• 제목/요약/키워드: Tri-layer

검색결과 88건 처리시간 0.028초

Synthesis and Tribological Behavior of Nanocomposite Polymer Layers

  • Tsukruk, V.V.;Ahn, Hyo-Sok;Julthongpiput, D.;Kim, Doo-In
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.51-52
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    • 2002
  • We report results on microtribological studies of chemically grafted nanoscale polymer layers of different architecture with thickness below 30 nm. We have fabricated the molecular lubrication coatings from elastomeric tri-block copolymers and tested two different designs of corresponding nanocomposite coatings. We observed a significant reduction of friction forces and an increase of the wear stability when a minute amount of oil was trapped within the grafted polymer layer. These polymer gel layers exhibited a very steady friction response and a small value of the coefficient of friction as compared to the initial polymer coating. A polymer 'triplex' coating has been formed by a multiple grafting technique. The unique design of this layer Includes a hard-soft-hard architecture with a compliant rubber interlayer mediating localized stresses transferred through the topmost hard layer. This architecture provides a non-linear mechanical response under a normal compression stress and allows additional dissipation of mechanical energy via the elastic rubber interlayer.

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Population Dynamics of Pinus densiflora for. erecta at Sokwang-Ri, Uljin-Gun in Southeastern Korea

  • Yun, Chung-Weon;Bae, Kwan-Ho;Hong, Sung-Cheon
    • The Korean Journal of Ecology
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    • 제24권6호
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    • pp.341-348
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    • 2001
  • Population dynamics of the oldest relic stand of Pinus densiflora for. erecta which remains as a status of patch in Sokwang-Ri area, Uljin-Gun, was studied to provide the basic data for conservation of the oldest pine stand in Korea. The upper slope site and ridge site including total 12 plots mainly represented Pinus densiflora for. erecta and Quercus mongolica. These two tree species showed reverse J-shaped distribution. From this information, it was concluded that intensive interspecific competition between two species could be occurring. Age distribution of P. densiflora for. erecta on the sites above middle slope area was indicated bi-modal type or tri-modal type which was known as an age structure of climax forest. Therefore, it was estimated that Pinus densiflora for. erecta population could be continuously maintained in the each patch above middle slope area. In the valley sites, hardwood species such as Q. mongolica, Q. variabilis, Styrax obassia and Acer pseudosieboldianum occupied most part of the under crown-cover area and their seedlings and saplings were developing into the closed upper layer crown because the height of upper layer crown reached about 35 meters and such a high crown height was more suitable for light utilization by plants of under layer. The growth patterns were mainly fluctuated for the entire life time of the oldest tree caused by frequent disturbance. And the initial growth curves of the mature trees and suppressed juvenile trees showed different tendencies along the sites.

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F4-TCNQ 분자를 정공 수송층에 이용한 유기 발광 소자의 전기적 특성 향상 (Enhancement of Electrical Properties of Organic Light-Emitting Diodes Using F4-TCNQ Molecule as a Hole-Transport Layer)

  • 나수환;이원재
    • 한국전기전자재료학회논문지
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    • 제30권11호
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    • pp.717-721
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    • 2017
  • We studied the performance enhancement of organic light-emitting diodes (OLEDs) using 2,3,5,6-fluoro-7,7,8,8-tetracyanoquinodimethane ($F_4-TCNQ$) as the hole-transport layer. To investigate how $F_4-TCNQ$ affects the device performance, we fabricated a reference device in an ITO (170 nm)/TPD(40 nm)/$Alq_3$(60 nm)/LiF(0.5 nm)/Al(100 nm) structure. Several types of test devices were manufactured by either doping the $F_4-TCNQ$ in the TPD layer or forming a separate $F_4-TCNQ$ layer between the ITO anode and TPD layer. N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD), tri(8-hydroxyquinoline) aluminum ($Alq_3$), and $F_4-TCNQ$ layers were formed by thermal evaporation at a pressure of $10_{-6}$ torr. The deposition rate was $1.0-1.5{\AA}/s$ for TPD and $Alq_3$. The LiF was subsequently thermally evaporated at a deposition rate of $0.2{\AA}/s$. The performance of the OLEDs was considered with respect to the turn-on voltage, luminance, and current efficiency. It was found that the use of $F_4-TCNQ$ in OLEDs enhances the performance of the device. In particular, the use of a separate layer of $F_4-TCNQ$ realizes better device performance than other types of OLEDs.

BAC 공정에서 운전기간 및 여층깊이 변화에 따른 생물막 생체량 및 용존유기물질 생분해 특성 평가 (Evaluation of Biomass of Biofilm and Biodegradation of Dissolved Organic Matter according to Changes of Operation Times and Bed Depths in BAC Process)

  • 손형식;정철우;최영익;이건;손희종
    • 한국환경과학회지
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    • 제23권6호
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    • pp.1101-1109
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    • 2014
  • In this study we followed biofilm formation and development in a granular activated carbon (GAC) filter on pilot-scale during the 12 months of operation. GAC particles and water samples were sampled from four different depths (-5, -25, -50 and -90 cm from surface of GAC bed) and attached biomass were measured with adenosine tri-phosphate (ATP) analysis and heterotrophic plate count (HPC) method. The attached biomass accumulated rapidly on the GAC particles of top layer throughout all levels in the filter during the 160 days (BV 23,000) of operation and maintained a steady-state afterward. During steady-state, biomass (ATP and HPC) concentrations of top layer in the BAC filer were $2.1{\mu}g{\cdot}ATP/g{\cdot}GAC$ and $3.3{\times}10^8cells/g{\cdot}GAC$, and 85%, 83% and 99% of the influent total biodegradable dissolved organic carbon ($BDOC_{total}$), $BDOC_{slow}$ and $BDOC_{rapid}$ were removed, respectively. During steady-state process, biomass (ATP and HPC) concentrations of middle layer (-50 cm) and bottom layer (-90 cm) in the BAC filter were increased consistently. Biofilm development (growth rate) proceed highest rate in the top layer of filter (${\mu}_{ATP}=0.73day^{-1}$; ${\mu}_{HPC}=1,74day^{-1}$) and 78%~87% slower in the bottom layer (${\mu}_{ATP}=0.14day^{-1}$; ${\mu}_{HPC}=0.34day^{-1}$). This study shows that the combination of different analytical methods allows detailed quantification of the microbiological activity in drinking water biofilter.

시안기를 가진 유기 EL 물질들의 합성 및 유기 EL 소자에서의 발광특성평가 (Synthesis of Organic EL Materials with Cyano Group and Evaluation of Emission Characteristics in Organic EL Devices)

  • 김동욱
    • 대한화학회지
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    • 제43권3호
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    • pp.315-320
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    • 1999
  • 고성능 전계발광(electroluminescent, EL) 소자에 사용되는 발광물질의 개발을 위하여 설계된 발광기능기의 분자구조는 비스스틸렌구조의 발광기능기에 전자주입과 수송을 위한 시안기와 정공주입과 수송을 위한 페닐아민기를 가진 구조이다. 위의 발광기능기로 구성 된 고분자물질, PU-BCN과 저분자물질, D-BCN을 합성하였다. PU-BCN과 D-BCN을 발광층으로 사용하여 만들어진 단층형 소자(SL)의 구조는 Indium-tin oxide(ITO)/발광층/MgAg이고, 적층형소자의 구조는 ITO/발광층/oxadiazole dehvative/MgAg, (DL-E)와 ITO/tri-phenylamine derivative/발광층/MgAg,(DL-H)의 두 종류이다. 동일한 발광기능기를 가진 고분자 발광물질, PU-BCN과 저분자발광물질, D-BCN은 전하주입과 수송성이 띄어난 물질로 평가되었으며, 두 발광물질들은 높은 전류밀도하에서 거의 동일한 발광특성을 보였다. 발광물질들의 최대 발광 피이크는 약 640 nm의 적색 발광영역에서 측정되었다.

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Remote O2 plasma functionalization for integration of uniform high-k dielectrics on large area synthesized few-layer MoSe2

  • Jeong, Jaehun;Choi, Yoon Ho;Park, Dambi;Cho, Leo;Lim, Dong-Hyeok;An, Youngseo;Yi, Sum-Gyun;Kim, Hyoungsub;Yoo, Kyung-Hwa;Cho, Mann?Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.281.1-281.1
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    • 2016
  • Transition metal dichalcogenides (TMDCs) are promising layered structure materials for next-generation nano electronic devices. Many investigation on the FET device using TMDCs channel material have been performed with some integrated approach. To use TMDCs for channel material of top-gate thin film transistor(TFT), the study on high-k dielectrics on TMDCs is necessary. However, uniform growth of atomic-layer-deposited high-k dielectric film on TMDCs is difficult, owing to the lack of dangling bonds and functional groups on TMDC's basal plane. We demonstrate the effect of remote oxygen plasma pretreatment of large area synthesized few-layer MoSe2 on the growth behavior of Al2O3, which were formed by atomic layer deposition (ALD) using tri-methylaluminum (TMA) metal precursors with water oxidant. We investigated uniformity of Al2O3 by Atomic force microscopy (AFM) and Scanning electron microscopy (SEM). Raman features of MoSe2 with remote plasma pretreatment time were obtained to confirm physical plasma damage. In addition, X-ray photoelectron spectroscopy (XPS) was measured to investigate the reaction between MoSe2 and oxygen atom after the remote O2 plasma pretreatment. Finally, we have uniform Al2O3 thin film on the MoSe2 by remote O2 plasma pretreatment before ALD. This study can provide interfacial engineering process to decrease the leakage current and to improve mobility of top-gate TFT much higher.

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피복입자핵연료에서 증착조건이 탄화규소층의 특성에 미치는 영향 (Effect of Deposition Parameters on the Property of Silicon Carbide Layer in Coated Particle Nuclear Fuels)

  • 김연구;김원주;여승환;조문성
    • 한국분말재료학회지
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    • 제23권5호
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    • pp.384-390
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    • 2016
  • Tri-isotropic (TRISO) coatings on zirconia surrogate beads are deposited using a fluidized-bed vapor deposition (FB-CVD) method. The silicon carbide layer is particularly important among the coated layers because it acts as a miniature pressure vessel and a diffusion barrier to gaseous and metallic fission products in the TRISO-coated particles. In this study, we obtain a nearly stoichiometric composition in the SiC layer coated at $1400^{\circ}C$, $1500^{\circ}C$, and $1400^{\circ}C$ with 20 vol.% methyltrichlorosilane (MTS), However, the composition of the SiC layer coated at $1300-1350^{\circ}C$ shows a difference from the stoichiometric ratio (1:1). The density decreases remarkably with decreasing SiC deposition temperature because of the nanosized pores. The high density of the SiC layer (${\geq}3.19g/cm^2$) easily obtained at $1500^{\circ}C$ and $1400^{\circ}C$ with 20 vol.% MTS did not change at an annealing temperature of $1900^{\circ}C$, simulating the reactor operating temperature. The evaluation of the mechanical properties is limited because of the inaccurate values of hardness and Young's modulus measured by the nano-indentation method.

셀룰로오스에 의한 지지체 친수화가 압력지연삼투막 성능에 미치는 영향 (Hydrophilizing Effect of Support on PRO Membrane Performance through Cellulose Solution Treatment)

  • 최명호;구기갑;임정애;김범식
    • 멤브레인
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    • 제23권6호
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    • pp.425-431
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    • 2013
  • 본 연구의 목적은 지지체의 친수화가 압력지연삼투(Pressure retarded osmosis, PRO)막의 투과특성에 미치는 영향에 대해서 알아보고자 하였다. 소수성 지지체인 폴리에스테르를 친수성 고분자인 셀룰로오스 용액을 사용하여 친수화도를 조절하였다. 지지체의 친수화 특성만을 파악하기 위해서 지지층 없이 동일한 활성층을 사용하여 PRO 막 투과 특성을 비교하였다. 사용된 활성층은 1,4-dioxane과 cellulose tri-acetate (CTA, 13 wt%)를 사용하여 제조하였으며, $5kgf/cm^2$ 압력 하에서 행한 PRO 성능 평가의 경우 투과도가 친수화된 지지체를 사용한 경우와 친수화되지 않은 경우에 각각 $1.2L/m^2hr$$0.8L/m^2hr$로 친수화된 지지체를 사용할 경우 약 50% 투과량이 증가되는 특성을 보였다. 그러나 셀룰로오스 농도 변화에 따른 지지체의 친수화도 증가가 투과량 변화를 가져오지는 않았다. 이는 지지체를 친수화하기 위해 사용된 셀룰로오스의 농도가 증가함에 따라 지지체의 기공이 막히는 현상에 기인한 것으로 보인다. 이러한 결과를 통해 정삼투공정에서 투과유량을 높이기 위해서는 지지체로서 친수성 소재를 사용하여 분리막을 제조함과 동시에 지지체 기공을 유지하는 것이 중요함을 확인하였다.

동해남부 대마난류계에서의 염소화 Biphenyls의 분포특성 (Distribution Chara Cteristics of Polychlorinated Biphenyls in the Southern Korea)

  • 이동인;옥곤;양한섭;장윤석
    • 한국수산과학회지
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    • 제30권4호
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    • pp.679-686
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    • 1997
  • 본 연구조사는 동해남부 대마난류계에서의 PCBs의 분포특성을 파악하기 위하여 1996년 8월과 10월에 걸쳐 5개 정점을 선정하여 각 정점의 수심별의 수온, 염분 및 용존산소를 측정하여 수괴 분석을 실시하였으며, 또한, 각 정점별, 수심별의 PCBs의 분석을 실시하였다. 수괴의 분포특성을 조사한 결과 수온 및 염분약층은 수심 30m부분에 존재하고 있었으며, 대마난류 중층수는 30m이하로 간주되었으며, 대마난류의 표층수는 한국근해에서 대마도쪽으로 확장되는 양상을 보였다. PCBs의 분석결과 표층수는 8월의 경우 대마도쪽으로 갈수록 농도가 약간 낮아지는 경향을 보이다가, 대마도쪽에서 다시 약간의 증가경향이 관찰되었다. 표층 해수중에서의 PCBs의 평균농도는 $0.29\;ng/\ell$정도 였으며, 중층에서의 평균농도는 $0.31\;ng/\ell$정도로 표층에 비교하여 중층에서의 농도가 약간 증가하는 것으로 나타났다. 해수중 PCBs의 농도는 부유물질의 농도변화 경향과 유사성을 나타났으며, 농도의 수평 및 연직변화는 그다지 크게 나타나지 않아 비교적 균일한 농도분포를 나타내고 있었다. 해수의 수심별 PCBs의 상대농도 조성비는 표층에서 Di- 및 Tri-PCBs의 비율이 높았지만, 심층으로 갈수록 Peta-PCBs의 상대농도 조성비율이 높은 것으로 나타나, 수심의 변화에 따른 PCBs의 구성비와 소실에 차이가 있는 것으로 사료된다.

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Dependence of Light-Emitting Characteristics of Blue Phosphorescent Organic Light-Emitting Diodes on Electron Injection and Transport Materials

  • Lee, Jeong-Ik;Lee, Jonghee;Lee, Joo-Won;Cho, Doo-Hee;Shin, Jin-Wook;Han, Jun-Han;Chu, Hye Yong
    • ETRI Journal
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    • 제34권5호
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    • pp.690-695
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    • 2012
  • We investigate the light-emitting performances of blue phosphorescent organic light-emitting diodes (PHOLEDs) with three different electron injection and transport materials, that is, bathocuproine(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline) (Bphen), 1,3,5-tri(m-pyrid-3-yl-phenyl)benzene (Tm3PyPB), and 2,6-bis(3-(carbazol-9-yl)phenyl)pyridine (26DCzPPy), which are partially doped with cesium metal. We find that the device characteristics are very dependent on the nature of the introduced electron injection layer (EIL) and electron transporting layer (ETL). When the appropriate EIL and ETL are combined, the peak external quantum efficiency and peak power efficiency improve up to 20.7% and 45.6 lm/W, respectively. Moreover, this blue PHOLED even maintains high external quantum efficiency of 19.6% and 16.9% at a luminance of $1,000cd/m^2$ and $10,000cd/m^2$, respectively.