• 공업화학
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• 제7권3호
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• pp.580-587
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• 1996

소성법을 이용하여 반응은도 $1050^{\circ}C$, 반응시간 3시간, $K_2CO_3$에 대한 $TiO_2$(rutile)의 mole ratio 2.8 그리고 $1^{\circ}C/min$의 서냉속도로 서냉하여 초생상을 합성하였으며, 이를 비등수로 10시간 처리하여 층상구조를 갖는 장섬유의 $K_2Ti_4O_9$을 효과적으로 합성하였다. 또한 합성된 $K_2Ti_4O_9$의 열적안정성을 조사하였으며, 이 결과 $K_2Ti_4O_9$은 열적으로 매우 불안정하여 온도가 올라감에 따라 $K_2O$와 $K_2Ti_6O_{13}$으로 분리됨을 확인하였다.

• Macromolecular Research
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• 제14권3호
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• pp.272-286
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• 2006

Dendritic hyperbranched poly(methyl methacrylate)s (PMMA)s, whose branched architectures resemble the 'dendron' part(s) of dendrimer, were synthesized by an iterative methodology consisting of two reactions in each iteration process: (a) a coupling reaction of u-functionalized, living, anionic PMMA having two tert-butyldimethylsilyloxymethylphenyl(SMP) groups with benzyl bromide(BnBr)-chain-end-functionalized PMMA, and (b) a transformation reaction of the introduced SMP groups into BnBr functionalities. These two reactions, (a) and (b), were repeated three times to afford a series of dendron-like, hyperbranched (PMMA)s up to third generation. Three dendron-like, hyperbranched (PMMA)s different in branched architecture were also synthesized by the same iterative methodology using a low molecular weight, functionalized 1,1-diphenylalkyl anion prepared from sec-BuLi and 1,1-bis(3-tert-butyldime-thylsilyloxymethylphenyl)ethylene in the reaction step (b) in each iterative process. Furthermore, structurally similar, dendron-like, hyperbranched block copolymers could be successfully synthesized by the iterative methodology using $\alpha$-functionalized, living, anionic poly(2-(perfluorobutyl) ethyl methacrylate) (PRfMA) in addition to $\alpha$-functionalized, living PMMA. Accordingly, the resulting block copolymers were comprised of both PMMA and PRfMA segments with different sequential orders. After the block copolymers were cast into films and annealed, their surface structures were characterized by angle-dependent XPS and contact angle measurements. All three samples showed significant segregation and enrichment of PRfMA segments at the surfaces.

• 대한금속재료학회지
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• 제47권8호
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• pp.488-493
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• 2009

Direct syntheses of bulk $Ti_3Al$ via electro-discharge-sintering (EDS) of a stoichiometric elemental powder mixture were investigated. A capacitor bank of $450{\mu}F$ was charged with three input energies, 0.5, 1.0, and 1.5 kJ. The charged capacitor bank was then instantaneously discharged through 0.3 g of a Ti-25.0 at.%Al powder mixture for consolidation. Complete phase transformation occurred in less than $200{\mu}sec$ by the discharge and a bulk $Ti_3Al$ compact was obtained. Compared with consolidated samples fabricated by conventional methods such as high vacuum sintering and casting, the electro-discharge-sintered $Ti_3Al$ compact shows a very fine microstructure with a hardness value of 425 Hv. Electro-discharge-sintering under a $N_2$ atmosphere successfully modified the surface Ti oxide of the $Ti_3Al$ compact into Ti nitride, which concurred with the synthesis and consolidation of $Ti_3Al$. Complete conversion yielding a single phase $Ti_3Al$ is primarily dominated by the fast solid state diffusion reaction.

• 한국컴퓨터그래픽스학회논문지
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• 제14권2호
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• pp.19-25
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• 2008

이 논문에서는 각기 다른 스케일에서 각각의 구조를 띤 텍스처를 합성하는 기법을 제안한다. 우리의 기법은 GPU로 실시간으로 수행되는 병렬 텍스처 합성 기법에 기반을 두었다. 새로 도입된 좌표 변환 연산자를 이용하면 이미 합성된 좌표 맵을 다른 스케일의 입력 텍스처로의 좌표 공간으로 변환할 수 있다. 이 연산자는 작은 룩업 테이블로 미리 연산될 수 있기 때문에 본 기법을 도입함으로써 생기는 오버헤드는 매우 적다. 우리의 업샘플 기법은 텍스처가 두드러전 이미지의 해상도를 높일 때 특히 유용하다. 그리고, 우리의 기법을 이용하여 저해상도 컨트롤 이미지를 이용한 텍스처 디자인도 가능하다. 이 디자인 툴은 지형을 특정한 스타일로 디자인하는 데에 유용하며 일반적인 높낮이 조절 브러시를 이용할 수 있으므로 직관적이다.

• 융합신호처리학회논문지
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• 제8권4호
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• pp.285-292
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• 2007

SoC는 소프트웨어와 하드웨어가 통합 설계되는 시스템 수준 설계 플랫폼이며 상위 수준 합성은 SoC 설계방법론의 중요한 과정이다. 최근 SPARK라 불리는 병렬 상위 수준 합성 툴이 개발되었다. SPARK는 C코드를 입력받아 코드 이동과 다양한 변형 기술을 이용해서 스케줄하고 최종적으로 합성 가능한 RTL VHDL를 생성한다. 기본 적인 디지털 신호 및 영상처리 알고리즘은 반복 순환문으로 표현되며, 합성을 동해 SPARK는 다양한 루프 변형 알고리즘을 적용한다. 그러나 이 기법에 의한 합성 결과는 디자이너가 수동으로 직접 설계한 최적구현과 비교했을 때 성능 면에서 만족할 만한 결과를 생성하지 못한다. 본 논문에서는 전용 프로그램 논리소자를 가지는 새로운 SoC 플랫폼을 제안하고, C로 기술된 행위 수준 반복 순환문을 2차원 시스톨릭 어레이로 매핑하는 과정을 기술한다. 최종적으로 유도된 시스톨릭 어레이는 제안된 SoC 플랫폼 상의 전용 프로그램 논리소자 상에 구현된다.

• 한국정보과학회논문지:시스템및이론
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• 제28권10호
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• pp.520-529
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• 2001

캐리-세이브 가산기(CSA)는 빠른 수행과 작은 면적을 가지는 연산 하드웨어 구현에서 가장 효과적으로 사용되는 연산 셀들 중의 하나이다. 현재 CSA 적용기술의 근복적인 약점을 그 적용이 덧셈식으로 직접 변환되는 부분에 해당되는 회로에만 가능하다는 것이다. 이러한 제한점을 극복하기위하여, 우리는 새로운 몇가지 CSA 변환 기법들을 제안한다. 구체적으로 멀티플렉서를 포함한 연산에서의 CSA 변환, 다수 회로를 포함한 연산에서의 CSA 변환, 곱셈 연산을 내포한 연산에서의 CSA 변화를 제안한다. 또한 이러한 기법들을 실제의회로 합성에서 효과적으로 적용하는 통합 알고리즘을 제안한다. 우리는 다양한 실험을 통하여 제시된 기법들에 기반한 우리의 알고리즘의 기존의 CSA 방법들과 비교하여 실제적인 회로 합성에서 매우 효율적임을 보인다.

• Journal of Electrical Engineering and Technology
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• 제8권5호
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• pp.1188-1193
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• 2013

In content based image retrieval (CBIR) system, the images are represented based upon its feature such as color, texture, shape, and spatial relationship etc. In this paper, we propose a MRI Image Retrieval using wavelet transform with mahalanobis distance measurement. Wavelet transformation can also be easily extended to 2-D (image) or 3-D (volume) data by successively applying 1-D transformation on different dimensions. The proposed algorithm has tested using wavelet transform and performance analysis have done with HH and $H^*$ elimination methods. The retrieval image is the relevance between a query image and any database image, the relevance similarity is ranked according to the closest similar measures computed by the mahalanobis distance measurement. An adaptive similarity synthesis approach based on a linear combination of individual feature level similarities are analyzed and presented in this paper. The feature weights are calculated by considering both the precision and recall rate of the top retrieved relevant images as predicted by our enhanced technique. Hence, to produce effective results the weights are dynamically updated for robust searching process. The experimental results show that the proposed algorithm is easily identifies target object and reduces the influence of background in the image and thus improves the performance of MRI image retrieval.

• Bulletin of the Korean Chemical Society
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• 제26권4호
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• pp.515-522
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• 2005

Enzyme-metal combo catalysis is described as a useful methodology for the synthesis of optically active compounds. The key point of the method is the use of enzyme and metal in combination as the catalysts for the complete transformation of racemic substrates to single enantiomeric products through dynamic kinetic resolution (DKR). In this approach, enzyme acts as an enantioselective resolving catalyst and metal does as a racemizing catalyst for the efficient DKR. Three kinds of enzyme-metal combinations - lipase-ruthenium, subtilisin-ruthenium, and lipase-palladium –have been developed as the catalysts for the DKRs of racemic alcohols, esters, and amines. The scope of the combination catalysts can be extended to the asymmetric transformations of ketones, enol acetates, and ketoximes via the DKRs. In most cases studied, enzyme-metal combo catalysis provided enantiomerically-enriched products in high yields.

• 대한기계학회논문집B
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• 제32권3호
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• pp.224-230
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• 2008

In this article, $TiO_2$ nanoparticles were synthesized by using $O_2$-enriched coflow, hydrogen, diffusion flames. We investigated the thermal stability of the flame-synthesized $TiO_2$ nanoparticles by examining the crystalline structures of the nanoparticles. Also, the results were compared with those of commercial P-25 nanoparticles. $TiO_2$ nanoparticles, which were spherical with diameters approximately ranging from 30 to 60nm, were synthesized. From the XRD analyses, about 96wt% of the synthesized nanoparticles were anatase-phase. After the heat-treatment at $800^{\circ}C$ for 30 minutes, the synthesized $TiO_2$ nanoparticles showed no significant changes of their shapes and crystalline phases. On the other hand, most of the commercial particles sintered with each other and changed to the rutile-phase. Based on the result of XRD analysis it is believed that the flame-synthesized $TiO_2$ nanoparticles have higher thermal stability at $800^{\circ}C$ than the commercial particles.

• 대한화학회지
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• 제63권2호
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• pp.94-101
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• 2019

Nb, Mo-doped and Nb/Mo-codoped $VO_2(M)$ nanocrystallites with various doping levels were synthesized for the first time by a hydrothermal and post thermal transformation method. The reversible phase transition characteristics of those doped $VO_2(M)$ was comparatively investigated. Nb-doping of $VO_2(M)$ by this method resulted in a very efficient lowering of the transition temperature ($T_c$) with a rate of $-16.7^{\circ}C/at.%$ that is comparable to W-doping, while Mo-doping did not give a serious reduction of $T_c$ with only a rate of $-5.1^{\circ}C/at.%$. Nb/Mo-codoping gave a similar result to Nb-doping without a noticeable difference. The thin films of Nb-doped and Nb/Mo-codoped $VO_2(M)$ with a thickness of ca. 120 nm were prepared by a wet-coating of the nanoparticle-dispersed solutions. Those films showed a good thermochromic modulation of near infrared radiation with 30-35% for Nb-doped $VO_2(M)$ and 37-40% for Nb/Mo-codoped ones. Nb/Mo-codoped $VO_2(M)$ film showed slightly enhanced thermochromic performance compared with Nb-doped $VO_2(M)$ film.