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Study on Phosphorus Removal in the Secondary Effluent by Flotation Using Microbubble Liquid Film System

미세기포 액막화 부상법을 이용한 하수 2차 처리수의 인 제거에 관한 연구

  • Lee, Shun-Hwa (Department of Environmental Engineering, Yeungnam University) ;
  • Kang, Hyun-Woo (Department of Environmental Engineering, Yeungnam University) ;
  • Lee, Se-Han (Department of Environmental Engineering, Yeungnam University) ;
  • Kwon, Jin-Ha (Department of Environmental Engineering, Yeungnam University) ;
  • Jung, Kye-Joo (Department of Environmental Engineering, Yeungnam University)
  • Received : 2011.08.17
  • Accepted : 2012.01.20
  • Published : 2012.01.31

Abstract

In this study, experiment on phosphorus removal was performed by using microbubble liquid film flotation tank with microbubble module. After dissolving gas and liquid in dissolving tank, microbubble liquid film system created microbubbles in equal size under fixed low pressure. After being passed through $A_2O$ and m-$O_3$ process, secondary treatment wastewater was used as influent in phosphorus removal process. When the T-P concentration of influent was 2.89 mg/L, alum(8%, 30 mg/L) was injected into a microbubble flotation tank, the treatment resulted 94% of T-P removal rate. Remaining T-P concentration was less than 0.2 mg/L, which is in accord with the effluent quality standard. Seasonal variations in water temperature showed no differences in T-P removal property. When the inflow concentration of SS was 1.0 mg/L or more, it served as coagulation nuclei in the coagulation process. In that condition, average T-P removal rate was higher than 97%. When 50% of floated scum was returned, coagulator Al included in scum assisted the injected coagulator and maximized the coagulation efficiency of pollutant. In such treatment, the T-P concentration was measured as 0.18 mg/L and satisfied the outflow water quality standard, which is 0.2 mg/L or less.

본 연구에서는 미세기포 액막화 부상조를 이용하여 인 제거에 관한 연구를 실시하였다. 미세기포 액막화 부상조는 기체용해탱크를 이용하여 부상 전 기 액을 충분히 용해시킨 후 일정한 저 압력으로 동일한 미세기포를 생성하도록 하는 방법을 사용하였다. $A_2O$ 공정과 m-$O_3$(미세기포 생성장치와 오존용해탱크가 결합된 공정)복합공정을 거친 2차 유출수를 인 제거 공정의 유입수로 사용하였으며, 원수의 T-P 농도가 2.89 mg/L일 때, 8%의 Alum을 30 mg/L의 농도로 주입하였을 경우 T-P 제거율이 94%를 나타내었고, T-P의 방류수수질기준인 0.2 mg/L 이하를 만족시키는 것으로 조사되었으며, 계절에 따른 수온 변화는 T-P 제거 특성에 영향을 주지 않았다. SS의 유입농도가 1.0 mg/L 이상일 시 SS가 응집공정 내의 seed 역할을 하여 평균 T-P의 제거율이 97% 이상 되는 것으로 조사되었고, 부상스컴을 50% 반송할 경우, 부상스컴 내에 포함되어 있는 응집제 성분 Al이 주입되는 응집제의 역할을 보조하여 오염물질의 응집효율을 극대화 시키는 것으로 조사되었다. 이러한 조건에서 T-P의 방류수 수질기준 0.2 mg/L 이하를 만족하는 0.18 mg/L의 농도를 나타내는 것으로 조사되었다.

Keywords

References

  1. Mervat, E. and Logan, A. W., "Removal of phosphorous from secondary effluent by a matrix filter," Desalination, 106, 247-253(1996) https://doi.org/10.1016/S0011-9164(96)00115-4
  2. 법제처, [별표 1] 공공하수처리시설의 방류수수질기준(제3조제1항제1호 관련)(2010)
  3. (주)태영건설, (주) 태영엔텍 "액막화 기체용해기술 및 마이크로버블 부상분리 시스템을 이용한 고도 인 제거 기술 신기술 인증 신청서"(2010)
  4. Grady, C. P. L, Jr, G. T. Daigger, and H. C. Lim, "Biological Wastewater Treatment, 2d ed., rev. and expanded, Marrcel Dekker, New York(1999)
  5. 이순화, 정계주, 권진하, 이세한, "잉여슬러지 가용화를 위한 마이크로버블 오존 이용에 관한 연구," 대한환경공학회지, 32(4), 325-332(2010)
  6. 환경부, "하수슬러지 처리시설 실태조사 및 기술지원 계획" (2006)
  7. 환경부, "하수슬러지관리 기본계획"(2006)
  8. 환경부, 런던협약 '96의정서 발효에 따른 하수슬러지관리 종합대책(2007. 5)
  9. Muller, J. A. "Pretreatment processes for the recycling and reuse of sewage sludge," Water Sci. Technol., 42(9), 167-174(2000)
  10. H. Yasui et al., "A Full-Scale Operation of a Novel Activated Sludge Process Without Excess Sludge Production," Water Sci. Technol. 34(3-4), 395-404(1996) https://doi.org/10.1016/0273-1223(96)00604-X
  11. 김병훈, "미세기포와 응집제를 이용한 조류제어 연구" 강원대학교 석사학위논문(2000)
  12. R. W. Ward, and G. M. Degraeve, "Residual Toxicity of Several Disinfectants in Domestic Wastewater," J. WPCF, 50(46) (1978)
  13. Metcalf & Eddy, "Wastewater Engineering," Treatment, Disposal and Reuse(1991)
  14. 이승재, "환경정책저감에 관한 연구," 고려대학교 박사학위 논문(2010)
  15. 환경부, 하수도법 시행규칙, 환경부령 제363호(2010. 10. 26)
  16. 이경용, "총인 기준 강화에 따른 하수정책 방향," 첨단환경기술, 18(10), 2-7, 환경관리연구소, 서울(2010. 10)
  17. Yeoman, S., Stephenson, T., Lester, J. N. and Perry, R., "The removal of phosphorus during wastewater treatment: A review," Environ. Pollut., 49, 183-233(1988) https://doi.org/10.1016/0269-7491(88)90209-6
  18. Elisabeth G. and Roland G., "Phosphorus removal from wastewaters: Experimental and theoretical support for alternative mechanism," Water Res., 31(2), 328-338(1997) https://doi.org/10.1016/S0043-1354(96)00256-4
  19. Hus, P. H., "Interaction between aluminium and phosphate in aqueous solution," Adv. Chem. Ser., 73, 115-127(1968) https://doi.org/10.1021/ba-1968-0073.ch005
  20. Lijklema, L., "Interaction of orthphosphate with iron(III) and aluminium hydroxides," Environ. Sci. Technol., 14, 537-541 (1980) https://doi.org/10.1021/es60165a013
  21. H. Ratnaweera, J. Fettig, and H. Odegaard., "Particle and phosphate removal mechanism with prepolymerized coagulants," Chemical water and wastewater treatment II, Proceedings of the 5th Gothenburg symposium, Nice France, pp. 28-30(1992)

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