• Title/Summary/Keyword: Ternary Solution

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Development of latent footwear impression on porous surfaces using DL-alanine solution and 1,2-indanedione solution (DL-alanine과 1,2-indanedione을 이용한 종이에 남은 족적의 증강)

  • Hong, Sungwook;Kim, Euna;Park, Miseon;Lee, Eunhye
    • Analytical Science and Technology
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    • v.30 no.6
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    • pp.303-311
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    • 2017
  • A new method for obtaining the photoluminescence of footwear impression by using 1,2-indandione (1,2-IND) solution, which is a latent fingerprint-developing reagent, was studied. A binary complex of DL-alanine and 1,2-IND was prepared by spraying a DL-alanine solution and the 1,2-IND solution (an amino acid sensitive reagent) onto dry or wet origin footwear impression deposited on the surface of printed A4 paper. This binary complex reacts with the trace metal component in the footwear impression to form a ternary complex that exhibits photoluminescence. However, when 5-methylthioninhydrin (5-MTN) solution was used instead of 1,2-IND, no consistent photoluminescence was observed even under identical treatment conditions. In addition, when footwear impressions treated with DL-alanine and 1,2-IND solutions were stored under various temperature conditions (30, 40 and $50^{\circ}C$) and various humidity conditions (30 %, 40 %, 50 % and 60 % RH), the contrast between the footwear impression and the background decreased. Optimal footwear impression photoluminescence was obtained when the footwear impressions treated with DL-alanine and 1,2-IND solutions were stored at $30^{\circ}C$ and 30 % RH for 1 h. The sensitivity of the developed method was ccompared with the sensitivities of three known methods - black gelatin lifting, 2,2'-dipyridyl treatment, and 8-hydroxyquinoline treatment. The results showed that the sensitivity of the developed method was worse than that of the black gelatin lifting method but better than that of 2,2'-dipyridyl or 8-hydroxyquinoline treatment method.

Synthesis and Characterization of PtPd and PtRuPd Anode Catalysts for Direct Methanol Fuel Cells

  • Horvath G.;Park K. W.;Sung Y. E.
    • 한국전기화학회:학술대회논문집
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    • 2002.07a
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    • pp.211-218
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    • 2002
  • In this study, Pt/Pd (1.1), PtPd (2:1) and PtPd (3:1) binary catalysts and Pt/Ru/Pd (5:4:1) ternary catalyst were designed. The catalysts were synthesized by impregnation method using $NaBH_4$ as a reducing agent. A good catalyst for methanol oxidation requires low on-set potential, stable durability and low activation energy. In order to investigate the catalytic activity for the methanol oxidation, electrochemical measurements such as cyclic voltammetry and chronoamperometry were peformed in sulfuric acid with/without methanol solution. In order to calculate the activation energy of the reaction, electrochemical measurements were also tested at different temperatures. For investigation of the structural analysis such as particle size and alloying, X-ray diffraction and transmission electron microscopy analysis were used. In order to identify the role of the Pd and to determine the composition of the surface of the Pt/Pd nanoparticles, X-ray photoelectron spectroscopy (XPS) analysis was investigated. The XPS spectra of Pd showed that Pd appears only as a metallic state in the binary catalysts. The chemical states of Pt in PtPd catalysts are both metallic and oxidative. Polarization curves and power density data were obtained by testing the DMFC unit cell performance of PtPd and PtRuPd catalysts. These data showed that Pt/Pd (2:1) and Pt/Ru/Pd (5:4:1) have better performance than Pt and Pt/Ru, respectively.

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The characteristics of the sulfur-doped $In_{1-x}Ga_xP$ Light emitting diode (Sulfur를 첨가한 $In_{1-x}Ga_xP$의 발광 다이오드 특성)

  • Cho, M.W.;Moon, D.C.;Kim, S.T.
    • Proceedings of the KIEE Conference
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    • 1988.11a
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    • pp.168-171
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    • 1988
  • The p-n homo junction diode of the III-V ternary alloy semiconductor $In_{1-x}Ga_xP$ : S grown by the temperature gradient solution (TGS) was fabricated by Zn-diffusion, and it's characteristics was investigated. The carrier concentration of $In_{1-x}Ga_xP$ doped with sulfur, 0.5 mol %, was $1{\times}10^{17}cm^{-3}$ and the mobility was varied with the composition. In the case that the diffusion time was constant as 30 minutes. The temperature dependence of diffusion coefficient was decreased from D= $4.2{\times}10^{-5}$ exp (-1.74/$k_{B}T$) to D= $2.5{\times}10^{-5}$ exp (-3.272/$k_{B}T$) with increasing of composition $\times$ from 0.43 to 0.98. The major peak of E.L spectrum was due to D-A pair recombination and the peak intensity was increased with the increasing of input current. And the E.L intensity was decreased with the increasing temperature, and shift to the long wavelength. The luminescence efficiencies measured at $5^{\circ}C$, atmosphere temperature, was decreased from $2.6{\times}10^{-4}$% to $9.49{\times}10^{-6}$ % with increasing of composition it from 0.39, direct transition region, to 0.98, indirect transition region.

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Multi-match Packet Classification Scheme Combining TCAM with an Algorithmic Approach

  • Lim, Hysook;Lee, Nara;Lee, Jungwon
    • IEIE Transactions on Smart Processing and Computing
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    • v.6 no.1
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    • pp.27-38
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    • 2017
  • Packet classification is one of the essential functionalities of Internet routers in providing quality of service. Since the arrival rate of input packets can be tens-of-millions per second, wire-speed packet classification has become one of the most challenging tasks. While traditional packet classification only reports a single matching result, new network applications require multiple matching results. Ternary content-addressable memory (TCAM) has been adopted to solve the multi-match classification problem due to its ability to perform fast parallel matching. However, TCAM has a fundamental issue: high power dissipation. Since TCAM is designed for a single match, the applicability of TCAM to multi-match classification is limited. In this paper, we propose a cost- and energy-efficient multi-match classification architecture that combines TCAM with a tuple space search algorithm. The proposed solution uses two small TCAM modules and requires a single-cycle TCAM lookup, two SRAM accesses, and several Bloom filter query cycles for multi-match classifications.

Phase Stability and Plasma Erosion Resistance of La-Gd-Y Rare-earth Oxide - Al2O3 Ceramics (La-Gd-Y 희토류계 산화물-알루미나 세라믹스의 상안정화 영역과 내플라즈마 특성)

  • Kim, Kyeong-Beom;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.540-545
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    • 2010
  • In this study, we have investigated new plasma resistant materials with less usage of rare-earth oxides than $Y_2O_3$ which is currently used in the semiconductor industry. We observed the stability ranges of $(Gd{\cdot}Y)_3Al_5O_{12}$ and $(La{\cdot}Y)Al_{11}O_{18}$ ternary systems, and measured their etch rates under typical fluorine plasma. $(Gd{\cdot}Y)_3Al_5O_{12}$ system showed an extensive solid solution up to 80 mol% gadolinium, but $(La{\cdot}Y)Al_{11}O_{18}$ showed a negligible substitution between rare-earth ions, which can be explained by the differences between the ionic radii. The etch rates depended on the total amount of rare-earth oxides but not on the substitution of the rare-earth ions. When the specimen was examined using XPS after the exposure to fluorine plasma, the strong surface fluorination was observed with a shift of the binding energy to higher energy.

Diffusion Characteristics for Chloride Ion of Concrete Subjected to Sulfate Attack (황산염 침투를 받은 콘크리트의 염소이온 확산특성)

  • Park, Jae-Im;Bae, Su-Ho;Yu, Jae-Won;Lee, Kwang-Myong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.213-214
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    • 2010
  • An objective of this experimental research is to investigate the diffusion characteristics for chloride ion of concrete subjected to sulfate attack. For this purpose, concretes with three types of cement such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) containing mineral admixtures were made for water-binder ratios of 32% and 43%. The concrete specimens were immersed in sulfate solution for 365 days, and then the resistance against chloride ion penetration of them were estimated by using NT BUILD 492. It was observed from the test results that the resistance to chloride ion penetration of concrete subjected to sulfate attack was greatly decreased than that of standard curing concrete under the same age.

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Synthesis Processing of the Fine (Ni, Zn)-ferrite Powder for $CO_2$ Decomposition of the Flue Gas in the Iron Foundry (제철소의 연소배가스 $CO_2$ 분해용 (Ni, Zn)-ferrite 미세분말 합성공정 연구)

  • 김정식;안정률
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.164-167
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    • 2000
  • Flue gases in the iron foundry consist of 15~20% CO2 as an air pollution gas whose emission should be mitigated in order to protect the environment. In the present study, ultrafine powders of NixZn1-xFe2O4 as a potential catalyst for the CO2 decomposition were prepared by the coprecipitation methods. Oxygen deficient ferrites (MeFe2O4-$\delta$) can decompose CO2 as C and O2 at a low temperature of about 30$0^{\circ}C$. The XRD result of synthesized ferrites showed the spinel structure of ferrites and ICP-AES and EDS quantitative analyses showed the composition similar with initial molar ratios of the mixed solution prior to reaction. The BET surface area of the (Ni, Zn)-ferrites was about 77~89.5$m^2$/g and their particle size was observed about 10~20 nm. The CO2 decomposition efficiency of the oxygen deficient (Nix, Zn1-x)-ferrites was the highest at x=0.3, and the ternary (Ni, Zn)-ferrites was better than that of binary Ni-ferrites.

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Fundamental Characteristics of High Strength SCMs Concrete According to Mixing Ratio of FA and BS (FA 및 BS의 혼합비율 변화에 따른 3성분계 고강도 콘크리트의 기초적 특성)

  • Kim, Min-Sang;Moon, Byeong-Yong;Lee, Jae-Jin;Park, Sung-Bae;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.154-155
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    • 2017
  • With the recent development in construction industry, industrial by-products fly ash(FA) and blast furnace slag(BS) have been used in large quantities as an alternative to cement, as a solution for environmental problems and resource exhaustion. This study analyzed the basic characteristics according to the changes in replacement ratio and mixing ratio of FA and BS in high strength SCMs concrete, from which in turn it sought to find the optimal mixing ratio for high strength concrete The results showed that in unhardened concrete the more the replacement ratio and FA mixing ratio increases the slump flow will increase while amount of air decreases, and setting time is delayed. In hardened concrete the more the replacement ratio and FA mixing ratio increases the more the overall compression strength decreases, but until 28 days of material age the larger of the BS ratio displayed the best compression strength.

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The Phase Behavior of Nonionic Surfactants having Sucrose as Hydrophilic Group(II) - The Phase Behavior of Sucrose Monopalmitate/Alkanol/Water System - (당류를 친수기로 한 비이온성 계면활성제계의 상거동(제2보) - 슈크로오스 팔미테이트/알칸올/물 계에서의 상거동 -)

  • Lee, Hyang-Woo;Lee, Jin-Hee;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.246-251
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    • 1997
  • The phase behavior of sucrose monopalmitate/alkanol/water ternary system was investigated. According to compositions of three components ranging from micellar(or inverse micellar) solution up to various lyotropic liquid crystalline(LC) phase, each texture of the separated phases was identified by crossed polarizers equipped with a camera whose stage was connected to a thermostatic circulator. As the carbon atom number in alkanol of the polar oily substance increases, patterns of the various LC phases were also observed hexanol

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Silica aerogels for potential sensor material prepared by azeotropic mixture (공비혼합물로 제조된 다공성 센서재료용 실리카 에어로젤)

  • Shlyakhtina, A.V.;Oh, Young-Jei
    • Journal of Sensor Science and Technology
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    • v.16 no.6
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    • pp.395-400
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    • 2007
  • Ambient drying sol-gel processing was used for monolithic silica ambigels in the temperature range of $130-250^{\circ}C$. A new method of mesopore ambigels, which mean the aerogels prepared by ambient pressure drying process synthesis, is suggested at first. This method includes two important approaches. The first point is that $SiO_{2}$ surface modification of wet gel was performed by trimethylchlorosilane in n-butanol solution. This procedure is provided the silica gel mesopore structure formation. The second point is a creation of the ternary azeotropic mixture water/n-butanol/octane as porous liquid, which is effectively provided removing of water such a low temperature by 2 step drying condition under ambient pressure. The silica aerogels, which were prepared by ambient pressure drying from azeotropic mixture of water/n-butanol/octane, are transparent, crack-free and mesoporous (pore size ${\sim}$ 5.6 nm) with surface area of ${\sim}$ $923{\;}m^2/g$, bulk density of $0.4{\;}g/cm^3$ and porosity of 85 %.