• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1998년도 춘계학술발표회 초록집
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• pp.3-3
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• 1998

The atmospheric corrosIOn properties of Zinc (Zn) under wet/dry transition of $H_20$ film were investigated in this study. The atmospheric corrosion of metal is usually occurred as a result of repetitious thickness transition (so called wet/dry transition) of liquid phase which is covering the metal surface. Corrosion potential and the polarization behaviour of Zn during liquid film thickness transition were measured by Kelvin probe method which IS using vibrating reference electrode without touching the liquid film. The oxidized states of Zn as a result of successive wet/dry transition were also investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the corrosion potential and the corrosIOn rate of Zn both are increasing during drying. However, the corrOSIon rate is decreasing again when the Zn surface is completely dried while the corrosion potential still remains high. This behaviour can be explained by the polarization behaviour change of Zn according to the $H_20$ film thickness change. The completely dried surface is consisted mostly with Zn and ZnO phases. After a number of cycles of wet/dry transition, however, the oxidized Zn phase of ${\varepsilon}-Zn(OH)_2$, which has rather voluminous and defected structure, were found.

• 한국주조공학회지
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• 제14권6호
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• pp.508-513
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• 1994

For Pb-20wt%Cu alloys, severe macrosegregation due to density difference of the resulting phases in normal directional solidification has been minimized and a uniformly aligned dendritic structure has been produced by axially rotating the sample of 5mm diameter in conjunction with horizontal directional solidification. Under the constant growth velocity of $20{\mu}m/sec$, increasing the rotation rate from 0.18 to 12rpm results in a transition from an aligned columnar to an equiaxed Cu-dendritic structure. With a constant rotation rate of 0.18rpm, increasing the growth velocity from 10 to $50{\mu}m/sec$ also has promoted a transition from columnar to equiaxed structure.

• Bulletin of the Korean Chemical Society
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• 제24권8호
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• pp.1215-1218
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• 2003

An analysis of the bonding situation in CaM₂P₂ (M=Fe, Ni) with ThCr₂Si₂ structure is made in terms of DOS and COOP plots. The main contributions to covalent bonding are due to M-P and P-P interactions in both compounds. Particularly, the interlayer P-P bonding by variation in the transition metal is examined in more detail. It turns out that the shorter P-P bonds in CaNi₂P₂ form as a result of the decreasing electron delocalization into ${{\sigma}_p}^*$ of P₂ due to the weaker bonding interaction between the metal d and ${{\sigma}_p}^*$ as the metal d band is falling from Fe to Ni.

• 한국세라믹학회지
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• 제26권5호
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• pp.670-676
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• 1989

The PbTiO3 is well known materials having remarkable ferroelectric, piezoelectric, and pyroelectric properties. PbTiO3 thin films with a perovskite structure were successfully fabricated on titanium substrate by chemical vapor deposition. These films were characterized according to composition, crystal structure, and electrical properties. Semi-quantitative compositional analysis of the deposited films was made by Auger Electron Spectroscopy(AES). The PbTiO3 film deposited on titanium substrate at the deposition temperature 75$0^{\circ}C$, the Ti(C2H5O)4 fraction 0.15, and O2 partial pressure 0.06atm, has a columnar structure and grows with(001) preferred orientation, and has stoichiometric composition. A clear dielectric transition and offset in the dc conductivity near the transition temperature(48$0^{\circ}C$) were observed in the deposited lead titanate film.

• 한국소음진동공학회논문집
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• 제15권9호
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• pp.1053-1059
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• 2005

Dynamic stability of an axially accelerating beam structure is investigated in this paper. The equations of motion of a fixed-free beam are derived using the hybrid deformation variable method and the assumed mode method. Unstable regions due to periodical acceleration are obtained by using the Floquet's theory. Stability diagrams are presented to illustrate the influence of the dimensionless acceleration, amplitude, and frequency. Also, buckling occurs when the acceleration exceeds a certain value. It is found that relatively large unstable regions exist around the first bending natural frequency, twice the first bending natural frequency, and twice the second bending natural frequency. The validity of the stability diagram is confirmed by direct numerical integration of the equations of motion.

• 건축역사연구
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• 제13권4호
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• pp.7-18
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• 2004

From the results of an examination of the transition process of the site plan divided into 5 stages based on literature and materials relating to the Sangju Confucian School as well as the construction history, we can see the general transition flow as follows. The arrangement form of Sangju Confucian School shows the structures with both the sacrificial rites function and the learning function in the early period. This shows a large general flow where the form with the learning function structure at the front and sacrificial rites function structure at the back changed to a form where the learning function structure was positioned behind the boarding facilities, after which there was a transformation which left only the learning function (the form where the learning function structure was positioned in front of the boarding facilities). The type where the learning function structure is positioned in front of the boarding facilities is hard to find in the Yeongnam area, also, there are not many examples of the 2 story Myeonglyundang (hall of confucianism teachings) throughout the country Sangju Confucian School which possess the value of rarity is appraised as being a precious material showing another area characteristic in Sangju of the Yeongnam area. Also, during the late Chosun period the scale of the Dongseojae (boarding facility) was reduced and the appearance of Yangsajae can be said to be a typical example of confucian school constructions of late Chosun era.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4161-4164
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• 2012

Density functional MO calculations for the methylsilole anion of $[C_4H_4SiMe]^-$ and methylgermole anion of $[C_4H_4SiMe]^-$ at the B3LYP (full)/6-311+$G^*$ level (GAUSSIAN 94) were carried out and characterized by frequency analysis. The ground state structure for the methylsilole anion and methylgermole anion is that the methyl group is pyramidalized with highly localized structure. The difference between the calculated $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are 9.4 and 11.5 pm, respectively. The E-Me vector forms an angle of $67.9^{\circ}$ and $78.2^{\circ}$ with the $C_4E$ plane, respectively. The optimized structures of the saddle point state for the methylsilole anion and methylgermole anion have been also found as a planar with highly delocalized structure. The optimized $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are nearly equal for both cases. The methyl group is located in the plane of $C_4E$ ring and the angle between the E-Me vector and the $C_4E$ plane for the methylsilole anion and methylgermole anion is $2.0^{\circ}$ and $2.3^{\circ}$, respectively. The energy difference between the ground state structure and the transition state structure is only 5.1 kcal $mol^{-1}$ for the methylsilole anion. However, the energy difference of the methylgermole anion is 14.9 kcal $mol^{-1}$, which is much higher than that for the corresponding methylsilole monoanion by 9.8 kcal $mol^{-1}$. Based on MO calculations, we suggest that the head-to-tail dimer compound, 4, result from [2+2] cycloaddition of silicon-carbon double bond character in the highly delocalized transition state of 1. However, the inversion barrier for the methylgermole anion is too high to dimerize.

• 한국재료학회지
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• 제25권11호
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• pp.583-589
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• 2015

This paper presents a study on the room- and low-temperature impact toughness of hypoeutectoid steels with ferrite-pearlite structures. Six kinds of hypoeutectoid steel specimens were fabricated by varying the carbon content and austenitizing temperature to investigate the effect of microstructural factors such as pearlite volume fraction, interlamellar spacing, and cementite thickness on the impact toughness. The pearlite volume fraction usually increased with increasing carbon content and austenitizing temperature, while the pearlite interlamellar spacing and cementite thickness mostly decreased with increasing carbon content and austenitizing temperature. The 30C steel with medium pearlite volume fraction and higher manganese content, on the other hand, even though it had a higher volume fraction of pearlite than did the 20C steel, showed a better low-temperature toughness due to its having the lowest ductile-brittle transition temperature. This is because various microstructural factors in addition to the pearlite volume fraction largely affect the ductile-brittle transition temperature and low-temperature toughness of hypoeutectoid steels with ferrite-pearlite structure. In order to improve the room- and low-temperature impact toughness of hypoeutectoid steels with different ferrite-pearlite structures, therefore, more systematic studies are required to understand the effects of various microstructural factors on impact toughness, with a viewpoint of ductile-brittle transition temperature.

• 한국철도학회논문집
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• 제12권5호
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• pp.678-686
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• 2009

국내에서 개발된 한국형 틸팅열차는 현재 시제차량 제작을 마치고, 충북선을 시작으로 시운전 시험이 단계적으로 진행되고 있다. 시운전 시험에서는 한국형 틸팅열차의 시스템 안정화를 위해 차량 외에 궤도, 구조물, 전차선, 신호 등 각 시스템 상호간의 인터페이스 검증이 필요하며, 선로구축물 분야에서는 개발차량의 증속이 궤도구조에 미치는 영향을 비롯한 궤도부담력 검토를 통해 궤도구조의 안정성과 주행안정성 평가가 수행되어야 한다. 따라서 본 연구에 서는 완화곡선구간을 주행하는 틸팅차량(한빛200호), 고속차량(KTX) 및 일반차량(무궁화)에 의해 궤도에서 발생하는 동적 윤중 및 횡압을 측정하였다. 측정데이터를 통해 차종별 주행패턴을 비교하고 윤중과 횡압의 증감율을 확률적으로 분석하였다. 분석결과, 고정식 대치구조를 갖는 기존 차량의 캔트변화에 따른 발생 윤중 및 횡압의 분포범위는 일정 범위 내에서 작은 편차로 분포하였다. 반면 진자식 대차구조인 틸팅차량의 경우 캔트변화에 따른 차체의 틸팅작용에 의해 비교적 넓은 범위에 큰 편차로 궤도작용력이 분포하는 것으로 나타났다.

• Molecules and Cells
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• 제21권2호
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• pp.229-236
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• 2006

Gaegurin 4 (GGN4), a novel peptide isolated from the skin of a Korean frog, Rana rugosa, has broad spectrum antimicrobial activity. A number of amphipathic peptides closely related to GGN4 undergo a coil to helix transition with concomitant oligomerization in lipid membranes or membrane-mimicking environments. Despite intensive study of their secondary structures, the oligomeric states of the peptides before and after the transition are not well understood. To clarify the structural basis of its antibiotic action, we used analytical ultracentrifugation to define the aggregation state of GGN4 in water, ethyl alcohol, and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). The maximum size of GGN4 in 15% HFIP corresponded to a decamer, whereas it was monomeric in buffer. The oligomeric transition is accompanied by a cooperative 9 nm blue-shift of maximum fluorescence emission and a large secondary structure change from an almost random coil to an ${\alpha}$-helical structure. GGN4 induces pores in lipid membranes and, using electrophysiological methods, we estimated the diameter of the pores to be exceed $7.3{\AA}$, which suggests that the minimal oligomer structure responsible is a pentamer.