• 공업화학
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• 제26권6호
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• pp.681-685
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• 2015

본 연구에서는 열 변색 물질로 알려진 순수한 $BiVO_4$ 분말과 금속이 도핑된 $M-BiVO_4$ (M = Mg, Cu) 분말들을 bismuth nitrate ($Bi(NO_3)_3$)와 ammonium vanadate ($NH_4VO_3$)의 혼합 수용액으로부터 고압반응기에서 수열 합성법을 통하여 성공적으로 제조하였다. 시료들의 결정구조, 미세구조 및 열 변색 특성들은 FE-SEM, FT-IR, XRD, DSC, UV-Vis-NIR 분광기 및 colorimeter를 이용하여 분석하였다. 시료를 상전이 온도 이상으로 가열시키면, 순수한 $BiVO_4$ 시료에 비하여 $M-BiVO_4$ (M = Mg, Cu) 시료의 색상이 상대적으로 선명하게 열 변색하였다.

• 공업화학
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• 제24권6호
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• pp.611-615
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• 2013

본 연구에서는 바나듐 산화물($VO_2$)과 텅스텐이 도핑된 바나듐 산화물(W-$VO_2$) 분말을 바나듐 산화물($V_2O_5$)과 옥살산수화물로부터 수열합성과 하소공정을 통하여 성공적으로 제조하였다. 시료들의 결정구조와 열변색 특성들은 FE-SEM, XRD, XPS, DSC 및 UV-Vis-NIR 분광기를 이용하여 분석하였다. W-$VO_2$ 시료에 W의 도핑량을 증가시키면, W-$VO_2$ 시료의 상전이 온도가 $70^{\circ}C$에서 $42^{\circ}C$로 낮아지는 경향이 있었다. 또한, W-$VO_2$ 시료를 상전이 온도 이상으로 가열시키면 UV-Vis-NIR 곡선이 가시광 영역에서는 변하지 않고 NIR 영역에서는 낮은 투과도 방향으로 이동하는 경향이 있었다.

• 청정기술
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• 제21권4호
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• pp.235-240
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• 2015

본 연구에서는 열변색 물성을 향상시키기 위한 방안의 하나로 0~0.5 at % 범위의 티타늄을 도핑한 이산화 바나듐(Ti-VO₂)을 제조하였다. Ti-VO₂ 입자들은 바나딜설페이트, 중탄산암모늄, 사염화 티타늄 등을 사용하여 바나듐 화합물 전구체를 제조한 후 열분해법을 이용하여 제조하였다. 제조된 시료들의 결정 구조, 형상, 화학적 구조 및 열변색 특성은 X-선 회절분석기, 전계방사 주사전자현미경, X-선 광전자 분광기, 시차주사열량분석기, 자외선-가시광선-근적외선 분광기 등을 이용하여 분석하였다. 제조된 Ti-VO₂ 입자들은 단사 결정계를 지니고 있고, 또한 티타늄이 이산화 바나듐 결정내에 잘 도핑되어 있음을 확인할 수 있었다. 티타늄 도핑량이 증가함에 따라 최종 Ti-VO₂ 입자들의 크기가 작아지고 상전이 온도가 낮아졌으며, 또한 NIR switching efficiency는 증가하였다.

• 대한화학회지
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• 제63권2호
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• pp.94-101
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• 2019

Nb, Mo-doped and Nb/Mo-codoped $VO_2(M)$ nanocrystallites with various doping levels were synthesized for the first time by a hydrothermal and post thermal transformation method. The reversible phase transition characteristics of those doped $VO_2(M)$ was comparatively investigated. Nb-doping of $VO_2(M)$ by this method resulted in a very efficient lowering of the transition temperature ($T_c$) with a rate of $-16.7^{\circ}C/at.%$ that is comparable to W-doping, while Mo-doping did not give a serious reduction of $T_c$ with only a rate of $-5.1^{\circ}C/at.%$. Nb/Mo-codoping gave a similar result to Nb-doping without a noticeable difference. The thin films of Nb-doped and Nb/Mo-codoped $VO_2(M)$ with a thickness of ca. 120 nm were prepared by a wet-coating of the nanoparticle-dispersed solutions. Those films showed a good thermochromic modulation of near infrared radiation with 30-35% for Nb-doped $VO_2(M)$ and 37-40% for Nb/Mo-codoped ones. Nb/Mo-codoped $VO_2(M)$ film showed slightly enhanced thermochromic performance compared with Nb-doped $VO_2(M)$ film.

• 한국산업안전학회:학술대회논문집
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• 한국안전학회 2005년도 춘계 학술발표회
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• pp.391-394
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• 2005

• Bulletin of the Korean Chemical Society
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• 제16권11호
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• pp.1007-1009
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• 1995

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.540-545
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• 2001

An experimental study was conducted to compare the heat transfer characteristics of an impinging slot jet and three kinds of impinging circular jets. Thermochromic liquid crystal with an image processing system was employed to measure the temperature of impinging wall where constant heat flux condition was applied. The distribution of convective heat transfer coefficients were then evaluated for eight nozzle-to-surface distance settings for each jet cases. The cooling effect was linearly proportional to the number of nozzles for circular jet cases at the same nozzle exit speed. However, the heat transfer under constant volume flow rate was the most at single circular jet. It was concluded that the overall convective heat transfer was better at the circular jets than the slot jet.

• 한국결정성장학회지
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• 제23권5호
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• pp.224-229
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• 2013

Vanadium oxide thin films were deposited on $c-Al_2O_3$ (001) substrate by in-situ RF magnetron sputtering. Oxygen partial pressure was adjusted to prepare thermochromic $VO_2$ phase. X-ray diffraction patterns and scanning electron microscopy convincingly showed that plate-like $V_2O_5$ grains were changed into round-shape $VO_2$ grains as oxygen partial pressure decreased. After the optimized deposition conditions were fixed, the effect of substrate temperature and orientation on the optical properties of $VO_2$ thin films was analyzed.

• 대한기계학회논문집B
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• 제21권12호
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• pp.1595-1607
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• 1997

The natural convection of a horizontal layer heated from below in a three-dimensional rectangular enclosure was dealt with both numerically and experimentally. The aspect ratios are 1:2:3.5 and Boussinesq fluid is water with the Prandtl number of 5.0. This experimental study showed how to measure the variation of temperature field in a 3-D rectangular enclosure with small aspect ratios by using TLC(Thermochromic Liquid Crystal) and color capturing technique. The experimental temperature field had periodic characteristics of 75 sec at Ra=2.37*10$^{5}$ . But the numerical convection flow had periodic characteristics of 79 sec at the same Rayleigh number. In three dimensional computation it was found that the convection roll structure bifurcated from four rolls to two rolls as the Rayleigh number is increased.

• Journal of Advanced Marine Engineering and Technology
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• 제27권3호
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• pp.395-404
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• 2003

Quantitative data of the temperature and velocity were obtained simultaneously by using liquid crystal tracer. PIV(Particle Image Velocimety) based on a grey-level cross-correlation method was used for visualizing and analysis of the flow field. The temperature gradient was obtained by applying the color-image processing to a visualized image, and a neural-network a1gorithm was applied to the color-to-temperature calibration. This simultaneous measurement was applied to the Rayleigh-Bernard convection. This paper describes the method, and presents the quantitative visualization of Rayleigh-Bernard convection and the effect of aspect ratio and viscosity. Also the experimental results were compared with the numerical results.