• Title/Summary/Keyword: UV-visible spectrometer

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Development of Energy Harvesting Hybrid system consisted of Electrochromic Device and Dye-Sensitized Solar Cell using Nano Particle Deposition System (나노 입자 적층 시스템(NPDS)을 이용한 염료 감응 태양전지 - 전기 변색 통합 소자 및 에너지 하베스팅 시스템에 대한 연구)

  • Kim, Kwangmin;Kim, Hyungsub;Choi, Dahyun;Lee, Minji;Park, Yunchan;Chu, Wonshik;Chun, Dooman;Lee, Caroline Sunyong
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.65-71
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    • 2016
  • In this study, Antimony Tin Oxide (ATO) ion storage layer and $TiO_2$ working electrode were fabricated using Nano Particle Deposition System. NPDS is the cutting-edge technology among the dry deposition methods. Accelerated particles are deposited on the substrate through the nozzle using NPDS. The thicknesses for coated layers were measured and layer's morphology was acquired using SEM. The fabricated electrochromic cell's transmittance was measured using UV-Visible spectrometer and power source at 630 nm. As a result, the integrated electrochromic/DSSC hybrid system was successfully fabricated as an energy harvesting system. The fabricated electrochromic cell was self-operated using DSSC as a power source. In conclusion, the electrochromic cell was operated for 500 cycles, with 49% of maximum transmittance change. Also the photovoltaic efficiency for DSSC was measured to be 2.55% while the electrochromic cell on the integrated system had resulted in 26% of maximum transmittance change.

Hydrogen Production from Splitting of Methanol/Water Solution Using Perovskite Structured NbxSrTi1-xO3 Photocatalyts (Perovskite NbxSrTi1-xO3 광 촉매를 이용한 메탄올/물 분해로부터 수소제조)

  • Kim, Dongjin;Han, Gi Bo;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.513-517
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    • 2013
  • This study focused on the synthesis of $Nb_xSrTi_{1-x}O_3$ photocatalysts which partially inserted Nb ions with excellent ability of fluorescence into the perovskite structured $SrTiO_3$ frameworks and their photocatalytic hydrogen productions from methanol/water splitting corresponding to the molar ratios of Ti and Nb. The characteristics of the synthesized $SrTiO_3$ and $Nb_xSrTi_{1-x}O_3$ powders were analyzed by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), and UV-Visible spectrometer. The hydrogen evolution from methanol/water photo-splitting was enhanced over $Nb_{0.05}SrTi_{0.95}O_3$ compared to those over $SrTiO_3$ and another $Nb_xSrTi_{1-x}O_3$; 4.9 mL of hydrogen gases was collected after 8 h when 0.5g of $Nb_{0.05}SrTi_{0.95}O_3$ catalyst was used in pH 10.

A Study on the Anti-Reflection Coating Effects of Polymer Eyeglasses Lens (폴리머 안경렌즈의 반사방지 코팅효과 연구)

  • Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.216-221
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    • 2017
  • Reducing optical reflection in the visible light range, in order to increase the share of transmitted light and avoid the formation of ghost images in imaging, is important for polymer lens applications. In this study, polymer lenses with refractive indices of n=1.56, 1.60, and 1.67 were fabricated by the injection-molding method with a polymer lens monomer, dibutyltin dichloride as the catalyst and an alkyl phosphoric ester as the release agent. To investigate their anti-reflection (AR) effects, various AR coating structures, viz. a multi-layer AR coating structure, tri-layer AR coating structure with a discrete approximation Gaussian gradient-index profile, and tri-layer AR coating structure with a quarter-wavelength approximation, were designed and coated on the polymer lens by an E-beam evaporation system. The optical properties of the polymer lenses were characterized by UV-visible spectrometry. The material properties of the thin films, refractive index and surface roughness, were analyzed by ellipsometry and AFM, respectively. The most effective AR coating structure of the polymer lens with low refractive index, n=1.56, was the both side coating of multi-layer AR coating structure. However, both side coating of the tri-layered discrete approximation Gaussian gradient-index profile AR coating structure gave comparable results to the both side coating of the multi-layer AR coating structure for the polymer lens with a high refractive index of n=1.67.

Synthesis of Subphthalocyanine Compound Derivatives and Their Properties (Subphthalocyanine 화합물 유도체들의 합성 및 특성 비교)

  • Kim, Jae Hwan;Heo, Jin;Lee, Yun-Yi;Kim, Bo Hyun;Lee, Geun-Dae;Hong, Seong-Soo;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.46-51
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    • 2009
  • Subphthalocyanine (SubPc) derivatives consisting of the different kinds and positions of substitute group were successfully synthesized using various types of the precursor as the intermediate compound. The chemical structure of precursor and product was determined by the means of $^{1}H-NMR$ and FT-IR spectrometer. Also, spectroscopic and crystalline properties were determined by means of UV-Vis spectrometer and XRD, respectively. It was found that SubPc derivatives absorbed selectively visible light ranging from 560 to 600 nm, their solubility was enhanced by introducing substitute groups, and their maximum absorbing wavelength was shifted by changing the kind and position of substitute groups.

Effect of thermal treatment on spray deposited CdTe thin films (스프레이 증착법을 이용한 CdTe박막의 열처리에 따른 특성 분석)

  • Lee, Jinyoung;Hwang, Sooyeun;Lee, Taejin;Ryu, Siok
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.49.2-49.2
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    • 2010
  • Polycrystalline CdTe thin films for solar cell continues to be a promising material for the development of cost effective and reliable photovoltaic processes. The two key advantages of this material are its high optical absorption coefficient and its near ideal band gap for photovoltaic conversion efficiency of 1.4-1.5 eV. In this study we made the CdTe thin films for solar cell application which was deposited on the glass substrates using a modified chemical spray method at low temperature. This process does not require the sophisticated and expensive vacuum systems. The prepared CdTe films were characterized with the aid of scanning electron microscope (SEM), UV-visible spectrophotometer, and X-ray diffraction spectrometer (XRD). Following are results of a study on the "Human Resource Development Center for Economic Region Leading Industry" Project, supported by the Ministry of Education, Science & Tehnology(MEST) and the National Research Foundation of Korea(NRF).

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Effect of RF Power on SnO Thin Films Obtained by Sputtering (스퍼터링에 의해 제조된 SnO 박막의 RF 파워에 따른 특성 연구)

  • Um, Joseph;Roh, Byeong-Min;Kim, Sungdong;Kim, Sarah Eunkyung
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.399-403
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    • 2012
  • SnO thin films were fabricated by rf reactive sputtering on borosilicate substrates with an Sn target and Ar/$O_2$ gas mixture. The effect of rf power on the structural, electrical, and optical properties of SnO thin films was investigated with XRD, AFM, SEM, Hall effect measurements, and UV-Vis spectrometer. As a plasma power increased the crystallinity with a preferred orientation of SnO thin films was improved and the grain size slightly increased. However the grains were coalesced and excessively irregular in shape. The electrical conductivity of SnO thin films demonstrated a relatively low p-type conductivity of 0.024 $(Wcm)^{-1}$ at a higher power condition. Lastly, SnO thin films had poor optical transmittance in the visible range as a plasma power increased.

저온공정에서 제작한 ZnO:Al 박막의 특성 분석

  • Jung, Yu-Sup;Kim, Sang-Mo;Hong, Jung-Soo;Son, In-Hwan;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.201-202
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    • 2009
  • ZnO:Al transparent conductive films for solar cells were deposited on the glass substrates at room temperature by facing target sputtering (FTS) method. The sputtering targets were 100 mm diameter disks of 2w.t..%. AZO and Zn metal. ZnO:Al thin films were deposited as a function film thickness. A base pressure was $2{\times}10^{-6}$torr, and a working pressure was 1mTorr. The properties of thin films on the structural, electrical and optical properties of the deposited films were investigated using a four-point probe (Chang-min), an X-ray diffraction (Rigaku), a Hall Effect measurement (Ecopia), an UV/VIS spectrometer (HP) and a $\alpha$-step (Tencor). The lowest resistivity of film was $5.67{\times}10^{-4}[{\Omega}-cm]$ at 500nm. The average transmittance of over 80% was seen in the visible range.

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Properties of IZTO Thin Film prepared by the Hetero-Target sputtering system (상온에서 증착한 IZTO 박막의 기판 종류에 따른 특성)

  • Kim, Dae-Hyun;Rim, You-Seong;Kim, Sang-Mo;Keum, Min-Jong;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.203-204
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    • 2009
  • The Indium Zinc Tin Oxide (IZTO) thin films for flexible display electrode were deposited on poly carbonate (PC) and polyethersulfone(PES) and glass substrates at room temperature by facing targets sputtering (FTS). Two different kinds of targets were installed on FTS system. One is ITO ($In_2O_3$ 90 wt.%, $SnO_2$ 10 wt.%), the other is IZO ($In_2O_3$ 90 wt.%, ZnO 10 wt.%). As-deposited IZTO thin films were investigated by a UV/VIS spectrometer, an X-ray diffractometer (XRD), an atomic force microscope (AFM) and a Hall Effect measurement system. As a result, we could prepare the IZTO thin films with the resistivity of under $10^{-4}\;[{\Omega}{\cdot}cm]$ and IZTO thin films deposited on glass substrate showed an average transmittance over 80% in visible range (400~800 nm) in all IZTO thin films except in IZTO thin film deposited at $O_2$ gas flow rate of 0.1[sccm].

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Color Difference Characterization on Nickel Silicides (니켈실리사이드의 색차분석)

  • Jung Youngsoon;Song Ohsung;Kim Dugjoong;Choi Yongyun;Kim Chongjun
    • Journal of the Korean institute of surface engineering
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    • v.38 no.1
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    • pp.44-48
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    • 2005
  • We prepared nickel silicide layers from p-Si(l00)/SiO₂(2000 Å)/poly-Si(700 Å)/Ni(400 Å) structures, feasible for gates in MOSFETs, by annealing them from 500℃~900℃ for 30 minutes. We measured the color coordination in visible range, cross sectional micro-structure, and surface topology with annealing temperature by an UV-VIS-IR spectrometer, field effect scanning electron microscope(FE-SEM), and scanning probe micro-scope respectively. We conclude that we may identify the nickel silicide by color difference of 0.90 and predict the silicide process reliability by color coordination measurement. The nickel silicide layers showed similar thickness while the columnar grains size and surface roughness increased as annealing temperature increased.

Fabrication and Properties of Au fine Particles Doped ZrO2 Thin Films by the Sol-gel Method (졸-겔법에 의한 Au 미립자 분산 ZrO2 박막의 제조와 특성)

  • 이승민;문종수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.475-480
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    • 2003
  • Nanocomposite of Au doped ZrO$_2$ films was prepared, which could be used as non-linear optic materials, selective absorption and transmission films. After heat treatment of prepared thin film by dip-coating method, the characteristics were investigated by X-ray diffraction, UV-VIS Spectrometer, Atomic Force Microscopy (AFM) and Scanning Electron Microscope (SEM). Film thickness was about 150 nm, the Au particle size was 15~35 nm. The thin film had a smooth surface roughness about 1.06 nm. Nonlinearity optics was found that films showed absorption peak at 600~650 nm visible region by plasma resonance of Au metal particles.