• Title/Summary/Keyword: Tailored-Properties

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Progress In Commercialization Of Light Emitting Polymers: Dow Polyfluorenes

  • Wu, W.;Inbasekaran, M.;Hudack, M.;Welsh, D.;Yu, W.;Chen, Y.;Wang, C.;Kram, S.;Tacey, M.;Bernius, M.;Fletcher, R.;Kiszka, K.;Munger, S.;O'Brien, J.;Hills, M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.340-343
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    • 2002
  • We report here our recent progress in the development and commercialization of polyfluorenes emitting red, green and blue (ROB) colors as materials for light emitting diodes (LEDs). Our patented version of the Suzuki coupling process has been used to synthesize a variety of fluorenebased homopolymers and copolymers emitting colors across the entire visible spectrum. The optical and electronic properties of the polymers are tailored through selective incorporation of different aromatic units into the polyfluorene backbone. Our latest green emitter, reported herein, provides very efficient devices with a low turn-on voltage of 2.25 V, a peak efficiency of 10.5 Cd/A at 6,600 Cd/$m^2$ at 4.85 V. These devices maintain an efficiency of greater than 10 Cd/A up to 50,000 Cd/$m^2$ and demonstrate very good stability as exemplified by a device half-life of greater than 1,500 hours starting from 1,100 Cd/$m^2$. Considerable progress has also been made with red and blue emitters and will be the subject of this presentation.

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Low-temperture Synthesis of CdTe/Te Core-shell Hetero-nanostructures by Vapor-solid Process

  • Song, Gwan-U;Kim, Tae-Hun;Bae, Ji-Hwan;Lee, Jae-Uk;Park, Min-Ho;Yang, Cheol-Ung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.580-580
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    • 2012
  • Heterostructures has unique and important properties, which may be helpful for finding many potential applications in the field of electronic, thermoelectric, and optoelectronic devices. We synthesized CdTe/Te core-shell heterostructures by vapor-solid process at low temperatures using a quartz tube furnace. Two step vapor-solid processes were employed. First, various tellurium structures such as nanowires, nanorods, nanoneedles, microtubes and microrods were synthesized under various deposition conditions. These tellurium nanostructures were then used as substrates in the second step to synthesize the CdTe/Te core-shell heterostructures. Using this method, various sizes, shapes and types of CdTe/Te core-shell structures were fabricated under a range of conditions. These structures were analysed by scanning electron microscopy, high resolution transmission electron microscopy, and energy dispersive x-ray spectroscopy. The vapor phase process at low temperatures appears to be an efficient method for producing a variety of Cd/Te hetero-nanostructures. In addition, the hetero-nanostructures can be tailored to the needs of specific applications by deliberately controlling the synthetic parameters.

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Zeolite Membranes: Functionalizing of Properties by Tailored Compositions (제올라이트 분리막: 조성 변경을 통한 분리막 성질의 조절)

  • Richter, Hannes;Weyd, Marcus;Simon, Adrian;Kuhnert, Jan-Thomas;Gunther, Christiane;Voigt, Ingolf;Michaelis, Alexander
    • Membrane Journal
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    • v.27 no.6
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    • pp.469-476
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    • 2017
  • Membrane separation is a technology of low energy consumption. Membranes made of zeolites are of great interest because their fixed and open pores in the size of small molecules inside crystalline structures allow separation processes under harsh conditions. While zeolite NaA (LTA-type) is industrially used for dewatering of organic solvents, its pore size and thermal and hydrothermal stability can be tuned by exchange of framework and extra-framework elements. SOD with pores of only 0.28 nm is of great interest for $H_2$- und $H_2O$-separation and also can be tuned by ion exchange. Zeolites open the opportunity to create membranes of adapted separation behavior for small molecules in conditions of surrounding technical processes.

Wet Foam Stability from Colloidal Suspension to Porous Ceramics: A Review

  • Kim, Ik Jin;Park, Jung Gyu;Han, Young Han;Kim, Suk Young;Shackelford, James F.
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.211-232
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    • 2019
  • Porous ceramics are promising materials for a number of functional and structural applications that include thermal insulation, filters, bio-scaffolds for tissue engineering, and preforms for composite fabrication. These applications take advantage of the special characteristics of porous ceramics, such as low thermal mass, low thermal conductivity, high surface area, controlled permeability, and low density. In this review, we emphasize the direct foaming method, a simple and versatile approach that allows the fabrication of porous ceramics with tailored microstructure, along with distinctive properties. The wet foam stability is achieved under the controlled addition of amphiphiles to the colloidal suspension, which induce in situ hydrophobization, allowing the wet foam to resist coarsening and Ostwald ripening upon drying and sintering. Different components, like contact angle, adsorption free energy, air content, bubble size, and Laplace pressure, play vital roles in the stabilization of the particle stabilized wet foam to the porous ceramics. The mechanical behavior of the load-displacements curves of sintered samples was investigated using Herzian indentations testes. From the collected results, we found that microporous structures with pore sizes from 30 ㎛ to 570 ㎛ and the porosity within the range from 70% to 85%.

Traditional Foods: Historical Perspectives and Future Prospects (문화와 과학의 융합적 관점에서 본 전통음식의 역사 및 미래)

  • Kim, Hee Sup
    • Journal of the Korean Society of Food Culture
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    • v.30 no.1
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    • pp.1-7
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    • 2015
  • Traditional cuisine reflects cooking traditions shaped by political, economic, social, cultural, and environmental conditions characterized by authenticity and uniqueness. Traditional food is not only a part of our cultural heritage but also a knowledge resource. Application of food science and technology in Korean traditional foods was reviewed from six points of view, including food preservation, fermentation, changes in food materials, utilization of food functionality, and packaging and development of cooking appliances. Books from disparate times were chosen in order to cover a wide range of materials from the past to the present. Food preservation and fermentation techniques were applied to various food materials. Combination of science and skills contributes to the accessibility of diverse food materials and better quality foods. Koreans use assorted and resilient plants, which have an abundance of functional substances such as food materials. Among cooking appliances, microwave oven and refrigerator are the most innovative products with huge influences on food eating patterns as well as lifestyle. Packaging effectively reduces post-harvest preservation losses, and better packaging has technical improvements for storage and distribution. Kimchi was chosen as an example in order to study technology from the past to the present. Availability of Kimchi cabbage, enrichment of functional ingredients, identification of useful microbial species, standardization of recipe for commercialization, prevention of texture softening, introduction of salted Kimchi cabbage and Kimchi refrigerators, and packaging were reviewed. The future of traditional foods in the market will be competitive. First, traditional foods market should be maintained to protect the diversity of food materials. Secondly, tailored foods for individuals should be considered using foods with functional properties. Information on health benefits would provide insights into health and traditional food products. Third, speedy transfer of new technology to the traditional food industry is needed to ensure food quality production and new opportunities in the market. Fourth, safety of traditional foods should be ensured without sacrificing the essential characteristics of culturally important foods. Improvement of logistics, distribution, and facility should be carried out. As demand for convenience foods increases, traditional foods should be developed into products.

Radioisotope identification using sparse representation with dictionary learning approach for an environmental radiation monitoring system

  • Kim, Junhyeok;Lee, Daehee;Kim, Jinhwan;Kim, Giyoon;Hwang, Jisung;Kim, Wonku;Cho, Gyuseong
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.1037-1048
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    • 2022
  • A radioactive isotope identification algorithm is a prerequisite for a low-resolution scintillation detector applied to an unmanned radiation monitoring system. In this paper, a sparse representation with dictionary learning approach is proposed and applied to plastic gamma-ray spectra. Label-consistent K-SVD was used to learn a discriminative dictionary for the spectra corresponding to a mixture of four isotopes (133Ba, 22Na, 137Cs, and 60Co). A Monte Carlo simulation was employed to produce the simulated data as learning samples. Experimental measurement was conducted to obtain practical spectra. After determining the hyper parameters, two dictionaries tailored to the learning samples were tested by varying with the source position and the measurement time. They achieved average accuracies of 97.6% and 98.0% for all testing spectra. The average accuracy of each dictionary was above 96% for spectra measured over 2 s. They also showed acceptable performance when the spectra were artificially shifted. Thus, the proposed method could be useful for identifying radioisotopes in gamma-ray spectra from a plastic scintillation detector even when a dictionary is adapted to only simulated data. Furthermore, owing to the outstanding properties of sparse representation, the proposed approach can easily be built into an insitu monitoring system.

Combinatorial Experiment for Al-6061 and Al-12Si alloy Based on Directed Energy Deposition (DED) Process (3차원 적층 제조 공정(DED) 기반 Al-6061+Al-12Si 합금 조합 실험)

  • Seoyeon Jeon;Suwon Park;Yongwook Song;Jiwon Park;Hyunyoung Park;Boram Lee;Hyunjoo Choi
    • Journal of Powder Materials
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    • v.30 no.6
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    • pp.463-469
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    • 2023
  • Aluminum alloys, known for their high strength-to-weight ratios and impressive electrical and thermal conductivities, are extensively used in numerous engineering sectors, such as aerospace, automotive, and construction. Recently, significant efforts have been made to develop novel aluminum alloys specifically tailored for additive manufacturing. These new alloys aim to provide an optimal balance between mechanical properties and thermal/electrical conductivities. In this study, nine combinatorial samples with various alloy compositions were fabricated using direct energy deposition (DED) additive manufacturing by adjusting the feeding speeds of Al6061 alloy and Al-12Si alloy powders. The effects of the alloying elements on the microstructure, electrical conductivity, and hardness were investigated. Generally, as the Si and Cu contents decreased, electrical conductivity increased and hardness decreased, exhibiting trade-off characteristics. However, electrical conductivity and hardness showed an optimal combination when the Si content was adjusted to below 4.5 wt%, which can sufficiently suppress the grain boundary segregation of the α-Si precipitates, and the Cu content was controlled to induce the formation of Al2Cu precipitates.

Synthesis Methods of Silver Sulfide for SWIR Region Applications (SWIR 영역에서 활용 가능한 Silver Sulfide의 다양한 합성법)

  • Yunhye Jeong;Gi-Hwan Kim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.374-381
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    • 2024
  • This paper delves into the application of the short-wave infrared (SWIR) region, with a focus on the synthesis and optical characteristics of silver sulfide (Ag2S) nanostructures. SWIR offers advantages such as reduced damage to biological tissues and enhanced optical transparency, making it valuable across various domains. The study introduces three distinct synthesis methods, each showcasing the ability to obtain nanostructures with improved optical properties. These research findings open up the possibility of providing tailored solutions in detection, imaging, and other applications by controlling the size and ligands of Ag2S nanoparticles. This paper provides new insights into the utilization of Ag2S in the SWIR region, which is expected to foster advancements in future technologies.

Proteome-wide Characterization and Pathophysiology Correlation in Non-ischemic Cardiomyopathies

  • Seonhwa Lee;Dong-Gi Jang;Yeon Ju Kyoung;Jeesoo Kim;Eui-Soon Kim;Ilseon Hwang;Jong-Chan Youn;Jong-Seo Kim;In-Cheol Kim
    • Korean Circulation Journal
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    • v.54 no.8
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    • pp.468-481
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    • 2024
  • Background and Objectives: Although the clinical consequences of advanced heart failure (HF) may be similar across different etiologies of cardiomyopathies, their proteomic expression may show substantial differences in relation to underlying pathophysiology. We aimed to identify myocardial tissue-based proteomic characteristics and the underlying molecular pathophysiology in non-ischemic cardiomyopathy with different etiologies. Methods: Comparative extensive proteomic analysis of the myocardium was performed in nine patients with biopsy-proven non-ischemic cardiomyopathies (3 dilated cardiomyopathy [DCM], 2 hypertrophic cardiomyopathy [HCM], and 4 myocarditis) as well as five controls using tandem mass tags combined with liquid chromatography-mass spectrometry. Differential protein expression analysis, Gene Ontology (GO) analysis, and Ingenuity Pathway Analysis (IPA) were performed to identify proteomic differences and molecular mechanisms in each cardiomyopathy type compared to the control. Proteomic characteristics were further evaluated in accordance with clinical and pathological findings. Results: The principal component analysis score plot showed that the controls, DCM, and HCM clustered well. However, myocarditis samples exhibited scattered distribution. IPA revealed the downregulation of oxidative phosphorylation and upregulation of the sirtuin signaling pathway in both DCM and HCM. Various inflammatory pathways were upregulated in myocarditis with the downregulation of Rho GDP dissociation inhibitors. The molecular pathophysiology identified by extensive proteomic analysis represented the clinical and pathological properties of each cardiomyopathy with abundant proteomes. Conclusions: Different etiologies of non-ischemic cardiomyopathies in advanced HF exhibit distinct proteomic expression despite shared pathologic findings. The benefit of tailored management strategies considering the different proteomic expressions in non-ischemic advanced HF requires further investigation.

A Comparison of Cooking Quality on Commercial Eco-Friendly Functional Rice (시판 친환경재배 건강기능성 쌀의 취반 가공적성 비교)

  • Kim, Joo-Hee;Moon, Jung-Eun;Kang, Mi-Young;Lee, Sang-Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.4
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    • pp.451-458
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    • 2013
  • The physicochemical properties and cooking qualities of four rice varieties (Goami, Giant-embryonic rice, Baegjinju, Aranghyangchal) which grown under ecofriendly farming as development of material for chronic disease tailored instant rice and porridge, respectively, were investigated. The contents of crude protein, crude lipid and crude fiber were the highest in Goami. The water absorption rate of Aranghyangchal at $85^{\circ}C$ was higher than other rice. However on rice flour, the water absorption rate and solubility of all functional rices at $85^{\circ}C$ were higher than control (brown rice flour). In addition viscosity of all functional rices at $100^{\circ}C$ were higher than control (brown rice flour). In spite of brown rice, Aranhyangchal showed no significant differences about hardness of Ilpum (white rice). The sensory evaluation was shown that Aranghyangchal was the highest in glossiness, flavor, roasted nutty taste, cohesiveness and overall preference. Although Giant-embryonic rice and Baegjinju were brown rice, overall preference was higher than Ilpum (white rice). These study results were showed that the functional rices could be good to make instant rice.