• Title/Summary/Keyword: UV emission

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Escape of LyC and Lyα Photons from Simulated Turbulent Clouds

  • Kimm, Taysun;Blaizot, Jeremy;Garel, Thibault;Michel-Dansac, Leo;Katz, Harley;Rosdahl, Joakim;Verhamme, Anne;Haehnelt, Martin
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.73.2-73.2
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    • 2019
  • Understanding how ionizing radiation propagates from molecular clouds to the intergalactic space is the key to the study of reionization and the emergence of $Ly{\alpha}$ emission from galaxies. In this contribution, I will present our new efforts to better understand the escape of UV photons from turbulent clouds with different masses, star formation efficiencies, and spectral energy distributions using radiation-hydrodynamic simulations. I will also show predicted Lya profiles from turbulent clouds and discuss a few interesting differences identified when compared with the properties of the local green pea galaxies.

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Time-resolved UV Fluorescence Spectroscopy of Aorta and its Related Chromophores, Collagen and Elastin, Using 320 nm Excitaion

  • Park, Young D.
    • Bulletin of the Korean Chemical Society
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    • v.15 no.3
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    • pp.249-256
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    • 1994
  • Fluorescence time decay of human aorta has been measured at 380, 440, 480 nm using 320 nm excitation and time-correlated single photon counting technique. Fluorescence decay was found to be nonexponential at all emission frequencies. The normal and diseased sample showed significantly different fluorescence behaviors at 380 nm while this time decay difference was decreased in the fluorescence at 440 and 480 nms. The decay data were multiexponential and were analyzed with two exponential decay constants. The fluorescence decays were compared with and analyzed in terms of collagen and elastin.

Synthesis of CaZrO3 : Eu3+ phosphor by skull melting method (스컬용융법에 의한 CaZrO3 : Eu3+ 형광체 합성)

  • Choi, Hyunmin;Kim, Youngchool;Seok, Jeongwon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.131-135
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    • 2020
  • Single crystal phased CaZrO3 : Eu3+ phosphor have been synthesized by skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were investigated XRD (X-ray diffraction), SEM (scanning electron microscopy), UV (ultraviolet) fluorescence reaction and PL (photo luminescence). The starting materials having chemical composition of CaO: ZrO2 : Eu2O3= 0.962 : 1.013 : 0.025 mol% were charged into a cold crucible. The cold crucible was 120 mm in inner diameter and 150 mm in inner height, and 3 kg of mixed powder (CaO, ZrO2 and Eu2O3) was completely melted within 1 hour at an oscillation frequency of 3.4 MHz, maintained in the molten state for 2 hours, and finally air-cooled. The XRD results show that synthesized phosphor is stabilized in orthorhombic perovskite structure without any impurity phases. The synthesized phosphor could be excited by UV light (254 or 365 nm) and the emission spectra results indicated that bright red luminescence of CaZrO3 : Eu3+ due to magnetic dipole transition 5D07F2 at 615 nm was dominant.

Luminescence characterization of $EU^{3+}$ and $Bi^{3+}$ co-doped in ${Y_2}{SiO_5}$ red emitting phosphor by solid state reaction method (고상 반응법으로 합성한 ${Y_2}{SiO_5}:\;EU^{3+}$, $Bi^{3+}$ 적색 형광체의 발광 특성)

  • Moon, J.W.;Song, Y.H.;Park, W.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.15-18
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    • 2009
  • To enhance near UV-visible absorption region and to applied phosphor convert-white LEOs (PC-WLEDs), a red phosphor composed of ${Y_2}{SiO_5}:\;EU^{3+}$, $Bi^{3+}$ compounds was prepared by the conventional solid-state reaction. The photoluminescence (PL) shown that samples were excited by near UV light 395 nm for measurement of PL spectra. Emission spectra of samples have shown red emissions at 612 nm ($^5D_0{\to}^7F_2$). The enhanced near $UV{\sim}$ visible excitation spectrum with a broad band centered at 258 nm and 282 nm originated in the transitions toward the charge transfer state (CTS) due to the $Eu^{3+}-Bi^{3+}-O^{2-}$ interaction. The other excitation band at $350\;nm{\sim}480\;nm$, corresponding to the transitions $^7F_0{\to}^5L_9$ (364 nm), $^7F_0{\to}^5G_3$ (381 nm), $^7F_0{\to}^5L_6$ (395 nm), $^7F_0{\to}^5D_3$, (415 nm) and $^7F_0{\to}^5D_2$ (466 nm), occurred due to enhanced the f-f transition increasing $Bi^{3+}$ and $Eu^{3+}$ ions. The PL intensity increased with increased as concentration of $Bi^{3+}$ and the emission intensity becomes with a maximum at 0.125 mol.

A Study on the Cleanliness Evaluation Methods for the Selection of Alternative Cleaning Agents (대체 세정제의 선정을 위한 세정성 평가방법 연구)

  • Shin, Jin-Ho;Lee, Jae-Hoon;Bae, Jae-Heum;Lee, Min-Jae;Hwang, In-Gook
    • Clean Technology
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    • v.15 no.2
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    • pp.81-90
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    • 2009
  • In this study various cleaning evaluation methods were tested and comparatively evaluated to help cleaning industry. In order to select alternative cleaning agents objectively and systematically, various cleaning evaluation methods such as gravimetric, optically simulated electron emission (OSEE), contact angle, and analytical instrument methods were employed for cleaning contaminants such as flux, solder and grease. The analytical instruments used in this work were Fourier transform infrared spectroscopy (FTIR), ultraviolet visible spectroscopy (UV-VIS) and high performance liquid chromatography (HPLC). The gravimetric method was able to measure cleaning efficiencies easily and simply, but it was not easy to analyze them precisely because of its limitation in the gravimetric measurement. However, the OSEE technique was able to measure quickly and precisely the clean ability of cleaning agents in comparison with the gravimetric method. The contact angle method was found to be necessary for taking special precaution in its application to the cleaning evaluation due to possible formation of tiny organic film on the substrate surface which might be generated from contaminants and cleaning agents. In case of precision analysis that cannot be done by gravimetric method, fine analytical instruments such as UV-VIS, FTIR and HPLC could be used in analyzing trace amount of flux, solder and grease quantitatively, which were extracted from the surface by special solvents.

Optical emission analysis of hybrid air-water discharges

  • Pavel, Kostyuk;Park, J.Y.;Han, S.B.;Koh, H.S.;Gou, B.K.;Lee, H.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.521-522
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    • 2006
  • In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen yield. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates, and point-to-plane electrode gap distance. The primary focus of this experiment was put on the optical emission of the near UV range, with the energy threshold sufficient for water dissociation and excitation. The $OH(A^{2+},'=0\;X^2,"=0$) band's optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. In the gaseous atmosphere saturated with water vapor the OH(A-X) band intensity was relatively high compared to the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. In the gaseous phase discharge phenomenon for Ar carrier gas transformed into a gliding arc via the flow rate growth. OH(A-X) band's intensity increased according to the flow rate or residence time of He feeding gas. Reciprocal tendency was acquired for $N_2$ and Ar carrier gases. The peak value of OH(A-X) intensity was observed in the proximity of the water surface, however in the cases of Ar and $N_2$ with 0.5 SLM flow rate peaks shifted to the region below the water surface. Rotational temperature ($T_{rot}$) was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which corresponds to the arc-like-streamer discharge.

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Photoluminescence properties of eight coordinated terbium(III) complexes (8배위 터븀 (III) 착화합물의 합성과 Photoluminescence 특성)

  • Yun, Myung-Hee;Kim, Yeon-Hee;Choi, Won-Jong;Chang, Choo-Hwan;Choi, Seong-Ho
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.451-459
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    • 2011
  • Eight coordinated terbium(III) complexes, tris (2-pyrazinecarboxylato)(phenanthroline) terbium(III) [$Tb(pzc)_3$(phen)], tris (5-methyl-2-pyrazinecarboxylato) (phenanthroline) terbium(III) [$Tb(mpzc)_3$(phen)] and tris(2-picolinato) (phenanthroline) terbium(III) [$Tb(pic)_3$(phen)], have been synthesized and characterized by Fourier transform infrared (FT-IR), UV-Visible and X-ray photoelectron spectroscopy. Photoluminescence (PL) spectroscopy shows that these complexes emitted strong green luminescence. When powder samples of the $Tb^{3+}$ complexes are examined using time-resolved spectroscopic analysis, the luminescence lifetimes are found to be 0.87 ms and 1.0 ms, respectively. Thermogravimetric analysis reveals the terbium complexes to have good thermal stability up to $333-379^{\circ}C$. Cyclic voltammetry shows that HOMO-LUMO energy gap of the $Tb^{3+}$ complexes ranges from 4.26~4.41 eV. These values are similar to those obtained from the UV-visible spectra. Overall, the synthesized $Tb^{3+}$ complexes may be useful advanced materials for green light emitting devices.

UV 처리에 의해 표면 산화 처리한 Silver Oxide 박막의 결정 변화에 따른 Nano Mechanics 특성 연구

  • Lee, Gyu-Yeong;Kim, Seong-Jun;Song, Ji-Eun;Kim, Su-In;Lee, Chang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.506-506
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    • 2013
  • Ag (Silver) 박막은 낮은 전기 저항과 높은 가시광대의 반사율을 가져 T-OLED (Top Emission-Organic Light Emitting Diode)의 Anode로 각광 받고 있지만, 일반적인 Ag 박막의 일함수는 4.3 eV 이하로 T-OLED의 Anode로 사용하기에는 낮은 단점이 있다. 따라서 이를 극복하기 위한 방법으로 Ag 박막 표면을 산화시켜 일함수를 증가시키기 위한 연구가 진행중에 있다. 하지만 연구는 단순히 일함수를 증가시키는 것에 한정되어 있을 뿐 UV 처리된 박막의 nano-mechanics 특성에 대한 연구는 현재 전무하다. 따라서 본 연구에서는 순도 99.9%의 Ag 타겟을 이용하여 rf magnetron sputter 장비를 통해 Ag 박막을 증착 하였고, 이후 UV (Ultra-Violet) 램프를 통해 시료 표면을 산화시켰다. 특히, 이 논문의 주요 관심사인 박막의 nano mechanics 특성 분석을 위하여 nano indenter와 SPM (Scanning Probe microscope) 장치를 활용 하였다. 실험 결과 후처리 시간이 3분 이하인 경우 박막이 비결정질의 silver oxide로 성장하는 것을 확인하였으며, 이때 박막의 면저항은 $0.16{\Omega}$/sq.에서 $0.55{\Omega}$/sq.로 증가하는 것을 관찰할 수 있었고, 3분 이후, 비결정질의 silver oxide가 conducting 특성을 갖는 silver oxide 결정을 이루면서 면저항이 $0.55{\Omega}$/sq.에서 $0.21{\Omega}$/sq.로 감소하는 것을 보았다. 또한 결정질의 박막이 자라는 3분이상의 박막에서 surface hardness는 급격하게 증가($3.57{\rightarrow}9.47$ GPa)했으며, 6분 이후에는 감소하는($9.47{\rightarrow}3.46$ GPa) 경향을 보였다. 이러한 경향은 silver oxide의 결정 크기가 Ag 결정 보다 크므로 상대적인 압축응력을 받아 표면 경도가 증가됐다. 처리시간 6분 이후, 경도 감소는 박막의 표면 물성이 불안정해졌기 때문이다.

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Development of Shading Tape for Manufacturing of Touch Panel Display with High Screen-to-Body Ratio (기기 면적 대비 높은 화면 비율을 갖는 터치 패널 디스플레이 제조를 위한 차광 테이프의 개발)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • v.7 no.4
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    • pp.75-81
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    • 2017
  • The design trend of information technology is quickly changed with the times. The design trend of information display is a bezel-less display, recently. The bezel-less display or edge-less display is a new trend of mobile phone display. In this study, the shading tape was manufactured for assembling process of touch panel display with the high screen-to-body ratio so-called bezel-less display. The shading tape was fabricated on PET film with the UV curable acrylic pressure sensitive adhesive(PSA) by roll-to-roll process. The UV curable PSA was synthesized with the eco-friendly toluene-less manufacturing method. The adhesive power of manufactured shading tape was investigated by motorized tensile testing machine. The thixotropic, maintaining property of cutting shape, was characterized by field emission scanning electron microscope. As results, the shading tape exhibits high adhesive power and good thixotropic performance suitable for assembly process of touch panel display. The functional shading tape will be expected to improve productivity of assembly process of touch panel display.

Fabrication and performance evaluation of ultraviolet photodetector based on organic /inorganic heterojunction

  • Abdel-Khalek, H.;El-Samahi, M.I.;Salam, Mohamed Abd-El;El-Mahalawy, Ahmed M.
    • Current Applied Physics
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    • v.18 no.12
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    • pp.1496-1506
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    • 2018
  • Organic/inorganic ultraviolet photodetector was fabricated using thermal evaporation technique. Organic/inorganic heterojunction based on thermally evaporated copper (II) acetylacetonate thin film of thickness 200 nm deposited on an n-type silicon substrate is introduced. I-V characteristics of the fabricated heterojunction were investigated under UV illumination of intensity $65mW/cm^2$. The diode parameters such as ideality factor, n, barrier height, ${\Phi}_B$, and reverse saturation current, $I_s$, were determined using thermionic emission theory. The series resistance of the fabricated diode was determined using modified Nord's method. The estimated values of series resistance and barrier height of the diode were about $0.33K{\Omega}$ and 0.72 eV, respectively. The fabricated photodetector exhibited a responsivity and specific detectivity about 9 mA/W and $4.6{\times}10^9$ Jones, respectively. The response behavior of the fabricated photodetector was analyzed through ON-OFF switching behavior. The estimated values of rise and fall time of the present architecture under UV illumination were about 199 ms and 154 ms, respectively. Finally, enhancing the photoresponsivity of the fabricated photodetector, post-deposition plasma treatment process was employed. A remarkable modification of the device performance was noticed as a result of plasma treatment. These modifications are representative in a decrease of series resistance and an increase of photoresponsivity and specific detectivity. The process of plasma treatment achieved an increment of external quantum efficiency from 5.53% to 8.34% at -3.5 V under UV illumination.