• 제목/요약/키워드: UV stability

검색결과 548건 처리시간 0.028초

페로브스카이트 태양전지 상용화를 위한 자외선 및 수분 안정성 향상 전략 (A Brief Review on Strategies for Improving UV and Humidity Stability of Perovskite Solar Cells Towards Commercialization)

  • 황은혜;권태혁
    • Current Photovoltaic Research
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    • 제10권2호
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    • pp.49-55
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    • 2022
  • With rapid growth in light-harvesting efficiency from 3.8 to 25.8%, organic-inorganic hybrid perovskite solar cells (PSCs) have attracted great attention as promising photovoltaic devices. However, despite of their outstanding performance, the commercialization of PSCs has been suffered from severe stability issues, especially for UV and humidity: (i) UV irradiation towards PSCs is able to lead UV-induced decomposition of perovskite films or catalytic reactions of charge-transporting layers, and (ii) exposure to surrounding humidity causes irreversible hydration of perovskite layers by the penetration of water molecules, resulting considerable decrease in their power-conversion efficiency (PCE). This review investigates current status of strategies to enhance UV and humidity stability of PSCs in terms of UV-management and moisture protection, respectively. Furthermore, the multifunctional approach to increase long-term stability as well as performance is discussed as advanced research directions for the commercialization of PSCs.

Improvement in Long-Term Stability and Photovoltaic Performance of UV Cured Resin Polymer Gel Electrolyte for Dye-Sensitized Solar Cell

  • Park, Geun Woo;Hwang, Chul Gyun;Jung, Jae Won;Jung, Young Mee
    • Bulletin of the Korean Chemical Society
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    • 제33권12호
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    • pp.4093-4097
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    • 2012
  • We introduced a new UV-cured resin polymer gel as an electrolyte for dye-sensitized solar cells (DSSCs) that is cured with UV irradiation to form a thin film of UV-cured resin polymer gel in the cells. The gel film was characterized and its potential for use as an electrolyte in DSSCs was investigated. This new UV-cured resin polymer gel was successfully applied as a gel polymer electrolyte in DSSCs overcoming the problems associated with the liquid electrolytes in typical DSSCs. The effect of ${\gamma}$-butylrolactone (GBL) on the long-term stability and photovoltaic performance in DSSCs using this UV-cured resin polymer gel electrolyte was also investigated. The results of the energy conversion efficiency, ionic conductivity and Raman spectra of the UV-cured resin polymer gel electrolyte with the addition of 6 wt % GBL to the UV-cured resin polymer electrolyte showed good long-term stability and photovoltaic performance for the DSSCs with the UV-cured polymer gel electrolyte.

자외선 조사에 의한 폴리에스터의 광가교 (Photocrosslinking of Polyester by UV irradiation)

  • 윤득원;장진호
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2011년도 제45차 학술발표회
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    • pp.7-7
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    • 2011
  • Poly(ethylene terephthalate)(PET) is one of the most widely used materials in textile industry. It can have a low cost, silk-like handle, and excellent mechanical properties. Low thermal stability of PET had been a common problem limiting its high temperature application. The polyester have been known to have the disadvantage of degradation under ionized irradiation compared to crosslikable polymers such as polyethylene, polypropylene and polystylene. To improve thermal stability of PET, the PET films were photocrosslinked by UV irradiation. A hydrogen-abstractable photoinitiator was used to photocrosslink of PET by continuous UV irradiation. Photoinitiator addition increased the gel fraction. The photocrosslinking was attributed to the recombination of PET radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the PET polymer chains by the added photoinitiator. Also the crosslinked PET showed higher thermal stability and mechanical strength with increasing UV energy. Polyester type films such as poly(ethylene naphthalate)(PEN) and poly(butylene terephthalte)(PBT) were also increased the gel fraction and improved thermal stability and mechanical properties by UV irradiation.

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한약증류액의 안정성에 관한 연구 (Studies on Stability of distilled Herbal medicine)

  • 주혜정;이한구
    • 한국한의학연구원논문집
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    • 제1권1호
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    • pp.441-459
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    • 1995
  • To study stability of distilled herbal medicine, we chose changes in UV spectrum, pH, conductivity, and HPLC chromatogram. Aconiti Lateralis preparata Radix and Scutellariae Radix were selected and studied. There ws no consistancy in UV spectrums of preparatons and in duration. The changes in pH and conductivity were not correlated to those in UV spectrums. HPLC chromatograms were also compared each other depending on the preparations. One interesting peak of distilled Aconiti solution was appeared at 40 min retention time which was not identified yet. Ingeneral, UV spectrum, pH, conductivity measurements are pretty poor tool to study stability of herbal medicine although HPLC analysis should be studied further.

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Preparation and Characterization of Muscovite Mica/UV Coating Materials for Steel

  • Cheong, In-Woo;Kim, Hyeon-Seok;Hwang, Dong-Seop;Yoo, Hye-Jin;Kim, Jin-Tae;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.265-269
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    • 2010
  • This paper describes the exfoliation and surface modification of muscovite mica for UV coating formulation. For the exfoliation of the mica, hydrothermal process was used in the presence of lithium nitrate ($LiNO_3$). After the cation exchange with $Li^+$ ions, the surface of the mica was modified with several amphiphilic substances to increase compatibility and storage stability in UV coating formulation. Such a hydrophobic surface modification affected colloidal stability as well as dispersibility of the exfoliated mica in UV coating solution. Anticorrosive property of mica/UV coated steel plates was tested by salt spray test (SST) and compared with sodium montmorillonite ($Na^+$-MMT)/UV coated steel plates.

저압 UV램프 구동시스템 및 출력안정화 시스템에 관한 연구 (A Study on Driving System and Constant Output System for a Low Pressure UV Lamp)

  • 이진우;노재엽
    • 조명전기설비학회논문지
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    • 제19권8호
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    • pp.19-23
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    • 2005
  • 본 연구의 목표는 안정된 출력과 높은 효율을 갖는 저압 UV램프의 구동시스템을 설계하는 것이다. UV램프 시스템은 반도체공정, 살균 등 그 적용범위가 대단히 넓은 전력설비의 하나이며 고부가가치의 제품을 생산하기 위해서는 출력의 안정화 기술은 필수적이다. 본 연구에서 저압 UV램프의 구동시스템 설계 목표는 변환효율 90[%], 출력안정도 ${\pm}7.5[%]$, 램프출력은 300[W] 이상으로, 연구목표에 상응하는 결과를 얻을 수 있었으며 국내시장 선점에 유리할 것이고, 제품의 생산비를 낮추는 시도를 계속한다면, 수출도 가능할 것으로 예상된다. 또한 부가적인 보호회로가 개발되면, 자외선램프용 전자식 안정기의 신뢰성을 크게 재고시킬 것이다.

The Influence of Hydrotalcite Intercalated with Benzoate on UV Stability of Acrylic Coating

  • Nguyen, Thuy Duong;Nguyen, Anh Son;Thai, Thu Thuy;Pham, Gia Vu;To, Thi Xuan Hang;Olivier, Marie-Georges
    • Corrosion Science and Technology
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    • 제19권1호
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    • pp.16-22
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    • 2020
  • It is important to realize that benzoate was intercalated into hydrotalcite (HTC-Bz) by the co-precipitation method. In this case, acrylic coating with 0.5 wt% HTC-Bz was deposited on carbon steel using the spin coating method. Next, the HTC-Bz structure was characterized by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). In fact, an ultraviolet vision spectroscopy (UV-Vis) was used to determine the benzoate content in HTC-Bz, and the UV absorption ability of HTC-Bz. Using electrochemical techniques, water contact angle measurement, and thermal-gravimetric analysis, we compared the protective properties before and after QUV test, hydrophobicity and the thermal stability of acrylic coating containing HTC-Bz. The obtained results showed that HTC-Bz with a plate-like structure was successfully synthesized; benzoate was intercalated into the interlayer of hydrotalcite with a concentration of 28 wt%. Additionally, it was noted that HTC-Bz has an UV absorption peak at 225 nm. In conclusion, the addition of HTC-Bz enhanced the UV stability, hydrophobicity and the thermal stability of acrylic coating.

피부 주름 개선 소재인 페오니플로린의 에멀젼 안정성 (Stability of Paeoniflorin used as Anti-wrinkle Agents in Emulsions)

  • 조완구;경기열;유상문
    • 한국응용과학기술학회지
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    • 제26권2호
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    • pp.191-198
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    • 2009
  • We have tested the stability of paeoniflorin, a new cosmetic ingredient, extracted from the roots of Paeoniae lactiflora. The stability of aqueous paeoniflorin solution at pH 3, 5 and 7 varied by adding buffer solution was tested at $0^{\circ}C,\;25^{\circ}C,\;40^{\circ}C,\;and\;65^{\circ}C$. The test was performed with or without UV light. The solution of paeoniflorin was stable at pH 3.0, however, the recovery rate of paeoniflorin was 40% at pH 7.0. The stability of paeoniflorin solution was decreased as the pH of paeoniflorin solution was increased by pH 7.0. The effect of storage temperature of paeoniflorin solution shows that the stability of paeoniflorin solution was decreased as the temperature was increased. The stability of paeoniflorin was rather good under UV light than the condition given above $40^{\circ}C$. The stability of paeoniflorin in W/O emulsions shows similar pattern to that of aqueous solution.

Photodegradation stability study of PVDF- and PEI-based membranes for oily wastewater treatment process

  • Ong, C.S.;Lau, W.J.;Al-anzi, B.;Ismail, A.F.
    • Membrane and Water Treatment
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    • 제8권3호
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    • pp.211-223
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    • 2017
  • In this work, an attempt was made to compare the effects of UV irradiation on the intrinsic and separation properties of membranes made of two different polymeric materials, i.e., polyvinylidene fluoride (PVDF) and polyetherimide (PEI). The changes on membrane structural morphologies and chemical characteristics upon UV-A exposure (up to 60 h) were studied by FESEM and FTIR, respectively. It was found that cracks and fractures were detected on the PVDF-based membrane surface when the membrane was exposed directly to UV light for up to 60 h. Furthermore, the mechanical strength and thermal stability of irradiated PVDF-based membrane was reported to decrease with increasing UV exposure time. The PEI membrane surface meanwhile remained almost intact throughout the entire UV irradiation process. Filtration experiments showed that the permeate flux of UV-irradiated PVDF membrane was significantly increased from approximately 11 to $16L/m^2.h$ with increasing UV exposure time from zero to 60 h. Oil rejection meanwhile was decreased from 98 to 85%. For the PEI-based membrane, oil rejection of >97% was recorded and its overall structural integrity was marginally affected throughout the entire UV irradiation process. The findings of this work showed that the PEI-based membrane should be considered as the host for photocatalyts incorporation if the membrane was to be used for UV-assisted wastewater treatment process.

세척제에 의한 상아류 유물의 안정성 평가 연구 (Stability Assessment of Ivory Materials by Cleaning Agents)

  • 강대일;이병주;이희정
    • 보존과학회지
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    • 제28권3호
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    • pp.229-233
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    • 2012
  • 본 연구에서는 상아 시편에 습식 세척과 약산을 통한 색상 회복 처리를 실시하고, 이에 대한 안정성 평가를 실시하였다. 사용된 상아 시편은 블랙라이트와 능형무늬 분석을 통해 진위여부를 확인하였다. 습식 세척제로는 상아 및 골각류 유물 처리에 주로 사용되는 증류수, 에틸알코올, 아세톤으로 처리하였으며, 세척 결과 표면관찰, 중량 측정, 색도 측정에서 특별한 변화가 관찰되지 않았다. 약산을 통한 색상 회복 실험에서는 UV-A, UV-B, UV-C 세 가지 파장 하에서 1주일간 인공 열화 시킨 시편을 대상으로 약산 용액인 2%와 5%로 희석된 아세트산 용액과 레몬즙을 이용해서 처리하였다. 처리 결과, 모든 시편에서 표면에 균열과 공극이 관찰되었으며, 레몬즙을 사용한 경우 시편의 색이 붉게 변색되어 유물에 적용이 불가능하다고 판단된다.