• 한국분말재료학회지
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• 제30권6호
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• pp.478-483
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• 2023

High-entropy alloys (HEAs) are characterized by having five or more main elements and forming simple solids without forming intermetallic compounds, owing to the high entropy effect. HEAs with these characteristics are being researched as structural materials for extreme environments. Conventional refractory alloys have excellent high-temperature strength and stability; however, problems occur when they are used extensively in a high-temperature environment, leading to reduced fatigue properties due to oxidation or a limited service life. In contrast, refractory entropy alloys, which provide refractory properties to entropy alloys, can address these issues and improve the high-temperature stability of the alloy through phase control when designed based on existing refractory alloy elements. Refractory high-entropy alloys require sufficient milling time while in the process of mechanical alloying because of the brittleness of the added elements. Consequently, the high-energy milling process must be optimized because of the possibility of contamination of the alloyed powder during prolonged milling. In this study, we investigated the high-temperature oxidation behavior of refractory high-entropy alloys while optimizing the milling time.

• Membrane and Water Treatment
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• 제13권6호
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• pp.321-335
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• 2022

Copper-based Metal-organic framework (MOF) namely ([Cu (INA)₂]-MOF) is synthesized by ball milling and characterized using scanning electron microscopy (SEM) for the topography, microstructure, and elemental evidence determination, powdered X-ray diffraction (XRD) for the crystallinity measurement, thermogravimetric (TG) analysis was performed to determine the thermal stability of the material, and Fourier transformed infrared (FTIR) spectroscopy for functional groups identification. The use of [Cu (INA)₂]-MOF as hazardous removal material of β-agonists as persistent hazardous micro-pollutants in our environmental water is first reported in this study. The removal efficiency of the Cu-MOF is successfully determined to be 97.7% within 40 minutes, and the MOF has established an exceptional removal capacity of 835 mg L^-1 with 95 % percent removal on Clenbuterol (CLB) even after the 5th consecutive cycle. The Langmuir model of the adsorption isotherms was shown to be more favourable, while the pseudo-second-order model was found to be favoured in the kinetics. The reaction was exothermic and spontaneous from a thermodynamic standpoint, and the higher temperatures were unfavourable for the adsorption study of the CLB. As a result, the studied MOF have shown promising properties as possible adsorbents for the removal of CLB in wastewater.

• 한국대기환경학회지
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• 제14권1호
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• pp.63-72
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• 1998

Simultaneous CO and $C_3H_6$ oxidation was carried out over noble metal supported monolith catalysts in a flow thorugh type reactor at the temperature ranging from room temperature to $500^\circ$C. Pt and Pd were selected as major active species, 10wt% of Ce was impregnated as an additive and alumina and silica were used as supports. The reactant gases were simulated and the reaction products were analyzed by on-line G.C.. EDX, SEM, TGA, XRD and optical microscope were used to analyze the characteristics of the prepared catalysts. Under the given conditions in this study, the catalysts supported on alumina showed better activity for CO oxidation, while Pd catalysts showed better activity for $C_3H_6$ oxidation. The improvement of conversion due to increase in thermal stability possibily by Ce addition was observed only for Pt catalysts.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2019년도 추계학술대회
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• pp.166-167
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• 2019

Smart windows are used as windows and doors to determine cooling and heating efficiency in the construction field. It's characteristics can increase the energy saving efficiency. In addition, the function of the smart window that can control the light transmittance transmitted from the external environment of the building to the building according to the needs of the user is attracting attention. In this study, a liquid crystal cell capable of controlling light transmittance of 297 × 210 ㎟ was fabricated by using a liquid crystal device as an optical shutter. Analysis of transmittance change according to driving voltage and driving stability according to thermal environment, We confirmed the applicability of building exterior materials as smart windows.

• 한국초전도ㆍ저온공학회논문지
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• 제19권4호
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• pp.45-50
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• 2017

This paper presents a conceptual design and analysis for a 1-kW-class high-temperature superconducting rotating machine (HTSRM) rotor. The designed prototype is a small-scale integration system of a HTSRM and a HTS contactless rotary excitation device (CRED). Technically, CRED and HTSRM are connected in the same shaft, and it effectively charges the HTS coils of the rotor field winding by pumping fluxes via a non-contact method. HTS coils in rotor pole body and toroidal HTS wire in CRED rotor are cooled and operated by liquid nitrogen in cryogen tank located in inner-most of rotor. Therefore, it is crucial to securely maintain the thermal stability of cryogenic environment inside rotor. Especially, we critically consider not only on mechanical characteristics of the rotor but also on cryogenic thermal characteristics. In this paper, we conduct two main tasks covering optimizing a conceptual design and performing operational characteristics. First, rotor parameters are conceptually designed by analytical design codes. These parameters consider to mechanical and thermal performances such as mechanical strength, mechanical rigidity, and thermal heat losses of the rotor. Second, mechanical and thermal characteristics of rotor for 1-kW-class HTSRM are analyzed to verify the feasible operation conditions. Hence, three-dimensional finite element analysis (3D-FEA) method is used to perform these analyses in ANSYS-Workbench platform.

• Journal of Advanced Marine Engineering and Technology
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• 제39권3호
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• pp.201-205
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• 2015

극지와 해양에서 파이프라인은 최저 약 $-40^{\circ}C$의 매우 낮은 극한 온도에 노출된다. 이 경우 내부 유체는 상온에서와는 다른 유동특성을 나타내며, 3차원 유동해석을 통해 극한온도에 의한 내부유체의 압력, 온도, 속도, 액적분포 등의 특성 변화를 분석해야 한다. 또한 영하의 온도로 인해 내부 유체의 액적이 응결되며, 이로 인해 곡관부에서 충돌침식이 발생할 것으로 예상된다. 이러한 충돌침식은 장기간 운용되는 자원 이송망 등의 파이프라인의 안정성에 영향을 준다. 본 논문에서는 다성분 다상 유동 해석을 통해 극한 온도조건의 극지 및 해양 파이프라인에서 내부유체의 유동특성 및 충돌 침식에 대한 분석을 수행하였다.

• 방사선산업학회지
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• 제4권3호
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• pp.259-263
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• 2010

Carbon fibers are used as a reinforcement material in an epoxy matrix in advanced composites due to their high mechanical strength, rigidity and low specific density. An important aspect of the mechanical properties of composites is associated to the adhesion between the surface of the carbon fiber and the epoxy matrix. This paper aimed to evaluate the effects of electron beam irradiation on the physicochemical properties of carbon fibers to obtain better adhesion properties in resultant composite. Chemical structure and surface elements of carbon fiber were determined by FT-IR, elemental analysis and X-ray photoelectron spectroscopy, which indicated that the oxygen content increased significantly with increasing the radiation dose. Thermal stability of the carbon fibers was studied via the thermalgravimetric analysis. Surface morphology of carbon fiber was analyzed by scanning electron microscope. It was found that the degree of surface roughness was increased by electron beam irradiation.

• 방사선산업학회지
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• 제6권2호
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• pp.125-128
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• 2012

Kenaf (Hibiscuc cannabinus L.) is a renewable resource for industry and kenaf lignin is syringyl-guaiacyl lignin. The electron beam irradiated on kenaf core various doses range from 200 to 1,000 kGy to improve delignification. The yield of lignin, which is 2.53 g from 10 g of electron beam irradiated kenaf core. A comparison extracted lignin between from native kenaf core and electron beam irradiated kenaf core was then studied through chemical structure and bonding property by a Fourier transform infrared spectroscopy (FT-IR). Thermal stability of the extracted-purified lignin was performed via differential scanning calorimetry (DSC). These results were explained that electron beam irradiation increased performance of extracting efficiency.

• 방사선산업학회지
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• 제5권3호
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• pp.227-230
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• 2011

Pulps were separated from wood chips using an Electron beam irradiation (EBI) treatment without a NaOH-AQ (anthraquinone) treatment for cooking. The methods were based on a hot water treatment after EBI and two-step bleaching processes. Chemical compositions and FT-IR spectroscopy demonstrated that the content of lignin and hemicellulose in the bleached wood pulps treated with various EBI dose decreased with an increase of EBI doses. Specifically, the lignin in the bleached with pulps treated at 600 kGy of EBI dose was almost completely removed. Moreover, TGA analysis showed that a thermal stability increased with increasing the content of cellulose but the lignin decomposed slowly over the wide region.

• 한국진공학회지
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• 제15권5호
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• pp.499-505
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• 2006

열 화학기상법으로 만든 GaN와 GaP 나노와이어에서 전계 방출과, 산소와 아르곤 분위기에서 안정성에 대해 조사하였다. GaN 나노와이어의 경우 산소 분위기에서 전계 방출이 급격하게 줄었으나, GaP에서는 그렇지 않았다. 두 나노와이어 모두 아르곤 분위기에서는 큰 변화가 없었다. GaP 나노와이어의 외부에 존재하는 산화물 층이 전자 방출 안정성에 크게 기여한 것으로 생각된다. 나노와이어에서 방출된 전자의 에너지 분포를 통해 반도체 나노와이어는 탄소 나노튜브와 그 전계 방출 메카니즘이 다름을 유추할 수 있었다.