• Title/Summary/Keyword: Thermal threshold

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Effect of Graphite Nanofibers on Poly(methyl methacrylate) Nanocomposites for Bipolar Plates

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.671-674
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    • 2009
  • In this work, high-aspect-ratio graphite nanofibers (GNFs) were used to improve the electrical, thermal, and mechanical properties of the poly(methyl methacrylate) (PMMA) polymer, as well as those of PMMA composites suitable for use in bipolar plates. In the result, an electrical percolation threshold for the composites was formed between 1 and 2 wt% GNF content. This threshold was found to be influenced strongly by the three separate stages of the meltblending process. The composites exhibited higher thermal and mechanical properties and lower thermal shrinkage compared with the neat PMMA. Thus, GNFs were demonstrated to have positive impacts on the thermo-mechanical properties of PMMA composites and showed, thereby, reasonable potential for use in composites employed in the fabrication of bipolar plates.

A Study on Thermal Shock, Thermal Expansion and Thermal Cracking of Rocks under High Temperature (고온하에서 암석의 열충격, 열팽창 및 열파괴에 관한 연구)

  • 이형원;이정인
    • Tunnel and Underground Space
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    • v.5 no.1
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    • pp.22-40
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    • 1995
  • Thermomechanical characteristics of rocks such as thermal shock, thermal expansion, thermal cracking were experimentally investigaed using Iksan granite, Cheonan tonalite and Chung-ju dolomite to obtain the basic data for proper design and Chung-ju dolomite to obtain the basic data for proper design and stability analysis of underground structures subjected to temperature changes. The effect of thermal shock did not appear when the heating speed was under 3$^{\circ}C$/min. and there existed little difference between multi-staged cyclic heating and single-cycled heating. Thermal expansion of rocks was affected by mineral composition, crack porosity and the degree of thermal craking. In quartz-beraring multimineralic rocks such as Iksan granite and Cheonan tonalite, the thermal expansion coefficient increaseed continuously with temperature rise, but that of Chung-ju dolomite which was a monomineralic rock showed a constant value for the temperature above 250$^{\circ}C$, Chung-ju dolomite yielded the lowest critical threshold temperature(Tc) of 100$^{\circ}C$ and unstable thermal cracking was initiated above the new threshold temperature(Tc')of 300$^{\circ}C$. Above Tc' thermal cracks grew but they were not interconnected. Iksan granite showed closing of microcracks to the temperature of 100$^{\circ}C$, then expanded linearly to Tc of 200$^{\circ}C$. Above Tc, thermal cracking was initiated and progressed rapidly and almost all the grain boundaries were cracked at 600$^{\circ}C$. Cheonan tonalite also showed similar behavior to iksan granite except that Tc was 350$^{\circ}C$ and that thermal cracks propagated more rapidly. Thermal expansions calculated by Turner's equation were found to be valid in predicting the thermal expansion and cracking behavior of rocks.

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Improvement of Thermal and Electrical Conductivity of Epoxy/boron Nitride/silver Nanoparticle Composite (열전도도 및 전기전도도가 향상된 에폭시/보론나이트라이드/은나노입자 복합체의 제조)

  • Kim, Seungyong;Lim, Soonho
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.426-429
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    • 2017
  • In this study, we investigated the effect of BN (boron nitride) on the thermal and the electrical conductivity of composites. In case of epoxy/BN composites, the thermal conductivity was increased as the BN contents were increased. Epoxy/AgNP (Ag nanoparticle) nanocomposites exhibited a slight change of thermal conductivity and showed a electrical percolation threshold at 20 vol% of Ag nanoparticles. At the fixed Ag nanoparticle content below the electrical percolation threshold, increasing the amount of BN enhanced the electrical conductivity as well as thermal conductivity for the epoxy/AgNP/BN composites.

Effects of Design Parameters on the Thermal Performance of a Brushless DC Motor (BLDC 모터의 열적 성능에 대한 설계 인자의 영향)

  • Kim, Min-Soo;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.2
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    • pp.141-148
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    • 2008
  • A numerical simulation of brushless DC motor is performed to elucidate thermo-flow characteristics in winding and bearing with heat generation. Rotation of rotor and blades drives influx of ambient air into the rotor inlet. Recirculation zone exists in the tiny interfaces between windings. The flow separation causes poor cooling performance in bearing part and therefore the redesign of the bearing groove is required. The design parameters such as the inlet location, geometry and bearing groove threshold angle have been selected in the present simulation. As the inlet location moves inward in the radial direction, total incoming flow rate and heat transfer rate are increased. Total incoming flow rate is increased with increasing the inlet inner length. The effect of the bearing groove threshold angle on the thermal performance is less than that of other design parameters.

Theoretical models of threshold stress intensity factor and critical hydride length for delayed hydride cracking considering thermal stresses

  • Zhang, Jingyu;Zhu, Jiacheng;Ding, Shurong;Chen, Liang;Li, Wenjie;Pang, Hua
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1138-1147
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    • 2018
  • Delayed hydride cracking (DHC) is an important failure mechanism for Zircaloy tubes in the demanding environment of nuclear reactors. The threshold stress intensity factor, $K_{IH}$, and critical hydride length, $l_C$, are important parameters to evaluate DHC. Theoretical models of them are developed for Zircaloy tubes undergoing non-homogenous temperature loading, with new stress distributions ahead of the crack tip and thermal stresses involved. A new stress distribution in the plastic zone ahead of the crack tip is proposed according to the fracture mechanics theory of second-order estimate of plastic zone size. The developed models with fewer fitting parameters are validated with the experimental results for $K_{IH}$ and $l_C$. The research results for radial cracking cases indicate that a better agreement for $K_{IH}$ can be achieved; the negative axial thermal stresses can lessen $K_{IH}$ and enlarge the critical hydride length, so its effect should be considered in the safety evaluation and constraint design for fuel rods; the critical hydride length $l_C$ changes slightly in a certain range of stress intensity factors, which interprets the phenomenon that the DHC velocity varies slowly in the steady crack growth stage. Besides, the sensitivity analysis of model parameters demonstrates that an increase in yield strength of zircaloy will result in a decrease in the critical hydride length $l_C$, and $K_{IH}$ will firstly decrease and then have a trend to increase with the yield strength of Zircaloy; higher fracture strength of hydrided zircaloy will lead to very high values of threshold stress intensity factor and critical hydride length at higher temperatures, which might be the main mechanism of crack arrest for some Zircaloy materials.

Study for Thermal Stability of Liquid Crystal Device (액정 소자의 열적 안전성에 관한 연구)

  • 이상극;황정연;서대식;이준웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.439-442
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    • 2004
  • In this study, we investigated about electrooptics characteristic of three kinds of TN cell on the polyimide surface. Monodomain alignments of thermal stressed TN cell over temperature of liquid crystal isotropic phase were almost the same as that of no thermal stressed TN cells. However, the thermal stressed TN cells have many defects. Also, threshold voltage and response time of thermal stressed TN cells show the same performances as no thermal stressed TN cells. There were little changes of value in these TN cells. However, transmittances of TN cells on the polyimide surface decrease with increasing thermal stress time. Finally, the residual DC voltage of the thermal stressed TN cell on the polyimide surface shows decrease of characteristics as increasing thermal stress time. Therefore, the thermal stability of TN cell was decreased by high thermal stress for the long times.

Characteristics of Damage on Photosensor Irradiated by Intense Illumination : Thermal Diffusion Model (고섬광에 노출된 광센서의 손상 특성 : 열확산 모델)

  • Kwon, Chan-Ho;Shin, Myeong-Suk;Hwang, Hyon-Seok;Kim, Hong-Lae;Kim, Seong-Shik;Park, Min-Kyu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.2
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    • pp.201-207
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    • 2012
  • Pulsed lasers at the 613 nm and 1064 nm wavelengths on nanoseconds have been utilized to characterize the damage on Si photodiode exposed to intense illumination. Morphological damages and structural changes at sites on the photodiode irradiated during microseconds of laser pulses were analyzed by FE-SEM images and XRD patterns, respectively. The removal of oxide coating, ripple, melting marks, ridges, and crater on photodiodes were definitely observed in order of increasing the pulse intensities generated above the damage threshold. Then, the degradation in photosensitivity of the Si photodiode irradiated by high power density pulses was measured as a function of laser irradiation time at the various wavelengths. The free charge carrier and thermal diffusion mechanisms could have been invoked to characterize the damage. The relative photosensitivity data calculated using the thermal diffusion model proposed in this paper have been compared with the experimental data irradiated above the damage threshold.

Study on thermal and UV stability of Liquid Crystal Display for Projection TV Application (프로젝션 TV 적용을 위한 액정 디스플레이의 열적 및 UV 안전성에 관한 연구)

  • Choi, Sung-Ho;Hwang, Jeoung-Yeon;Bae, Yu-Han;Lee, Whee-Won;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.287-288
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    • 2005
  • In this study, we have investigated electro-optical characteristics of thermal and UV stressed TN cells on the rubbed polyimide surface. Mono-domain alignments of thermal stressed TN cells over temperature of liquid crystal isotropic phase were almost same that of no thermal stressed TN cells. Also, threshold voltage and response time of thermal stressed TN cells were same that of no thermal stressed TN cells. Finally, the residual DC voltage of the thermal stressed TN cell on the polyimide surface show decrease of characteristics as increasing thermal stress time. Therefore, thermal stability of TN cell was decreased by high thermal stress for the long times.

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Study on Thermal Stability of Liquid Crystal Display for Projection TV Application (프로젝션 TV 적용을 위한 액정 디스플레이의 열적 안정성에 관한 연구)

  • Kang, Hee-Jin;Hwang, Jeoung-Yeon;Oh, Yong-Cheul;Seo, Dae-Shik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.11
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    • pp.1033-1036
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    • 2006
  • We have investigated electro-optical characteristics in three kinds of twisted nematic (TN) cells on the polyimide surface. The threshold voltage and the response time of thermal stressed TN cells were same that of no thermal stressed TN cells. There were little change of value in these TN cells. On the other hand, transmittance of no thermal stressed TN cells were better than that of thermal stressed TN cells. Transmittances of TN cells on the polyimide surface decreased by increasing thermal stress time. Moreover, the residual DC of the thermal stressed TN cells increased as increasing thermal stress temperature and time. Therefore, thermal stability of TN cells were decreased gradually by giving high thermal stress for a long time.

Threshold Voltage Properties of OFET with CuPc Active Material

  • Lee, Ho-Shik;Kim, Seong-Geol
    • Journal of information and communication convergence engineering
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    • v.13 no.4
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    • pp.257-263
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    • 2015
  • In this study, organic field-effect transistors (OFETs) using a copper phthalocyanine (CuPc) material as an active layer and SiO2 as a gate insulator were fabricated with varying active layer thicknesses and channel lengths. Further, using a thermal evaporation method in a high-vacuum system, we fabricated a CuPc FET device of the top-contact type and used Au materials for the source and drain electrodes. In order to discuss the channel formation and FET characteristics, we observed the typical current-voltage characteristics and calculated the threshold voltage of the CuPc FET device. We also found that the capacitance reached approximately 97 pF at a negative applied voltage and increased upon the accumulation of carriers at the interface of the metal and the CuPc material. We observed the typical behavior of a FET when used as an n-channel FET. Moreover, we calculated the threshold voltage to be about 15-20 V at VDS = -80 V.