• Fire Science and Engineering
• /
• v.28 no.1
• /
• pp.44-51
• /
• 2014

Smoke from fire is a mixture of combustion gases and particles which include micro-droplets formed from condensed organic vapors and carbonaceous agglomerates. The inhalation of smoke particles causes adverse health effects, and it is prerequisite for the hazard and risk analysis of the smoke particles to know how they behaviour in the respiratory tract. The characteristics of the absorption and adsorption of toxic gases and the amount and location of the particle deposition within the respiratory tract that determine the adverse health effects are related to the morphology and the size distribution of smoke particles. In the present work, as a preliminary study for the adverse health effects of smoke particles, the morphologies of the smoke particles from combustible materials were investigated for each fire stage: smouldering, well-ventilated flaming, small under-ventilated flaming, fully-developed under-ventilated fire. The steady-state tube furnace method given in ISO/TS 19700 was used for the generation of smoke particles. The fire stages were controlled by changing furnace temperature and equivalent ratio. The morphologies were analyzed by using Transmission Electron Microscope (Bio-TEM) by collecting the particles on TEM grids put on each stage of a cascade impactor.

• Fire Science and Engineering
• /
• v.30 no.4
• /
• pp.121-127
• /
• 2016

This study analyzed the structural and electrical characteristics of an iron fittings type Corrugated Stainless Steel Tubing (CSST) damaged by the Primary Current Injection Test System (PCITS). CSST consists of cladding, tube, nuts, clamp ring, flare cap, socket, and ball valve. For an evaluation of the dielectric withstand voltage, the area between the live part and non-live part of the CCST shall withstand a voltage of 220 V AC for one minute. For an evaluation of the insulation performance by 500 V DC, it is required that the insulation exceed more than $1M{\Omega}$ before the temperature rise test, $0.3M{\Omega}$ after the test. Although the average resistance of the product was $11.5m{\Omega}$, that of the product damaged at a current of 130 A by the PCITS was $11.50m{\Omega}$. Furthermore, parts of the cladding were melted and black smoke appeared when a current of 130 A applied for 10 s. After 60 s, most parts were heated and turned red. At 120 s, the parts that turned red had widened. Although it did not form a normal distribution because the P value was 0.019 with a confidential interval of 95%, it revealed outstanding characteristics with an AD (Anderson-Darling) value of 0.896 and a standard deviation of 0.5573.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2009.06a
• /
• pp.84-85
• /
• 2009

New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

• Journal of Korea Water Resources Association
• /
• v.45 no.6
• /
• pp.557-568
• /
• 2012

In order to understand the hydrological processes on the mountainous forest, the configuration of soil evaporation (E) out of evapotranspiration (ET) is a challenging and important topic. In this study, we attempted to understand the soil evaporation process for a humid forest hillslope via measuring and analyzing soil moistures with a sampling interval in 2 hours at three locations for 10 days between May 22th and 31th 2009. Two methods were used to estimate soil evaporation in every 2hr; one is a method using soil moisture measurement ($E_{SM}$), the others methods are based on Penman equation (Penman (1948), Staple (1974), Konukcu (2007), Equilibrium Penman ($E_{equili}$)). As a critical parameter in determining $E_{SM}$, the dry surface layer (DSL), was estimated using energy balance equation. The accumulated soil evaporation ($E_{SM}$) of A, B, C points were estimated as 2.09, 1.08 and 2.88 mm, respectively. The estimated evaporation of Penman (1948), Staple (1974), Konukcu (2007), $E_{equili}$ were 4.91, 8.80, 8.63 and 3.28 mm. The proposed method with soil moisture measurement showed lower soil evaporations than the other conventional methods. The increasing soil temperature and interaction between soil and atmosphere due to existence of litter and DSL are considered as dominant factors for soil evaporation. The $E_{SM}$ has the apparent lag time between 2 and 4 hr compared with $E_{equili}$ and net radiation. The DSL and surface resistance ($r_s$) were increased as soil moisture was decreased for in this study. The estimated DSL through the temporal distribution analysis of soil moisture and tension measurements was also similar to that of the energy balance relationship.

• Korean Journal of Microbiology
• /
• v.52 no.3
• /
• pp.365-374
• /
• 2016

In high-latitude regions, temperature has risen ($0.6^{\circ}C$ per decade) and this leads to the increase in microbial degradability against soil organic carbon (SOC). Furthermore, the decomposed SOC is converted into green-house gases ($CO_2$ and $CH_4$) and their release could further increase the rate of climate change. Thus, understanding the microbial diversity and their functions linked with SOC degradation in soil-thawing model is necessary. In this study, we divided tundra soil from Council, Alaska into two depth regions (30-40 cm and 50-60 cm of depth, designated as SPF and PF, respectively) and incubated that for 108 days at $0^{\circ}C$. A total of 111,804 reads were obtained through a pyrosequencing-based metagenomic study during the microcosm experiments, and 574-1,128 of bacterial operational taxonomic units (OTUs) and 30-57 of archaeal OTUs were observed. Taxonomic analysis showed that the distribution of bacterial taxa was significantly different between two samples. In detail, the relative abundance of phyla Actinobacteria and Firmicutes largely increased in SPF and PF soil, respectively, while phyla Crenarchaeota was increased in both soil samples. Weight measurement and gel permeation chromatography of the SOC extracts demonstrated that polymerization of humic acids, main component of SOC, occurred during the microcosm experiments. Taken together our results indicate that these bacterial and archaeal phyla could play a key function in SOC degradation and utilization in cold tundra soil.

• Applied Chemistry for Engineering
• /
• v.19 no.2
• /
• pp.228-235
• /
• 2008

Nickel plating thickness increased with the electric current density, and the augmentation was more thick in $6{\sim}10A/dm^2$ than low current. Hull-cell analysis was tested to evaluate the current density. Optimum thickness was obtained at a temperature of $60^{\circ}C$, and the pH fluctuation of 3.5~4.0. Over the Nickel ion concentration of 300 g/L, plating thickness increased with the current density. The rate of decrease in nickel ion concentration was increased with the current density. The quantity of plating electro-deposition was increased at the anode surface, which was correlated with the increase of plating thickness. The plating thickness was increased because of the quick plating speed. However, the condition of the plating surface becomes irregular and the minuteness of nickel plating layer was reduced with the plating rate. After the corrosion test of 25 h, it was resulted in that maintaining low electric current density is desirable for the excellent corrosion resistance in lustered nickel plating. According to the program simulation, the thickness of diffusion layer was increased and the concentration of anode surface was lowered for the higher current densities. The concentration profile showed the regular distribution at low electric current density. The field plating process was controlled by the electric current density and the plating thickness instead of plating time for the productivity. The surface physical property of plating structure or corrosion resistance was excellent in the case of low electric current density.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.37 no.1
• /
• pp.80-91
• /
• 2017

The objective of this study was to select a model showing high-levels of interpretability which is high in R-squared value in terms of predicting the yield in the mixed pasture using the factors of fertilization, seeding rate and years after pasture establishment in steps, as well as the climate as a basic factor. The processes of constructing the yield prediction model for the mixed pasture were performed in the sequence of data collection (forage and climatic data), preparation, analysis, and model construction. Through this process, six models were constructed after considering climatic variables, fertilization management, seeding rates, and periods after pasture establishment years in steps, thereafter the optimum model was selected through considering the coincidence of the models to the forage production theories. As a result, Model VI (R squared = 53.8%) including climatic variables, fertilization amount, seeding rates, and periods after pasture establishment was considered as the optimum yield prediction model for mixed pastures in South Korea. The interpretability of independent variables in the model were decreased in the sequence of climatic variables(24.5%), fertilization amount(17.8%), seeding rates(10.7%), and periods after pasture establishment(0.8%). However, it is necessary to investigate the reasons of positive correlation between dry matter yield and days of summer depression (DSD) by considering cultivated locations and using other cumulative temperature related variables instead of DSD. Meanwhile the another research about the optimum levels of fertilization amounts and seeding rates is required using the quadratic term due to the certain value-centered distribution of these two variables.

• Journal of the Korean Electrochemical Society
• /
• v.10 no.1
• /
• pp.7-13
• /
• 2007

We synthesized and investigated $La_{0.75}Sr_{0.25}FeO_3$ by Glycine Nitrate Process(GNP) method used as cathode materials for SOFC(solid oxide fuel cell). Optimized amount of glycine is 3.17 mol. ICP elemental composition analysis indicated that the stoichiometry of the synthesized powders have nearly nominal values. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The sample powders were isostatically pressed to form a pellet. The green body was sintered at $1200^{\circ}C$ and the relative density of the sintered specimens were measured by Archimedes mettled. We measured electrochemical performance of LSF by AC impedance spectroscopy. Resistance of LSF shows lower value than that of LSM throughout all temperature region. The anode-supported solid oxide fuel cell showed a performance of $342mW/cm^2(0.7V,\;488mA/cm^2)$ at $750^{\circ}C$. The electrochemical characteristics of the single cell were examined by at impedance method.

• Polymer(Korea)
• /
• v.25 no.4
• /
• pp.496-502
• /
• 2001

Thermally stable polyquinonediimines(PQDI) containing di-azobenzene in the side chain were synthesized by means of condensation polymerization under $TiCl_4$. The synthesized monomers and polymers were identified by FT-IR, $^1H-NMR$, and elemental analysis. Especially, the polymerization of PQDI was confirmed by the double-bonding peak of >C=N appearing near 1625cm$^{-1}$ in FT-IR spectrum. PQDI with di-azobenzene group in one side chain was insoluble in methanol, acetone and non-polar solvents having big dielectric constant, but had good solubility in polar solvents having small dielectric constant. Molecular weight distribution of PQDI measured by GPC was 1.38. It was confirmed to be amorphous polymer through X-ray diffraction by the appearance of the halo in case of PQDI containing di-azobenzene in the side chain. The glass transition temperature ($_g$) of synthesized polymer was measured to be 116$^{\circ}C$ by differential scanning calorimetry. The SHG value for ${\chi}^{(2)}$ was 1.2 pm/V (${\lambda}$ = 1.542 ${\mu}$m). The SHG value slightly decreased in an early stage but showed temporal stability after 20 hours.

• The Korean Journal of Mycology
• /
• v.24 no.2 s.77
• /
• pp.111-126
• /
• 1996

Transfer of the isolated nuclei from Lentinus edodes into protoplasts of Pleurotus florida was induced with polyethlene glycol (PEG) and $CaCl_2$. The intergeneric transfer products were classified into nuclear hybrid, heterokaryon or synkaryon, and reconstituted cell. These progenies except nuclear hybrids formed mature fruiting bodies on sawdust rice bran medium. Formation of fruit bodies was influenced by several factors such as light, temperature, nutrition and physic state of the culture media. Most of fruiting body characters were similar to those of P. florida in synkaryon and L. edodes in reconstituted cell, respectively. All these basidiocarps had clamp connections though initial heterokaryon colonies were lacking. Isozyme patterns of intergeneric progenies were quite different from those of parents. DNA polymorphisms of transfer products were also compared by random amplified polymorphic DNAs (RAPD) analysis based on polymerase chain reaction. The RAPD patterns were different from those of donor and recipient. DNA fingerprints ranged in size from 0.25 to 4.0 Kb. On the basis of RAPD, the transfer products were classified into five groups. Two synkaryon were analysed with distribution of progenies and segregation of genetic markers by random spore analyses. The genetic markers were segregated into wild type and riboflavine requiring auxotrophs.