• Corrosion Science and Technology
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• 제18권6호
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• pp.267-276
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• 2019

The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.

• 한국재료학회지
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• 제28권7호
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• pp.428-434
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• 2018

Hydrogen evolution on a steel surface and subsequent hydrogen diffusion into the steel matrix are evaluated using an electrochemical permeation test with no applied cathodic current on the hydrogen charging side. In particular, cyclic operation in the permeation test is also conducted to clarify the corrosion-induced hydrogen evolution behavior. In contrast to the conventional perception that the cathodic reduction reaction on the steel in neutral aqueous environments is an oxygen reduction reaction, this study demonstrates that atomic hydrogen may be generated on the steel surface by the corrosion reaction, even in a neutral environment. Although a much lower permeation current density and significant slower diffusion kinetics of hydrogen are observed compared to the results measured in acidic environments, they contribute to the increase in the embrittlement index. This study suggests that the research on hydrogen embrittlement in ultra-strong steels should be approached from the viewpoint of corrosion reactions on the steel surface and subsequent hydrogen evolution/diffusion behavior.

• Journal of Welding and Joining
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• 제34권1호
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• pp.7-20
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• 2016

A brief overview is given of the development of various structural steels and their welding application technology. Firstly, the general characteristics and welding performance of structural steels used in architecture and bridge are introduced. For safety against earthquakes or strong wind, and for highly efficient welding in high-rise building constructions, ultra high strength steel with tensile strength over 800 MPa or high HAZ toughness steel plates under high heat input welding have been developed. In particular, efficient welding technology ensuring high resistance to cold and hot cracking of ultra high strength steel is reviewed in the present paper. Secondly, various coated steels used mainly for outer part in construction are briefly discussed. Moreover, a major drawback of coated steel during welding operation, and several solutions to overcome such technical problem are proposed. It is hoped that this review paper can lead to significant academic contributions and provide readers interested in the structural steels with useful welding technology.

• 한국재료학회지
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• 제17권12호
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• pp.634-636
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• 2007

The texture and microstructure in Cu/Nb added ultra low carbon steels through the different thickness layer were studied after hot rolling. It was found that the two ultra low carbon steels all show the inhomogeneity of hot rolling texture and the Cu-added ultra low carbon steel was far more inhomogeneous than Nb-added one. In the center layer, the strong ${\alpha}\;fibre,\;{\gamma}\;fibre$ textures and the shear textures including 001<110>, 111<112> were founded. Near the surface, the ${\alpha}\;fibre$ texture and the orientation texture caused by a typical plane-strain deformation condition of bcc metals were observed.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.157-158
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• 2002

A surface hardenable low alloy carbon steel was implanted with medium energy (20 - 50KeV) $N_2^+$ ions to produced a modified hardened surface. The implantation conditions were varied and are given in several doses. The surface hardness of treated and untreated steels were measured using depth sensing ultra micro indentation system (UMIS). It is shown that the hardness of nitrogen ion implanted steels varied from 20 to 50GPa depending on the implantation conditions and the doses of implantation. The structure of the modified surfaces was examined by X-ray photoelectron spectroscopy (XPS). It was found that the high hardness on the implanted surfaces was as a result of formation of non-equilibrium nitrides. High-resolution XPS studies indicated that the nitride formers were essentially C and Si from the alloy steel. The result suggests that the ion implantation provided the conditions for a preferential formation of C and Si nitrides. The combination of evidences from nano-indentation and XPS, provided a strong evidence for the existence of $sp^3$ type of bonding in a suspected $(C,Si)_xN_y$ stoichiometry. The formation of ultra hard surface from relatively cheap low alloy steel has significant implication for wear resistance implanted low alloy steels.

• Corrosion Science and Technology
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• 제20권5호
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• pp.295-307
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• 2021

Effects of ε-carbide (Fe_2.4C) on corrosion and hydrogen diffusion behaviors of ultra-strong steel sheets for automotive application were investigated using a number of experimental and analytical methods. Results of this study showed that the type of iron carbide precipitated during tempering treatments conducted at below A₁ temperatures had a significant influence on corrosion kinetics. Compared to a steel sample with cementite (Fe₃C), a steel sample with ε-carbide (Fe_2.4C) showed higher corrosion resistance during a long-term exposure to a neutral aqueous solution. In addition, the diffusion kinetics of hydrogen atoms formed by electrochemical corrosion reactions in the steel matrix with ε-carbide were slower than the steel matrix with cementite because of a comparatively higher binding energy of hydrogen with ε-carbide. These results suggest that designing steels with fine ε-carbide distributed uniformly throughout the matrix can be an effective technical strategy to ensure high resistance to hydrogen embrittlement induced by aqueous corrosion.

• Advances in concrete construction
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• 제10권1호
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• pp.1-11
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• 2020

This study intends to produce an ultra-high performance fibre reinforced concrete (UHPFRC) made with hybrid fibres (i.e., steel and polypropylene). Compressive and tensile strength characteristics of the hybrid fibres UHPFRC are considered. A total of 14 fibre-reinforced composites (FRCs) with different fibre contents or types of fibres were prepared and tested in order to determine a suitable hybrid fibre combination. The compressive and tensile strengths of each concrete at 7 days were determined. The results showed that a hybrid mix of micro-polypropylene and steel fibres exhibited good compromising performances and is the ideal reinforcement mixture in a strong, cost-effective UHPFRC. In addition, maximum compressive strength of 167 MPa was achieved for UHPFRC using 1.5% steel fibres blended with 0.5% macro-polypropylene fibres.

• Steel and Composite Structures
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• 제22권5호
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• pp.1085-1114
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• 2016

This paper investigates the transverse impact response for ultra lightweight cement composite (ULCC) filled pipe-in-pipe structures through a parametric study using both a validated finite element procedure and a validated theoretical model. The parametric study explores the effect of the impact loading conditions (including the impact velocity and the indenter shape), the geometric properties (including the pipe length and the dimensions of the three material layers) as well as the material properties (including the material properties of the steel pipes and the filler materials) on the impact response of the pipe-in-pipe composite structures. The global impact responses predicted by the FE procedure and by the theoretical model agree with each other closely. The parametric study using the theoretical approach indicates the close relationships among the global impact responses (including the maximum impact force and the maximum global displacement) in specimens with the equivalent thicknesses, proposed in the theoretical model, for the pipe-in-pipe composite structures. In the pipe-in-pipe composite structure, the inner steel pipe, together with the outer steel pipe, imposes a strong confinement on the infilled cement composite and enhances significantly the composite action, leading to improved impact resistance, small global and local deformations.

• 한국건설순환자원학회논문집
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• 제5권3호
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• pp.290-297
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• 2017

압축강도 160MPa와 길이 15.4m를 가진 분절형 U거더와 합성 U거더의 휨거동 실험을 수행하였다. 실험 변수로는 강섬유 혼입률과 U거더 상부의 슬래브이다. U거더의 복부와 하부플랜지에 종방향 철근을 배근하였다. 상부플랜지에 2개의 15.2mm 강연선을 포함한 2개의 프리스트레싱 텐던 그리고 하부플랜지에 7개의 15.2mm 강연선을 포함한 2개의 프리스트레싱 텐던이 배치되고 U거더 접합 시 한차례 긴장 작업을 하였다. 초고강도 콘크리트 강도로 인해 U거더에 도입한 충분히 강한 프리스트레싱 긴장력은 U거더 시공단계에서 자중과 고정하중을 부담할 수 있다. U거더의 취성적 거동에 비해 합성 U거더는 안정적이고 연성적인 하중처짐 관계를 보여주고 있다. U거더 상부에 슬래브를 시공한 후, U거더 접합 시 도입했던 프리스트레싱 긴장력에 의한 합성 U거더의 휨하중 내하력은 마지막 하중 단계에서 설계하중을 부담할 수 있다. 초고강도 콘크리트로 인한 간단한 프리스트레싱 방법은 시공단계와 공사비 면에서 장점을 가지고 있다. 간격이 작은 전단키는 초고강도 콘크리트 U거더와 고강도 콘크리트슬래브간의 완전한 합성관계를 가져와 파괴하중 직전까지 슬립현상이나, 벌어짐 현상을 보이지 않았다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.187-188
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• 2021

In the case of the Busan North Port, where the Busan Opera House is located, it is an environment exposed to various external deterioration factors such as frequent strong winds, seawater and salty winds, and an exterior material using UHPC (Ultra High Performance Concrete), a highly durable exterior material as a solution to this. Has been adopted. in this study, an economical production and construction direction was reviewed by applying UHPC to the exterior panels of atypical buildings that cannot cope with GFRC, metal, and glass, which are the main exterior finishing materials applied so far. When steel fibers are used, structural performance may be better than organic fibers, but due to environmental factors in Busan, corrosion due to exposure to steel fibers or problems with safety management after construction and completion may occur. Therefore, the site used the newly developed SACF fiber. Facade design of atypical buildings, which will increase in the future, is an important part, and the scope of use of UHPC panels is expected to increase in the future as design trends and demand for high durability increase.