throats. With the advantageous pore structure, PolyHIPE presents a potential as a support for carrier facilitated transport membrane. Tricaprylmethylammonium chloride (Aliquat 336) can be efficiently incorporated into the PolyHIPE membrane by a two-step solvent-nonsolvent method to obtain an Aliquat 336-immobilized PolyHIPE membrane with good stability. The study of Cr (VI) transport through Aliquat 336-immobilized PolyHIPE membrane indicates that the membrane has high initial flux and maxima stripping flux ($J_f^o=15.01({\mu}mol/m^2s)$, $J_s^{max}=6.15({\mu}mol/m^2s)$). The reusability study shows that the Aliquat 336-immobilized PolyHIPE membrane can maintain high Cr(VI) recovery efficiency even after 15 cycles of operations. The developed membrane was also used in the separation of Cr (VI) from other anions (i.e., $SO_4{^{2-}}$ and $NO_3{^-}$) and other cations (i.e., Ni (II), Mg (II) and Cu (II)) with good selectivity.

Separation of Th(IV) and U(VI) Using Arsenazo I-XAD-16 Chelating Resin (Arsenazo I-XAD-16 킬레이트 수지를 이용한 Th(IV)과 U(VI)의 분리)

  • Suh, Jung-Min;Kim, Min-Kyun;Lim, Jae-Hee;Lee, Chang-Hun;Lee, Won
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.397-404
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    • 1995
  • Three Arsenazo I-XAD Chelating resins, with different surface areas and pore sizes were synthesized and characterized. The total sorption capacities of these chelating resins for Cu(II) at pH 5.0 by batch method decreased as follows, Arsenazo I-XAD-16(0.59mmol/g)>Arsenazo I-XAD-4(0.56mmol/g)>Arsenazo I-XAD-2(0.38mmol/g). The sorption and desorption properties of Arsenazo I-XAD-16 chelating resins for U(VI), Th(IV), Hf(IV), Zr(IV), Ni(II), Mn(II), Cd(II). and Cu(II) were studied by both batch and elution method. The Arsenazo I-XAD-16 chelating resin was successfully applied to the separation and concentration of trace U(VI) and Th(IV) in sea and waste waters.

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Prediction of Aerodynamic Loads for NREL Phase VI Wind Turbine Blade in Yawed Condition

  • Ryu, Ki-Wahn;Kang, Seung-Hee;Seo, Yun-Ho;Lee, Wook-Ryun
    • International Journal of Aeronautical and Space Sciences
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    • v.17 no.2
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    • pp.157-166
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    • 2016
  • Aerodynamic loads for a horizontal axis wind turbine of the National Renewable Energy Laboratory (NREL) Phase VI rotor in yawed condition were predicted by using the blade element momentum theorem. The classical blade element momentum theorem was complemented by several aerodynamic corrections and models including the Pitt and Peters' yaw correction, Buhl's wake correction, Prandtl's tip loss model, Du and Selig's three-dimensional (3-D) stall delay model, etc. Changes of the aerodynamic loads according to the azimuth angle acting on the span-wise location of the NREL Phase VI blade were compared with the experimental data with various yaw angles and inflow speeds. The computational flow chart for the classical blade element momentum theorem was adequately modified to accurately calculate the combined functions of additional corrections and models stated above. A successive under-relaxation technique was developed and applied to prevent possible failure during the iteration process. Changes of the angle of attack according to the azimuth angle at the specified radial location of the blade were also obtained. The proposed numerical procedure was verified, and the predicted data of aerodynamic loads for the NREL Phase VI rotor bears an extremely close resemblance to those of the experimental data.