• Title/Summary/Keyword: Transfer resistance

Search Result 1,291, Processing Time 0.028 seconds

Triclinic Na3.12Co2.44(P2O7)2 as a High Redox Potential Cathode Material for Na-Ion Batteries

  • Ha, Kwang-Ho;Kwon, Mi-Sook;Lee, Kyu Tae
    • Journal of Electrochemical Science and Technology
    • /
    • v.11 no.2
    • /
    • pp.187-194
    • /
    • 2020
  • Two types of sodium cobalt pyrophosphates, triclinic Na3.12Co2.44(P2O7)2 and orthorhombic Na2CoP2O7, are compared as high-voltage cathode materials for Na-ion batteries. Na2CoP2O7 shows no electrochemical activity, delivering negligible capacity. In contrast, Na3.12Co2.44(P2O7)2 exhibits good electrochemical performance, such as high redox potential at ca. 4.3 V (vs. Na/Na+) and stable capacity retention over 50 cycles, although Na3.12Co2.44(P2O7)2 delivered approximately 40 mA h g-1. This is attributed to the fact that Na2CoP2O7 (~3.1 Å) has smaller diffusion channel size than Na3.12Co2.44(P2O7)2 (~4.2 Å). Moreover, the electrochemical performance of Na3.12Co2.44(P2O7)2 is examined using Na cells and Li cells. The overpotential of Na cells is smaller than that of Li cells. This is due to the fact that Na3.12Co2.44(P2O7)2 has a smaller charge transfer resistance and higher diffusivity for Na+ ions than Li+ ions. This implies that the large channel size of Na3.12Co2.44(P2O7)2 is more appropriate for Na+ ions than Li+ ions. Therefore, Na3.12Co2.44(P2O7)2 is considered a promising high-voltage cathode material for Na-ion batteries, if new electrolytes, which are stable above 4.5 V vs. Na/Na+, are introduced.

CGMMV Tolerance Test of CGMMV-CP Trangenic Watermelon Rootstock and Establishment of Transgenic Line (CGMMV-CP 형질전환 수박대목의 CGMMV 내성시험 및 계통확보)

  • Park, Sang-Mi;Kwon, Jung-Hee;Lim, Mi-Young;Shin, Yoon-Sup;Her, Nam-Han;Lee, Jang-Ha;Ryu, Ki-Hyun;Harn, Chee-Hark
    • Journal of Plant Biotechnology
    • /
    • v.34 no.1
    • /
    • pp.11-17
    • /
    • 2007
  • Previously developed transgenic watermelon rootstocks (gongdae) inserted by CGMMV-CP were examined to test the virus tolerance levels. In the restricted plastic house, the $T_{3}$ watermelon rootstock showed tolerance to CGMMV until 70 days after inoculation on the leaves while the non-transformed watermelon rootstock became susceptible at 20 days after inoculation. In the field, tolerance efficiency of transgenic rootstocks maintained up to 40% at 71 days after contamination with CGMMV in the soil while all of the non-transformed rootstocks became susceptible at 37 days with the same condition. In the same field, transgenic rootstocks showed more tolerance to CGMMV than the non-transformed rootstocks as those were inoculated on the leaves, but it showed only 10 days delay before being susceptible. Therefore, transgenic rootstocks have a characteristic of delay effect against CGMMV susceptibility, rather than resistance character. From $T_{3}$ rootstocks homozygous for the CGMMV-CP horticulturally favorable individuals were selected for further breeding and a transgenic line was finally obtained at the $BC_{1}T_{5}$. A material transfer experiment was conducted to find out if the DNA, RNA or expressed protein in the transgenic rootstocks could move to the grafted scion (non-transformed watermelon, Super-Kumcheon). PCR, northern, and western blot analysis were performed and no evidence of transferring of those materials from rootstock to scion was ever found.

Deubiquitinase Otubain 1 as a Cancer Therapeutic Target (암 치료 표적으로써 OTUB1)

  • Kim, Dong Eun;Woo, Seon Min;Kwon, Taeg Kyu
    • Journal of Life Science
    • /
    • v.30 no.5
    • /
    • pp.483-490
    • /
    • 2020
  • The ubiquitin system uses ligases and deubiquitinases (DUBs) to regulate ubiquitin position on protein substrates and is involved in many biological processes which determine stability, activity, and interaction of the target substrate. DUBs are classified in six groups according to catalytic domain, namely ubiquitin-specific proteases (USPs); ubiquitin C-terminal hydrolases (UCHs); ovarian tumor proteases (OTUs); Machado Joseph Disease proteases (MJDs); motif interacting with Ub (MIU)-containing novel DUB family (MINDY); and Jab1/MPN/MOV34 metalloenzymes (JAMMs). Otubain 1 (OTUB1) is a DUB in the OTU family which possesses both canonical and non-canonical activity and can regulate multiple cellular signaling pathways. In this review, we describe the function of OTUB1 through regulation of its canonical and non-canonical activities in multiple specifically cancer-associated pathways. The canonical activity of OTUB1 inhibits protein ubiquitination by cleaving Lys48 linkages while its non-canonical activity prevents ubiquitin transfer onto target proteins through binding to E2-conjugating enzymes, resulting in the induction of protein deubiquitination. OTUB1 can therefore canonically and non-canonically promote tumor cell proliferation, invasion, and drug resistance through regulating FOXM1, ERα, KRAS, p53, and mTORC1. Moreover, clinical research has demonstrated that OTUB1 overexpresses with high metastasis in many tumor types including breast, ovarian, esophageal squamous, and glioma. Therefore, OTUB1 has been suggested as a diagnosis marker and potential therapeutic target for oncotherapy.

Finger Tip Reconstruction Using $2^{nd}$ Toe Pulp Free Flap - A Case Report - (제2족지 수질부 유리피판을 이용한 수지첨부재건 치험례)

  • Park, Yong-Sun;Hong, Jong-Won;Kim, Young-Suk;Roh, Tai-Suk;Rah, Dong-Kyun
    • Archives of Reconstructive Microsurgery
    • /
    • v.19 no.1
    • /
    • pp.37-45
    • /
    • 2010
  • Purpose: First introduced by Buncke and Rose in 1979, the neurovascular partial $2^{nd}$ toe pulp free tissue transfer has been attempted to reconstruct posttraumatic finger tip injuries. Although some surgeons prefer other reconstructive methods such as skin graft and local flap, we chose the partial $2^{nd}$ toe pulp flap owing to its many advantages. We report three successful surgical cases in which the patients had undergone this particular method of reconstruction. Methods: We retrospectively examined three cases of fingertip injury patients due to mechanical injury. Bone exposure was seen in all three cases, All had undergone partial toe pulp free flap for soft tissue defect coverage. Results: All flaps survived without any complications such as partial necrosis, hematoma or dehiscence. Although tingling sensation has returned in both cases, two-point discrimination has not returned yet. Currently no patient is complaining of any pain which gradually improved during their course of recuperation. All stitches were removed on postoperative 2 weeks. Patients are satisfied with the final surgical result and there are no signs of any edema or hematoma. Conclusion: The homodigital reconstruction of finger tip injury using the partial $2^{nd}$ toe pulp flap has numerous advantages compared to other reconstructive modalities such as its resistance to wear and tear and in that it provides a non-slip palmar digital surface. However it requires microsurgery which may not be preferred by surgeons. Advanced age of the patient can be a relative contraindication to this approach since atheromatous plaque from the donor toe can compromise flap circulation after surgery. We report three successful cases which patient age was considered appropriate. Further investigation with a larger number of cases and long term follow-up is deemed necessary.

  • PDF

Fundamental Heat Analysis about the Thermoelectric Generation System Using the Waste Heat of Exhaust Gas from Ship (선박의 배기가스 폐열을 활용한 열전발전시스템에 관한 기초 열해석)

  • Kim, Myoung-Jun;Ga, Gwang-Jin;Chea, Gyu-Hoon;Kim, In-Seup
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.22 no.5
    • /
    • pp.583-592
    • /
    • 2016
  • IMO (International Maritime Organization) in the UN (United Nations) set up that aim at reducing $CO_2$ emission from ship by up to 30 percent until 2030. The final purpose of this study is the development of marine thermoelectric generation system using waste heat from vessel of internal combustion engines. Before the development of marine thermoelectric generation system, this paper carried out the fundamental heat analysis of marine thermoelectric generation system. It was able to obtain the valuable results about the efficiency improvement of the thermoelectric generation system. The results is as follows : 1) It was confirmed that the efficiency of thermoelectric generation system improves to 8.917 % with increasing the temperature difference of peltier module by reducing the temperature difference between peltier module and heat source at the hot side. 2) System efficiency according to change in the external load resistance was confirmed that the change width of about 6 % which does not significantly occur. 3) System efficiency in the case stainless steel at the same condition is 8.707 %. System efficiency could be confirmed that the stainless steel is higher than duralumin (8.605 %), copper (8.607 %).

Thermal Properties of Two-Layered Materials Composed of Dielectric Layer on Metallic Substrate along the Thickness Direction (금속기판에 유전체 후막을 형성시켜 제조한 2층 층상재료에서 두께 방향의 열전도 특성)

  • Kim, Jong-Gu;Jeong, Ju-Young;Ju, Jae-Hoon;Park, Sang-Hee;Cho, Young-Rae
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.23 no.4
    • /
    • pp.87-92
    • /
    • 2016
  • The importance of heat dissipation for the electric device modules along the thickness direction is increasing. Two types of two-layered materials, metal-metal bonding and dielectric-metal bonding, have been fabricated by roll bonding process and a thermal diffusivity of the specimens was measured along the thickness direction. The thermal diffusivity of specimens with metal-metal bonding measured by light flash analysis (LFA) showed a same value independent on the direction of heat flow. However, the thermal diffusivity of specimens with dielectric-metal bonding showed a big difference of 17.5% when the direction of heat flow changed oppositely in the LFA process. The measured thermal diffusivity of specimens when the heat flows from metal to dielectric direction showed smaller value of 17.5% compared to the value when the heat flow from dielectric to metal direction. The difference in thermal diffusivity of specimens with dielectric-metal bonding dependence on direction of heat flow is due to the electron-phonon resistance that occurred transfer process of electron energy to phonon energy near the interface.

Influence of the Micropore Structures of PAN-based Activated Carbon Fibers on Nerve Agent Simulant Gas (DMMP) Sensing Property (PAN계 활성탄소섬유의 미세기공 구조가 신경작용제 유사가스(DMMP) 감응 특성에 미치는 영향)

  • Kang, Da Hee;Kim, Min-Ji;Jo, Hanjoo;Choi, Ye Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.29 no.2
    • /
    • pp.191-195
    • /
    • 2018
  • In this study, the influence of microporous structures of activated carbon fibers (ACFs) on dimethyl methylphosphonate (DMMP) gas sensing properties as a nerve agent simulant was investigated. The pore structure was given to carbon fibers by chemical activation process, and an electrode was fabricated for gas sensors by using these fibers. The PAN based ACF electrode, which is an N-type semiconductor, received electrons from a reducing gas such as DMMP, and then electrical resistance of its electrode finally decreased because of the reduced density of electron holes. The sensitivity of the fabricated DMMP gas sensor increased from 1.7% to 5.1% as the micropore volume increased. It is attributed that as micropores were formed for adsorbing DMMP whose molecular size was 0.57 nm, electron transfer between DMMP and ACF was facilitated. In conclusion, it is considered that the appropriate pore structure control of ACFs plays an important role in fabricating the DMMP gas sensor with a high sensitivity.

Vibration Test for PCB/Connector Assembly (인쇄회로기판 진동이 커넥터에 미치는 영향)

  • 허남일;김성철;송규섭
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 1995.10a
    • /
    • pp.160-164
    • /
    • 1995
  • 정보통신 시스템의 고속/고밀도화 요구에 따라 개발되고 있는 ATM(Asynchronous Transfer Mode) 교환기 시스템은 팬을 이용한 강제대류냉각 방식의 채택과 시스템이 설치되는 장소에 따른 여러 환경조건에 의한 진동 문제가 발생될 수 있다. 시스템의 진동으로 인한 피해중 커넥터 접촉부에서 전기적 특성의 변화는 고속으로 전송되는 신호의 왜곡을 유발시킬 수 있어 시스템 개발시 이에 대한 충분한 연구 및 시험이 요구되고 있다. 진동환경에서 커넥터 접촉부는 접촉면의 상대운동으로 인한 접촉저항의 증가와 순간적인 신호전달 중단을 가져오게 되며, 특히 PCB/Connector Assembly에서 커넥터 접촉부는 PCB(Printed Circuit Board)의 장착 조건 및 동적 거동에 따라 전기적 특성이 변할 수 있다. 시스템에서 커넥터의 동적 거동을 이해하기 위해서는 PCB를 포함하는 시스템내 여러 요소의 동적 특성 이해와 복잡한 해석과정이 요구되며, 시스템 개발자는 진동 환경에서 이것의 시험 결과에 따라 커넥터의 사용을 결정해야 할 것이다. 커넥터의 전기적 특성 시험법은 IEC, EIA드 여러 국제 규격에 제시되어 있으며, 본 연구의 대상이 된 ATM교환기 시스템에서 PCB/Connector Assembly의 진동환경에서 접촉저항 측정과 관련된 접촉저항 임계치 및 측정법은 IEEE 규격 및 Bellcore 규격에 규정되어 있다. Bellcore에는 주어진 진동시험주기 전후에 IEC 규격의 LLCR(Low Level Contact Resistance) 측정회로를 이용한 측정법이 규정되어 있고, 냉각팬 및 주위 환경진동이 가해지는 동안의 영향에 대한 시험법은 규정되어 있지 않다. 본 연구에서는 한국통신의 전자장비 운용환경시험 조건의 진동에서 ATM 교환기 시스템에 사용되는 PCB/Connector Assembly 커넥터 접촉부의 접촉저항 변화와 PCB 진동에 의한 영향을 시험하였다.proach)등이 제시되었고 평면파 영역에 한하여 해서되어져 왔다. 본 논문에서는 분할 접근 방법(Segmentation Approach)을 이용하여 다공 요소로 이루어진 소음기를 해석하는데 적용하였다.로 성능 및 안정도에 영향을 미치므로 주의 깊게 선정해야 한다. 방법의 실질적인 적용에는 어려움이 있다. 본 연구에서는 기존의 방법들의 단점을 극복할 수 있는 새로운 회귀적 모우드 변수 규명 방법을 개발하였다. 이는 Fassois와 Lee가 ARMAX모델의 계수를 효율적으로 추정하기 위하여 개발한 뱉치방법인 Suboptimum Maximum Likelihood 방법[5]를 기초로 하여 개발하였다. 개발된 방법의 장점은 응답 신호에 유색잡음이 존재하여도 모우드 변수들을 항상 정확하게 구할 수 있으며, 또한 알고리즘의 안정성이 보장된 것이다.. 여기서는 실험실 수준의 평 판모델을 제작하고 실제 현장에서 이루어질 수 있는 진동제어 구조물에 대 한 동적실험 및 FRS를 수행하는 과정과 동일하게 따름으로써 실제 발생할 수 있는 오차나 error를 실험실내의 차원에서 파악하여 진동원을 있는 구조 물에 대한 진동제어기술을 보유하고자 한다. 이용한 해마의 부피측정은 해마경화증 환자의 진단에 있어 육안적인 MR 진단이 어려운 제한된 경우에만 실제적 도움을 줄 수 있는 보조적인 방법으로 생각된다.ofile whereas relaxivity at high field is not affected by τS. On the other hand, the change in τV does not affect low field profile but strongly in fluences on both inflection fie이 and the maximum relaxivity value. The results shows a fluences on both inflection field and the maximum relaxivity v

  • PDF

A Study on the Possibility of Homegrown Terrorism in Korea Depending on Internalization and Strategy to Cope with the Terrorism (국제화에 따른 한국내 자생테러 발생 가능성과 대응전략)

  • Yu, Hyung-Chang
    • Korean Security Journal
    • /
    • no.31
    • /
    • pp.125-155
    • /
    • 2012
  • Terrorist organization has shown the trend of secret organization and it is harder to cope with terrorism because of uncertainty of terrorism. Homegrown terrorism is the one, whose preparation, execution and effect are restricted to domestic area. By the way, in the worldwide economic depression, violence and radical demonstration have shown the expansion trends as in Middle East, political revolution of Africa, anti-social resistance of Europe and Wall Street Occupation of USA. Homegrown terrorism is occurring in various countries such as UK and Spain as well as USA. Specialists warn homegrown terrorism in Korea. The purpose of this study was to prospect the possibility of homegrown terrorism that can be generated in the transfer to multi-culture society as various foreigners come to Korea rapidly and suggest the method to cope with the trend. The study analyzed environment and analysis of homegrown terrorism that Korea faces now. The methods to cope with homegrown terrorism are as follows. First, distribution of radical homegrown terrorism via internet should be prevented. Second, the connection between terrorist organization and homegrown terrorist should be prevented. Third, there should be a cooperation among government, residents and religious group. Fourth, there should be an open approach against multi-culture society. Fifth, there should be a systematic control for cause of new conflict. Finally, there should be a long-term approach to cause of new conflict. If we do not make an effort to prevent homegrown terrorism, terrorism environment may face new aspect and national and social cost for it will increase.

  • PDF

Decrease of PEMFC Performance by Toluene in Air (공기 중 톨루엔에 의한 고분자전해질연료전지의 성능감소)

  • Lee, Ho;Song, Jin-Hoon;Kim, Ki-Joong;Kim, Sae-Hoon;Ahn, Byung-Ki;Lim, Tae-Won;Park, Kwon-Pil
    • Korean Chemical Engineering Research
    • /
    • v.49 no.1
    • /
    • pp.15-20
    • /
    • 2011
  • The contamination effect of toluene in the airstream on PEM fuel cell performance was studied with various toluene concentration under different operation conditions. And the recovery of the cell performance by applying clean air and the removal of toluene in the air by adsorption of active carbon were investigated. The toluene concentration range used in the experiments was from 0.1 ppm to 5.0 ppm. The performance degradation and recovery were measured by constant-current discharging and electrochemical impedance spectroscopy(EIS). Toluene adsorption capacity of KOH impregnated active carbon was obtained from the adsorption isotherm curve. The severity of the contamination increased with increasing toluene concentration, current density and air stoichiometry, but decrease with increasing relative humidity. The cell performance was recovered by toluene oxidation with oxygen and water in humidified neat air. EIS showed that the increase of charge transfer resistance due to toluene adsorption on Pt surface mainly reduced the performance of PEMFC. Toluene adsorption capacity of active carbon decreased as KOH weight increased in KOH impregnated active carbon.