• Steel and Composite Structures
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• v.35 no.6
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• pp.789-798
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• 2020

The effect of Chitosan (CS), Carbon Nanotube (CNT) and hybrid (CS-CNT) fillers on the natural frequency of drilled composite plate is investigated by experimentally in this study. The numerical validation is also made with a program based on Finite Element Method (SolidWorks). Nine types filled and one neat composite plates are used in the study. The fillers ratios are 1% CS, 2% CS, 3% CS, 0.1% CNT, 0.2% CNT, 0.3% CNT, 1% CS+0.3% CNT, 2% CS+0.3% CNT, 3% CS+0.3% CNT. The specimens cut to certain sizes by water jet from the plates 400 mm × 400 mm in dimensions. Some of them are drilled in certain dimensions with drill. The natural frequency of each specimen is measured by the vibration test set up to determine the vibration characteristic. The vibration test set up includes an accelerometer, a current source power unit, a data acquisition card and a computer. A code is written in Matlab^® program for the signal processing. The study are investigated and discussed in four main points to understand the effect of the fillers on the natural frequency of the composite plate. These are the effect of fillers contents and amounts, orientation angles of fibers, holes numbers and holes sizes. As results, the natural frequency of the plate with 1% CS and 0.1% CNT hybrid filler is lower than those of the plates with other fillers ratios for 45° orientation angle. Besides, in the composite plate with 0° orientation angle, the natural frequency increases with increasing the filler ratio. Moreover, the natural frequency increases until a certain hole number and then it decreases. Furthermore, the natural frequency is not affected until a certain hole diameter but then it decreases.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.520-521
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• 2005

To observe the orientation of carbon nanotubes (CNTs) dispersed in nematic liquid crystal (NLC), CNT-doped homogeneously-aligned NLC cells driven by in-plane field was fabricated. The CNTs were aligned with a LC director in the initial state, whereas the CNTs disturbed the LC director above critical ac field. We observed motional textures in the form of vertical stripes in the local area between electrodes, which were associated with a deformation of the LC director orientation. This suggests that CNTs start to vibrate three dimensionally with translational motion. The hysteresis studies of voltage-dependent transmittance under dc electric field show that the amount of residual dc is greatly reduced due to ion trapping by CNT.

• Composites Research
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• v.29 no.5
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• pp.269-275
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• 2016

Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.101-104
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• 2005

Recently, competition between LC modes for LC TVs becomes high. In this paper, status of each mode is briefly reviewed with commenting on its electro-optic characteristics and possible application fields. Further, to understand effects of carbon nanotubes (CNTs) dispersed in nematic liquid crystal on electro-optic characteristic and orientation of the LC, CNT-doped NLC cells are made and evaluated. The hysterisis studies of voltage-dependent capacitance show that the amount of residual dc is greatly reduced due to ion trapping by CNTS.

• Composites Research
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• v.33 no.6
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• pp.415-420
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• 2020

The interfacial properties in carbon fiber composites, which control the overall mechanical properties of the composites, are very important. Effective interface enhancement work is conducted on the modification of the carbon fiber surface with carbon nanotubes (CNTs). Nonetheless, most surface modifications methods do have their own drawbacks such as high temperatures with a range of 600~1000℃, which should be implemented for CNT growth on carbon fibers that can cause carbon fiber damages affecting deterioration of composites properties. This study includes the use of in-situ interfacial polymerization of polyamide 610/CNT to fabricate the carbon fiber composites. The process is very fast and continuous and can disperse CNTs with random orientation in the interface resulting in enhanced interfacial properties. Scanning electron microscopy was conducted to investigate the CNT dispersion and composites morphology, and the thermal stability of the composites was analyzed via thermogravimetric analysis. In addition, fiber pull-out tests were used to assess interfacial strength between fiber and matrix.

• Steel and Composite Structures
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• v.30 no.1
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• pp.31-46
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• 2019

In the present study, the various dynamic properties of MWCNT embedded fiber reinforced polymer uniform and tapered composite (MWCNT-FRP) plates are investigated. Various configurations of a tapered composite plate with ply-drop off and uniform composite plate have been considered for the development of the finite element formulation and experimental investigations. First order shear deformation theory (FSDT) has been used to derive the kinetic and potential energy equations of the hybrid composite plates by including the effect of rotary inertia, shear deformation and non-uniformity in thickness of the plate. The governing equations of motion of FRP composite plates without and with MWCNT reinforcement are derived by considering a nine- node rectangular element with five degrees of freedom (DOF) at each node. The effectiveness of the developed finite element formulation has been demonstrated by comparing the natural frequencies and damping ratio of FRP composite plates without and with MWCNT reinforcement obtained experimentally. Various parametric studies are also performed to study the effect of CNT volume fraction and CNT aspect ratio of the composite plate on the natural frequencies of different configurations of CNT reinforced hybrid composite plates. Further the forced vibration analysis is performed to compare the dynamic response of the various configurations of MWCNT-GFRP composite plate with GFRP composite plate under harmonic excitations. It was observed that the fundamental natural frequency and damping ratio of the GFRP composite plate increase approximately 8% and 37% respectively with 0.5wt% reinforcement of MWCNT under CFCF boundary condition. The natural frequencies of MWCNT-GFRP hybrid composite plates tend to decrease with the increase of MWCNT volume fraction beyond 2% due to agglomeration of CNT's. It is also observed that the aspect ratio of the CNT has negligible effect on the improvement of dynamics properties due to randomly orientation of CNT's.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.9
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• pp.999-1005
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• 2011

The effects of strain-induced crystallization (SIC) on the mechanical properties of elastomeric composites as functions of extension ratio (${\lambda}$), multiwalled carbon nanotube (CNT) content, and carbon black (CB) content are investigated. The differential scanning calorimetry (DSC) analysis shows that the degree of crystallinity increases with the increase in the CB and CNT content. As ${\lambda}$ increases, the glass transition temperature (Tg) of the composites increases, and the latent heat of crystallization (LHc) of the composites is maximum at ${\lambda}$=1.5. It is found that the mechanical properties have a linear relation with LHc, depending on the CNT content. According to the TGA (thermogravimetric analysis), the weight loss of the composite matrix is 94.3% and the weight of the composites decreases with the filler content. The ratio of tensile modulus ($E_{comp}/E_{matrix}$) is higher than that of tensile strength (${\sigma}_{comp}/{\sigma}_{matrix}$) because of the CNT orientation inside the elastomeric composites.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.7
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• pp.612-615
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• 2009

We need to control the growth orientation of CNTs on a substrate for applications to various electric devices. Generally, the flow direction of feed gases and electric field between two electrode affect to growth orientations of CNTs. In this paper, we varied tilt degrees $(0^{\circ},\;20^{\circ},\;35^{\circ},\;50^{\circ},\;65^{\circ},\;90^{\circ})$ of substrates on a cathode and DC bias voltages (0, 500, 700 V) applied between two electrodes in order to change growth orientations of CNTs. We confirmed that tilt degrees of the substrate and variation of DC bias voltages affected to the shape and orientation of the grown CNTs on the substrate.

• Composites Research
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• v.30 no.3
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• pp.193-201
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• 2017

Molecular dynamics simulation and the Mori-Tanaka micromechanics study are performed to investigate the effect of the covalent grafting between CNT and polyester on the mechanical behavior and load transfer of nanocomposites. The transversely isotropic stress-strain curves are determined through the tension and shear simulations according to the covalent grafting. Also, isotropic properties of randomly dispersed nanocomposites are obtained by orientation averaging the transversely isotropic stiffness matrix. By addressing the grafting, the transverse Young's modulus and shear moduli of the nanocomposites are improved, while the longitudinal Young's modulus decreases due to the degradation of the grafted CNT.

• Journal of Korea Society of Industrial Information Systems
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• v.11 no.4
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• pp.66-71
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• 2006

Carbon nanofibers have synthesized a low temperature using DC Ar plasma and Fe-Phthalocyanine, and a characteristic difference of the synthesized CNF according to the location of the substrate was investigated. The carbon nanofibers had about 100nm diameter and up to $10{\mu}m$ length. These were grown in random orientation. There are two shapes in the CNFs, screw and straight line shapes. Furthermore, we found the selective growth of nanofibers on the scratched substrates. The density of CNFs synthesized on the position (a) were higher than that synthesized on the position (b) [See the Fig. 2]. Also, the length of CNFs was different. In the shape, CNFs with screw and straight line shape were synthesized in the position (a), but. only CNFs with straight line shape were synthesized in the position (b). The difference have an important effect on the field emission characteristics.