• Journal of the Korean Ceramic Society
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• v.39 no.2
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• pp.120-125
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• 2002

AC powder EL devices were fabricated by screen printing method with the dielectric materials in insulating layer and the electrical resistivity of rear electrode. Brightness and current density were measured at voltage range of 50∼300 $V_{rms}$ to estimate optoelectrical properties of AC powder EL devices, respectively. Frequency generator was used as system producing frequency and voltage of a sine wave. Brightness and current density were measured by luminometer and multimeter. Also, dielectric constant for dielectric layer was measured by impedance analyser after preparing thick film. Dielectric constant was improved with amount of $TiO_2$ to $BaTiO_3$ powder. By applying such a process to dielectric layer of low cost AC powder EL device, brightness was improved to 50 cd/$m^2$ at similar current density. Dielectric constant $BaTiO_3$ powder by solution combustion process is better than commercial $BaTiO_3$ powder. By applying to that of low power consumption AC powder EL device, brightness was improved to 85 cd/$m^2$. Brightness of AC powder EL device was relatively decreased by control of electrical resistivity of rear electrode, current density was also decreased.

• Korean Journal of Materials Research
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• v.9 no.1
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• pp.51-56
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• 1999

The $BaTiO_3$ powders were synthesized by GNP (Glycine-Nitrate process). The powders were prepared using carbonate and alkoxide as starting materials and nitric acid was used as a solvent for starting materials as well as an oxidant for combustion. the effects of aggregates in $BaTiO_3$ powders on green densities, sintering and dielectric characteristics were investigated. When the glycine/cation molar ratio was 1.2, reactivity of self-combustion was most intensive and the degree of aggregates after calcination was low. On sintering at $1400^{\circ}C$, maximum theoretical relative density(94.99%%0 was obtained in case of 1.2 molar ratio of glycine/cation. The dielectric constant of this sintered $BaTiO_3$ was 1919.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.440-441
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• 2006

Several titanate powders ($Al_2TiO_5,\;SrTiO_3$, etc.) were synthesized by an ethylene glycol solution route. Titanium isopropoxide and nitrate salts were dissolved in stoichiometric proportions in liquid-type ethylene glycol without any precipitation. The parent precursor sols were dried to porous gels, and then the gels were calcined and crystallized. All synthesized titanate powders had stable crystallization behavior at low temperature and high specific surface area after a simple ball-milling process. A three-component PZT $(Pb(Zr_{0.52}{\cdot}Ti_{0.48})O_3)$ powder was also synthesized successfully by the ethylene glycol method. In this study, the characteristics of the multi-component titanate powders by the ethylene glycol method are examined.

• Korean Journal of Materials Research
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• v.4 no.1
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• pp.3-8
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• 1994

Recently, sound and mechanical vibration are becoming important problems in our life. In the present study, the measurement of vibration absorption characteristics of barium titanate ceramics and the investigation of its relationship to microstructures were carried out. The barium titanate ceramics is expected to be better vibration absorption material owing to its chemical and physical stability than other conventional vibration absorbers like glasswool board. Barium titanate ceramics were prepared by sintering fiberous $BaTiO_{3}$ crystallites in order to enhance the vibration absorption characteristics. The fiberous $BaTiO_{3}$ ceramics were prepared through the ionic exchange after the preparation of fiberous $K_2Ti_4O_9$ with 0.2$\mu\textrm{m}$, 1.2$\mu\textrm{m}$, 2.0$\mu\textrm{m}$, diameter length by KDC method. The fiberous crystallites were oriented in a plane perpendicular to the press direction and sintered. The investigation of the grain diameters of the sintered ceramics, equivalent factor, electromechanical coupling factor($k_1$), and the generated voltage(V) shows that the grain's diameter decreases with the increase of the diameter of the used fiberous crystallites. The vibration absorption increases the crystallites' diameter. That means that the vibration absorption increases with the internal friction of grain boundary. Which was identified by the investigation of the equivallent circuit.

• Journal of the Microelectronics and Packaging Society
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• v.8 no.4
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• pp.59-65
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• 2001

Epoxy/$BaTiO_3$composite capacitor films with excellent stability at room temperature, uniform thickness, and electrical properties over a large area ware successfully fabricated. The composite capacitor films with good film formation capability and easy process ability were made from epoxy resin developed for ACF as a matrix and two kinds of $BaTiO_3$powders as fillers to increase the dielectric constant of the composite film. The crystal structure of the powders and its effects on dielectric constant of the films were investigated by X-ray diffraction (XRD). And the optimum amount of dispersant, phosphate ester, was determined by viscosity measurement of suspension. DSC and dielectric property tests were conducted to decide the right curing temperature and the optimum amount of the curing agent. As a result, the capacitors of 7 $\mu \textrm{m}$ thick film with 10 nF/$\textrm{cm}^2$ and low leakage current were successfully demonstrated.

• Electrical & Electronic Materials
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• v.3 no.1
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• pp.9-19
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• 1990

본 연구에서는 산회물 혼합법, 솔-젤법, 공침법등의 세가지 방법으로 PbTiO$_{3}$분말을 제조하여 폴리머와 혼합 O-3 복합재료를 제작한 후, 하이드로폰으로의 응용을 위한 제 특성을 고찰하였다. 비유전상수는 PbTiO$_{3}$의 체적비 증가에 따라 지수함수적으로 증가하였으며 유전손실은 선형적으로 증가하였다. 수정입방체 모델로 부터 계산된 변형계수 n은 M-O, S-G, C-P의 경우 각각 0.724, 0.585, 0.483으로 나타났다. 압전 변형계수 d$_{33}$는 PbTiO$_{3}$의 체적비, 분극전장 및 분극 시간의 증가에 따라 증가하였으며 일정시간 경과후에는 포화값을 나타내었다.다.

• Journal of Powder Materials
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• v.9 no.1
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• pp.25-31
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• 2002

The efects of mechanical aloying conditions and the type of reducing agent on the solid state reductionof haematite $Fe_2O_3$ have been investigated at room temperature. Aluminium titanium zinc and copper were used as reducing agent. Nanocomposites of metal-oxide in which oxide particles with nano size were dispersed in Fe matrix were obtained by mechanical alloying of $Fe_2O_3$ with aluminium and titanium respectively However the reduction of $Fe_2O_3$ by coppe was not occurred Composite materials of iron with $Al_2O_3$ and $TiO_2$ were obtained from the system of $Fe_2O_3-Al$ and $Fe_2O_3-Ti$ after ball milling for 20 hrs and 30 hrs respectively. And the system of $Fe_2O_3-Zn$ resulted in the formationof FeO with ZnO after ball milling of 120 hrs. The final grain sizes of iron estimated by X-ray diffraction line-width measurement were in the ranges of 24~33 nm.

• Journal of the Korean Ceramic Society
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• v.39 no.11
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• pp.1108-1112
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• 2002

pellets were fabricated as a reactor control material by the powder process. Sinterability of $Dy_2O_3+TiO_2$ mixtures and phases of solid solutions were analyzed by using TMA and XRD, respectively. The thermal conductivity of pellet was determined from the measurement data of the specific heat and the thermal diffusivity of the pellet. The sinterability and the sintered density varied as a function of Dy content in $Dy_xTi_yO_z$. The pellet of $3\;g\;Dy/cm^3\;Dy_xTi_yO_z$ melted in the sintering temperature of $1580{\circ}C$. There were two phases of $Dy_2TiO_5+Dy_2Ti_2O_7$ and a single phase of $Dy_2TiO_5$ for the pellet that has the Dy content of and , respectively. The thermal conductivity of $Dy_xTi_yO_z$ was nearly constant in the temperature range of $25~600{\circ}$. It was 1.69~1.78 W/mK for the pellet sintered in and 1.49~1.55 W/mK for the pellet sintered in $1550{\circ}$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.198-199
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• 2008

페로브스카이트 구조의 (Ba,Sr,Ca)$TiO_3$ 분말에 $Y_2O_3$ 불순물을 첨가하여 첨가량에 따른 영향을 연구하였다. 시편의 제작은 Screen-printing을 이용하여 후막으로 제작하였으며, 구조적인 특성과 함께 유전적 특성을 관찰하였다. XRD 회절 운석을 통하여 $Y_2O_3$ 가 첨가된 모든 시편에서 전형적인 페로브스카이트 구조를 나타내는것을 알 수 있었다. 시편의 미세구조를 관찰한 결과 grain size 는 $Y_2O_3$ 첨가량이 증가 할수록 감소하였으며, 기공은 증가하는 것을 알 수 있었다. 후막의 두께는 $Y_2O_3$ 첨가량에 영향을 받지 않았으며 평균 두께는 $60{\mu}m$이었다. 유전상수는 $Y_2O_3$ 첨가량에 따라 감소하였으며, 유전손실은 모든 시편에서 1%이하의 양호한 값을 나타내었다.

• Journal of Powder Materials
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• v.24 no.1
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• pp.41-45
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• 2017

The effects of the heat treatment temperature and of the atmosphere on the dehydrogenation and hydrogen reduction of ball-milled $TiH_2-WO_3$ powder mixtures are investigated for the synthesis of Ti-W powders with controlled microstructure. Homogeneously mixed powders with refined $TiH_2$ particles are successfully prepared by ball milling for 24h. X-ray diffraction (XRD) analyses show that the powder mixture heat-treated in Ar atmosphere is composed of Ti, $Ti_2O$, and W phases, regardless of the heat treatment temperature. However, XRD results for the powder mixture, heat-treated at $600^{\circ}C$ in a hydrogen atmosphere, show $TiH_2$ and TiH peaks as well as reaction phase peaks of Ti oxides and W, while the powder mixture heat-treated at $900^{\circ}C$ exhibits only XRD peaks attributed to Ti oxides and W. The formation behavior of the reaction phases that are dependent on the heat treatment temperature and on the atmosphere is explained by thermodynamic considerations for the dehydrogenation reaction of $TiH_2$, the hydrogen reduction of $WO_3$ and the partial oxidation of dehydrogenated Ti.