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Solid State Reduction of Haematite by Mechanical Alloying Process

기계적 합금화법에 의한 헤마타이트의 고상환원

  • 이충효 (목포대학교 신소재공학과) ;
  • 홍대석 (목포대학교 신소재공학과) ;
  • 이만승 (목포대학교 신소재공학과) ;
  • 권영순 (울산대학교 지역협력연구센터)
  • Published : 2002.02.01

Abstract

The efects of mechanical aloying conditions and the type of reducing agent on the solid state reductionof haematite $Fe_2O_3$ have been investigated at room temperature. Aluminium titanium zinc and copper were used as reducing agent. Nanocomposites of metal-oxide in which oxide particles with nano size were dispersed in Fe matrix were obtained by mechanical alloying of $Fe_2O_3$ with aluminium and titanium respectively However the reduction of $Fe_2O_3$ by coppe was not occurred Composite materials of iron with $Al_2O_3$ and $TiO_2$ were obtained from the system of $Fe_2O_3-Al$ and $Fe_2O_3-Ti$ after ball milling for 20 hrs and 30 hrs respectively. And the system of $Fe_2O_3-Zn$ resulted in the formationof FeO with ZnO after ball milling of 120 hrs. The final grain sizes of iron estimated by X-ray diffraction line-width measurement were in the ranges of 24~33 nm.

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