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Transport and optical properties of indium tin oxide films fabricated by reactive magnetron sputtering (제작 온도 및 산소 분압에 의존하는 인듐 주석 산화물의 전기적, 광학적 성질)

  • 황석민;주홍렬;박장우
    • Korean Journal of Optics and Photonics
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    • v.14 no.3
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    • pp.343-348
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    • 2003
  • Indium tin oxide (ITO) thin films (170 nm) were grown by DC magnetron sputtering deposition on Coming glass substrates without a post annealing. The electrical transport and optical properties of the films have been investigated as a function of deposition temperature $T_{s}$ (10$0^{\circ}C$$\leq$ $T_{s}$$\leq$35$0^{\circ}C$) and oxygen partial pressure $P_{o_{2}}$, (0 $P_{o_{2}}$ $\leq$ 10$^{-5}$ torr). Films were deposited from a high density (99% of theoretical density) ITO target (I $n_2$ $O_3$: Sn $O_2$= 90 wt% : 10 wt%) made of ITO nano powders. With an increase of $T_{s}$ the electrical resistivity p of ITO thin films was found to decrease, but the mobility $\mu$$_{H}$ was found to increase. The carrier density nu shows the maximum value of 6.6$\times$10$^{20}$ /㎤ at $T_{s}$ = 30$0^{\circ}C$. At fixed Is, with an increase of the oxygen partial pressure, $n_{H}$ and $\mu$$_{H}$ were found to decrease, but p was found to increase. The minimum resistivity and maximum mobility values of the ITO films were found to be 0.3 mΩ.cm and 39.3 $\textrm{cm}^2$/V.s, respectively. The visible transmittance of the ITO films was above 80%.. 80%..

Growth Response and Arsenic Uptake of White Clover (Trifolium repens) and Evening Primrose(Oenothera odorata) Colonized with Arbuscular Mycorrhizal Fungi in Arsenic-Contaminated Soil

  • Kim, Dae-Yeon;Lee, Yun-Jeong;Lee, Jong-Keun;Koo, Na-Min;Kim, Jeong-Gyu
    • Korean Journal of Environmental Agriculture
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    • v.27 no.1
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    • pp.50-59
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    • 2008
  • A greenhouse experiment was conducted to investigate the role of the arbuscular mycorrhizal(AM) fungus, Glomus mosseae(BEG 107) in enhancing growth and arsenic(As) and phosphorus(P) uptake of white clover(Trifolium repens) and evening primrose(Oenothera odorata) in soil collected from a gold mine having concentrations of 381.6 mg total As $kg^{-1}$ and 20.5 mg available As $kg^{-1}$. Trifolium repens and O. odorata are widely distributed on abandoned metalliferous mines in Korea. The percent root colonization by the AM fungus was 55.9% and 62.3% in T. repens and O. odorata, respectively, whereas no root colonization was detected in control plants grown in a sterile medium. The shoot dry weight of T. repens and O. odorata was increased by 323 and 117% in the AM plants compared to non-mycorrhizal(NAM) plants, respectively. The root dry weight increased up to 24% in T. repens and 70% in O. odorata following AM colonization compared to control plants. Mycorrhizal colonization increased the accumulation of As in the root tissues of T. repens and O. odorata by 99.7 and 91.7% compared to the NAM plants, respectively. The total uptake of P following AM colonization increased by 50% in T. repens and 70% in O. odorata, whereas the P concentration was higher in NAM plants than in the AM plants. Colonization with AM fungi increased the As resistance of the host plants to As toxicity by augmenting the yield of dry matter and increasing the total P uptake. Hence, the application of an AM fungus can effectively improve the phytoremediation capability of T. repens and O. odorata in As-contaminated soil.

The Study on Chemical Durable Zinc-phosphate Glasses with $B_2$$O_3$Addition ($B_2$$O_3$첨가에 따른 Zinc Phosphate Glasses의 화학적 안정화)

  • 류봉기;이병철;이성욱;황차원;이종성
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.593-595
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    • 2001
  • Zinc-phosphate glasses에 B$_2$O$_3$를 도입하여 borate, phosphate, boro-phosphate networks가 혼재되어 있는 highly cross-linked structures를 형성시켜 Phosphate glasses의 화학적 안정화를 검토하였다. Raman 측정 결과 B$_2$O$_3$와 P$_2$O$_{5}$는 잘 혼화된 polynary networks를 이루고 있으며, 이렇게 하여 증진된 구조적 cross-linking에 의하여 xB$_2$O$_3$.(1-x)Zn$_2$P$_2$O$_{7}$ glasses의 T$_{g}$, T$_{d}$는 증가하였고 동시에 CTE는 감소하는 결과를 가져왔다.

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Synthesis and Hardness of Glass Ceramics for Dental Crown Prosthetic Application in the system CaO-MgO-SiO2-P2O5-TiO2 (치관 보철용 CaO-MgO-$SiO_2-P_2O_5-TiO_2$계 글라스 세라믹의 합성과 경도)

  • Chung, In-Sung;Kim, Kap-Jin;Cheong, HO-Keun;Lee, Jong-Il
    • Journal of Technologic Dentistry
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    • v.21 no.1
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    • pp.5-14
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    • 1999
  • Glass ceramics for dental crown prosthesis were prepared by crystallization of CaO-MgO-SiO2-$P_2O_5-TiO_2$ glasses. Their crystallization behaviors have been investigated as a function of heattreatment temperature, holding time and chemical composition in relation to mechinical properties. Crystallization peak temperatures were determined by differential thermal analysis(DTA). Crystalline phases and mircostructures of heat-treated sample were determined by the means of powder X-ray diffraction(XRD) and scanning electron microscopy(SEM). The final crystalline phase assemblages and the microstructures of the samples were found to be dependent on glass compositions, heattreatment temperature, and holding time. 1st crystallization peak temperature(TP), affected strongly by apatite, was found to be increased or decreased. From the experiment, the following results were obtained : 1. The crystallization peak temperature($T_P$) formed by apatite increased until adding up to 9wt% $TiO_2$ to base glass composition, then decreased above that. 2. Apatite($Ca_{10}P_6O_{25}$), whitlockite(${\beta}-3CaO-P_2O_5$), $\beta$-wollastonite($CaSiO_3$), magnesium tianate($MaTiO_3$) and diopside(CaO-MgO-$2SiO_2$) crystal phase were precipitated in MgO-CaO-$SiO_2-TiO_2-P_2O_5$ glass system containing 9wt% and 11wt% of $TiO_2$ 3. Vickers hardness of samples increased with increasing heat-treatment temperature and Vickers hardness of S415T9 samples heat-treated at 1075 was approxi-mately 813Kg $mm^{-2}$ as maximum value. 4. Vickers hardness of samples increased due to precipitation of apatite, whitlockite, $\beta$-wollastonite, magnesium titanate, and diopside crystal phases within glass matrix.

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Phytosociological Studies on the Beech(Fagus multinervis Nakai) Forest and the Pine (Pinus parviflora S. et Z.) Forest of Ulreung Island, Korea (한국 울릉도의 너도밤나무(Fagus multinervis Nakai)림 및 섬잣나무(Pinus parviflora S. et Z.)림의 식물사회학적 연구)

  • 김성덕
    • Journal of Plant Biology
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    • v.29 no.1
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    • pp.53-65
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    • 1986
  • The montane forests of Ulreung Island, Korea, were investigated by the ZM school method. By comparing the montane forests of this island with those of Korean Peninsula and of Japan, a new order, F a g e t a l i a m u l t i n e r v i s, a new alliance, F a l g i o n m u l t i n e r v i s, a new association, H e p a t i c o-F a g e t u m m u l t i n e r v i s and Rhododendron brachycarpum-Pinus parviflora community were recognized. The H e p a t i c o - F a g e t u m m u l t i n e r v i s was further subdivided into four subassociations; Subass. of Sasa kurilensis, Subass. of Rumohra standishii, Subass. of Rhododendron brachycarpum and Subass. of typicum. Each community was described in terms of floristic, structural and environmental features.

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Theoretical Investigation for the Structures and Binding Energies of H2O3 and Water (H2O) Clusters (H2O3과 물(H2O) 클러스터들의 분자구조와 열역학적 안정성에 대한 이론적 연구)

  • Seo, Hyun-il;Kim, Jong-Min;Song, Hui-Sung;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.61 no.6
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    • pp.328-338
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    • 2017
  • The density functional theory(DFT) and ab initio calculations have been applied to investigate hydrogen interaction of $H_2O_3(H_2O)_n$ clusters(n=1-5). The structures, IR spectra, and H-bonding energies are calculated at various levels of theory. The $trans-H_2O_3$ monomer is predicted to be thermodynamically more stable than cis form at the CCSD(T)/cc-pVTZ level of theory. For clusters, the geometries are optimized at the MP2/cc-pVTZ level of theory. The binding energy of $H_2O_3-H_2O$ cluster is predicted to be -6.39 kcal/mol at the CCSD(T)//MP2/cc-pVTZ level of theory after zero-point vibrational energy (ZPVE) and basis set superposition error (BSSE) correction. This result implies that $H_2O_3$ is a stronger proton donor(acid) than either $H_2O$ or $H_2O_2$. The average binding energies per $H_2O$ are predicted to be 8.25 kcal/mol for n=2, 7.22 kcal/mol for n=3, 8.50 kcal/mol for n=4, and 8.16 kcal/mol for n=5.

Study on Phosphorus Removal in the Secondary Effluent by Flotation Using Microbubble Liquid Film System (미세기포 액막화 부상법을 이용한 하수 2차 처리수의 인 제거에 관한 연구)

  • Lee, Shun-Hwa;Kang, Hyun-Woo;Lee, Se-Han;Kwon, Jin-Ha;Jung, Kye-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.1
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    • pp.42-48
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    • 2012
  • In this study, experiment on phosphorus removal was performed by using microbubble liquid film flotation tank with microbubble module. After dissolving gas and liquid in dissolving tank, microbubble liquid film system created microbubbles in equal size under fixed low pressure. After being passed through $A_2O$ and m-$O_3$ process, secondary treatment wastewater was used as influent in phosphorus removal process. When the T-P concentration of influent was 2.89 mg/L, alum(8%, 30 mg/L) was injected into a microbubble flotation tank, the treatment resulted 94% of T-P removal rate. Remaining T-P concentration was less than 0.2 mg/L, which is in accord with the effluent quality standard. Seasonal variations in water temperature showed no differences in T-P removal property. When the inflow concentration of SS was 1.0 mg/L or more, it served as coagulation nuclei in the coagulation process. In that condition, average T-P removal rate was higher than 97%. When 50% of floated scum was returned, coagulator Al included in scum assisted the injected coagulator and maximized the coagulation efficiency of pollutant. In such treatment, the T-P concentration was measured as 0.18 mg/L and satisfied the outflow water quality standard, which is 0.2 mg/L or less.

(1) Studies on the Determination of the Rate Control Steps in the Various Metabolic Cycles (I) - The Affect of the Light to the Enzyme Activities in the Cotyledons of the Germinating Seeds - (대사과정(代謝過程)에 있어서 율속단계(律速段階) 결정(決定)에 관(關)한 연구(硏究) (I) - 발아종자자엽(發芽種子子葉)에 있어서 산소활성(酸素活性)에 미치는 광선(光線)의 영향(影響) -)

  • Sin, Gwi-Nam
    • Applied Biological Chemistry
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    • v.3
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    • pp.1-7
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    • 1962
  • In order to study the rate control step in the protein metabolic course of the chlorophyll formation, the transaminase activities which are obtained freely in the extracts of cotyledons of germinating peas at the light and the dark places, are measured in Beckman mopel D.U, spectrophoto meter at 490 mu. In this case, of two enzymatic reaction products; oxalacetic acid and pyruvic acid, the former is converted to pyruvic acid by aniline citrate and after each pyruvate phenyl hydrazones are extracted by toluenes: when this is treated with strong alcoholic alkali, a colored hydrazone is formed and it is measured by above apparatus. The estimated G.O.T. and G.P.T. in the germinated cotyledons at dark and light places considerably differ in their activities; G.O.T. and G.P.T. activities which are formed at the light are more increased than at the dark and also they differ in their rates through germination, though G.O.T. activity increment is smoothly but that of G.P.T. is more sharply, and they are considered to be directly affected to the chlorophyll formation and indirectly to the growth. G.O.T. and G.P.T. in each fractions of cell in the cotyledons should be formed by dissociation of zymogens in the microsomal fractions and it seems to promoted by light. In the formation of the chlorophyll, the protein metabolism occurred mainly in the microsomal fractions and the rate determining step is found at the point where the zymogene that is able to produce G.P.T. is activated, and this activation is promoted by light as noted above.

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The Study of the Dielectric and Piezoeletric Properties of 0.05Pb(AlS12/3TWS11/3T)OS13T-0.95Pb(ZrS10.52TTiS10.48T)OS13T System Modified with MnOS12T and FeS12TOS13T (MnO2, Fe2O3 첨가에 따른 0.05Pb(Al2/3W1/3)O3-0.95Pb(Zr0.52Ti0.48)O3계의 유전 및 압전 특성에 관한 연구)

  • 윤석진;오현재;정형진
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.5
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    • pp.508-516
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    • 1992
  • In this study, dielectric and piezoelectric properties of 0.05Pb(AlS12/3TWS11/3T)OS13T-0.95Pb(ZrS10.52TTiS10.48T)OS13T system ceramics were investigated with respect to the variations of MnOS12T and FeS12TOS13T additions amounts. The results obtained in this study are summarized as follows: 1. As the amounts of MnOS12T and FeS12TOS13T are increased, tetragonality(c/a) and apparent density were decreased but grain size was increased, also the limits of solubility were revealed because pores were formed at the amounts of 0.3wt% MnOS12T and 0.5wt% FeS12TOS13T. 2. AS the increasing of amounts of MnOS12T and FeS12TOS13T, the temperature of phase transition(TS1cT) was decreased, and pemeability had maximum value at the amount of 0.3wt% MnOS12T but were sharply decreasd for the increasing FeS12TOS13T amounts. 3. As the amounts of MnOS12T and FeS12TOS13T are increased, the electro-mechanical coupling factor(kS1pT) was decreased from 60% to 41%, 19% respectively, but mechanical quality factor(QS1mT) had maximum values 720 for amount of 0.3wt% MnOS12T and 320 the amount of 0.5wt% FeS12TOS13T.

Crystallization and Electrical properties of $CuO-P_2O_5-V_2O_5$ Glass for solid state Electrolyte (고체 전해질용 $CuO-P_2O_5-V_2O_5$ 유리의 결정화와 전기 전도도)

  • Son, Myung-Mo;Lee, Heon-Soo;Chun, Yon-Soo;Gu, Hal-Bon;Lee, Sang-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.934-937
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    • 2003
  • Glasses in the system $CuO-P_2O_5-V_2O_5$ were prepared by a press-quenching method on the copper plate. The glass-ceramics from these glasses were obtained by post-heat treatment, and the crystallization behavior and DC conductivities were determined. The conductivities of the glasses were range from $10^{-6}s.Cm^{-1}$ at room temperature, but the conductivities of the glass-ceramics were $10^{-3}s.Cm^{-1}$ increased by $10^3$ order. The crystalline product in the glass-ceramics was $CuV_2O_6$. Heat-treatment conditions influenced the crystal growth of $CuV_2O_6$ and conductivity. The linear relationship between in (${\sigma}T$) and $T^{-1}$ suggested that the electrical conduction in the present glass-ceramics would be due to a small polaron hopping(SPH) mechanism.

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