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http://dx.doi.org/10.7464/ksct.2015.21.4.235

A Study on the Thermochromic properties of Ti-doped Vanadium Dioxide  

Park, Jin Wook (Department of Industrial Chemistry)
Park, Seong-Soo (Department of Industrial Chemistry)
Ahn, Byung Hyun (Department of Material Science and Engineering)
Hong, Seong-Soo (Department of Chemical Engineering)
Lee, Gun Dae (Department of Industrial Chemistry)
Publication Information
Clean Technology / v.21, no.4, 2015 , pp. 235-240 More about this Journal
Abstract
In this study, vanadium dioxide was doped with titanium (0~0.5 at %) to improve thermochromic properties. The titanium doped vanadium dioxide (Ti-VO2) particles were prepared via thermolysis process using vanadyl sulfate, ammonium bicarbonate and titianium chloride as precursors. The crystal structure, morphology, chemical bonding and thermochromic properties were investigated by using XRD, FE-SEM, XPS, DSC and UV-Vis-NIR spectroscopy. It was found that titanium was successfully doped into the crystal lattice of VO2 and the obtained Ti-VO2 particles have monoclinic structure. With increasing Ti concentration, the particle size and phase transition temperature of Ti-VO2 particles decreased and NIR switching efficiency increased.
Keywords
Thermochromic; Titanium; Doping; Vanadium dioxide;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
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1 Morin, F. J., “Oxides which Show a Metal-to-insulator Transition at the Neel Temperature,” Phys. Rev. Lett., 3, 34-36 (1959).   DOI
2 Ji, S., Zhang, F., and Jin, P., "Preparation of High Performance Pure Single Phase VO2 Nanopowder by Hydrothermal Reducing the V2O5 Gel," Sol. Energy Mater. Sol. Cells, 95, 3520-3526 (2011).   DOI
3 Song, L., Zhang, Y., Huang, W., Shi, Q., Li, D., Zhang, Y., and Xu, Y., "Preparation and Thermochromic Properties of Ce-doped VO2 Films," Mater. Res. Bull., 48, 2268-2271 (2013).   DOI
4 Wu, Y., Fan, L., Liu, Q., Chen, S., Huang, W., Chen, F., Liao, G., Zou, C., and Wu, Z., "Decoupling the Lattice Distortion and Charge Doping Effects on the Phase Transition Behavior of VO2 by Titanium (Ti4+) Doping," Sci. Rep., 5, 9328 (2015).   DOI
5 Zhang, Z., Gao, Y., Chen, Z., Du, J., Cao, C., Kang, L., and Luo, H., "Thermochromic VO2 Thin Film: Solution-based Processing, Improved Optical Properties, and Lowered Phase Transformation Temperature," Langmuir, 26, 10738-10744 (2010).   DOI
6 Gao, Y., Luo, H., Zhang, Z., Kang, L., Chen, Z., Du, J., Kanehira, M., and Cao, C., "Nanoceramic VO2 Thermochromic Smart Glass: A Review on Progress in Solution Processing," Nano Energy, 1, 221-246 (2012).   DOI
7 Kamalisarvestani, M., Saidur, R., Mekhilef, S., and Javadi, F. S., “Performance, Materials and Coating Technologies of Thermochromic Thin Films on Smart Windows,” Renew. sustainable Energy Rev., 26, 353-364 (2013).   DOI
8 Wu, Y., Fan, L., Chen, S., Shen, S., and Chen, F., "A Novel Route to Realize Controllable Phases in an Aluminum (Al3+)-doped VO2 System and the Metal-insulator Transition Modulation," Mater. Lett., 127, 44-47 (2014).   DOI
9 Xiao, X., Zhang, H., Chai, G., Sun, Y., Yang, T., Cheng, H., Chen, L., Miao, L., and Xu, G., "A Cost-effective Process to Prepare VO2(M) Powder and Films with Supirior Thermochromic Properties," Mater. Res. Bull., 51, 6-12 (2014).   DOI
10 Gao, Y., Cao, C., Dai, L., Luo, H., Kanehira, M., Ding, Y., and Wang, Z. L., "Phase and Shape Controlled VO2 Nanostructures by Antimony Doping," Energy Environ. Sci., 5, 8708-8715 (2012).   DOI
11 Wu, X., Wu, Z., Zhang, H., Niu, R., He, Q., Ji, C., Wang, J., and Jiang, Y., "Enhancement of VO2 Thermochromic Properties by Si Doping," Surf. Coat. Technol., 276, 248-253 (2015).   DOI
12 Ye, J., Zhou, L., Liu, F., Qi, J., Gong, W., Lin, Y., and Ning, G., “Preparation, Characterization and Properties of Thermochromic Tungsten-doped Vavadium Dioxide by Thermal Reduction and Annealing,” J. Alloy Compd., 504, 503-507 (2010).   DOI
13 Chen, S., Dai, L., Liu, J., Gao, Y., Liu, X., Chen, Z., Zhou, J., Cao, C,, Han, P., Luo, H., and Kanahira, M., "The Visible Transmittance and Solar Modulation Ability of VO2 Flexible Foils Simultaneously Improved by Ti Doping: an Optimization and First Principle Study," Phys. Chem. Chem. Phys., 15, 17537-17543 (2013).   DOI
14 Kiri, P., Hyett, G., and Binions, R., “Solid State Thermochromic Materials,” Adv. Mat. Lett., 1(2), 86-105 (2010).   DOI
15 Du, J., Gao, Y., Luo, H., Kang, L., Zhang, Z., Chen, Z., and Cao, C., "Significant Changes in Phase-transition Hysteresis for Ti-doped VO2 Films Prepared by Polymer-assisted Deposition," Sol. Energy Mater. Sol. Cells, 95, 469-475 (2011).   DOI
16 Luo, Y. Y., Zhu, L. Q., Zhang, Y. X., Pan, S. S., Xu, S. C., Liu, M., and Li, G. H., "Optimization of Microstructure and Optical Properties of VO2 Thin Film Prepared by Reactive Sputtering," J. Appl. Phys., 113, 183520-183527 (2013).   DOI
17 Parkin, I. V., and Manning, T. D., “Intelligent Thermochromic Windows,” J. Chem. Edu., 83, 393-400 (2006).   DOI
18 Shi, J., Zhou, S., You, B., and Wu, L., "Preparation and Thermochromic Property of Tungsten-doped Vanadium Dioxide Particles," Sol. Energy Mater. Sol. Cells, 91, 1856-1862 (2007).   DOI
19 Chen, S., Liu, J., Wang, L., Luo, H., and Gao, Y., "Unravelling Mechanism on Reducing Theraml Hysteresis Width of VO2 by Ti Doping: A Joint Experimental and Theoretical Study," J. Phys. Chem. C, 118, 18938-18944 (2014).   DOI
20 Zheng, C., Zhang, X., Zhang, J., and Liao, K., "Preparation and Characterization of VO2 Nanopowders," J. Solid State Chem., 156, 274-280 (2001).   DOI
21 Hwang, K.-J., Jo, C. W., and Yoo, J. W., “Synthesis of Tungsten Doped Vanadium Dioxide and Its Thermochromic Property Studies,” Appl. Chem. Eng., 24(1), 44-48 (2013).
22 Li, M., Wu, X., Li, L., Wang, Y., Li, D., Pan, J., Li, S., Sun, L., and Li, G., "Defect-mediated Phase Transition Temperature of VO2(M) Nanoparticles with Excellent Thermochromic Performance and Low Threshold Voltage," J. Mater. Chem. A, 2, 4520-4523 (2014).   DOI