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Syntheses of Alternating Head-to Head Vinyl Copolymers and Vinyl Terpolymers via Ring-Opening Mechanism. Ring-Opening Polymerization of Substituted-3,4-dihydro-2H-pyrans

  • Lee, Ju-Yeon;Cho, I-Whan
    • Bulletin of the Korean Chemical Society
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    • v.8 no.2
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    • pp.96-101
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    • 1987
  • 2-Ethoxy-6-methoxy-5-cyano-3,4-dihydro-2H-pyran (1_a$), 2-n-butoxy-6-methoxy-5-cyano-3,4-dihydro-2H-pyr an (1b), 2-isobutoxy-6-methoxy-5-cyano-3,4-dihydro-2H-py ran ($1_c$), and 2-ethoxy-6-methoxy-3-methyl-5-cyano-3,4-dihydro -2H-pyran ($1_d$) were prepared by (4 + 2) cycloaddition reaction of methyl $\alpha$-cyanoacrylate with the corresponding alkyl vinyl ethers. Compounds $1_{a-d}$ were ring-open polymerized by cationic catalyst to obtain alternating head-to-head (H-H) copolymers. For comparison, head-to-tail (H-T) copolymer $3_a$ was also prepared by free radical copolymerization of the corresponding monomers. The H-H copolymer exhibited minor differences in its $1_H% NMR and IR spectra, but in the $^{13}C$ NMR spectra significant differences were observed between the H-H and H-T copolymers. Glass transition temperature ($T_g$) of H-H copolymer was higher than that of the H-T copolymer, but thermal decomposition temperature of the H-H copolymer was lower than that of the H-T copolymer. Compounds $1_a$, $a_b$, and $1_c$, copolymerized well with styrene by cationic catalyst, but compound 1d failed to copolymerize with styrene. All of the H-H and H-T copolymers were soluble in common solvents and the inherent viscosities were in the range 0.2-0.4 dl/g.

Surface Properties, Friction, Wear Behaviors of the HOVF Coating of T800 Powder and Tensile Bond Strength of the Coating on Ti64

  • Cho, T.Y.;Yoon, J.H.;Joo, Y.K.;Cho, J.Y.;Zhang, S.H.;Kang, J.H.;Chun, H.G.;Kwon, S.C.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.11-12
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    • 2008
  • Micron-sized Co-alloy T800 powder was coated on Inconel718 (IN718) using high velocity oxygen fuel (HVOF) thermal spraying by the optimal coating process (OCP) determined from the best surface hardness of 16 coatings prepared by Taguchi program. The surface hardness improved 140-160 % from 399 Hv of IN718 to 560-630 Hv by the coating. Porosity of the coating was 1.0-2.7 %, strongly depending on spray parameters. Both friction coefficients (FC) and wear traces (WT) of the coating were smaller than those of IN718 substrate at both $25^{\circ}C$ and $538^{\circ}C$. FC and WT of IN718 and coating decreased with increasing the surface temperature. Tensile bond strength (TBS) and fracture location (FL) of Ti64/T800 were 8,770 psi and near middle of T800 coating respectively. TBS and FL of Ti64/NiCr/T800 were 8,740 psi and near middle of T800 coating respectively. This showed that cohesion of T800 coating was 8,740-8,770 psi, and adhesion of T800 on Ti64 and NiCr was stronger than the cohesion of T800.

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CHARACTERIZATIONS OF STABILITY OF ABSTRACT DYNAMIC EQUATIONS ON TIME SCALES

  • Hamza, Alaa E.;Oraby, Karima M.
    • Communications of the Korean Mathematical Society
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    • v.34 no.1
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    • pp.185-202
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    • 2019
  • In this paper, we investigate many types of stability, like (uniform stability, exponential stability and h-stability) of the first order dynamic equations of the form $$\{u^{\Delta}(t)=Au(t)+f(t),\;\;t{\in}{\mathbb{T}},\;t>t_0\\u(t_0)=x{\in}D(A),$$ and $$\{u^{\Delta}(t)=Au(t)+f(t,u),\;\;t{\in}{\mathbb{T}},\;t>t_0\\u(t_0)=x{\in}D(A),$$ in terms of the stability of the homogeneous equation $$\{u^{\Delta}(t)=Au(t),\;\;t{\in}{\mathbb{T}},\;t>t_0\\u(t_0)=x{\in}D(A),$$ where f is rd-continuous in $t{\in}{\mathbb{T}}$ and with values in a Banach space X, with f(t, 0) = 0, and A is the generator of a $C_0$-semigroup $\{T(t):t{\in}{\mathbb{T}}\}{\subset}L(X)$, the space of all bounded linear operators from X into itself. Here D(A) is the domain of A and ${\mathbb{T}}{\subseteq}{\mathbb{R}}^{{\geq}0}$ is a time scale which is an additive semigroup with property that $a-b{\in}{\mathbb{T}}$ for any $a,b{\in}{\mathbb{T}}$ such that a > b. Finally, we give illustrative examples.

Superconductivity recovery of vacuum annealed HTS GdBCO CC

  • You, Jong Su;Yang, Jeong Hun;Song, Kyu Jeong
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.3
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    • pp.41-46
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    • 2022
  • The superconducting properties of high temperature superconducting (HTS) GdBCO coated conductor (CC) tape (Ag/GdBCO/Buffer-layers/Stainless Steel) were investigated, specifically a series of samples prepared by vacuum heat treatment (200℃ to 600℃), using a Quantum Design PPMS-14. The critical current density Jc value was obtained by applying the modified Bean model to the irreversible magnetization ∆Mirr(H) data which was estimated from the magnetization M(H) loop. The reduction rates of lnJc and Tc values according to the increase of the vacuum annealing temperature Tan were d(lnJc)/dTan = - 0.016 A/(cm2∙℃) and dTc/dTan = - 0.24, respectively. We examined the effect of recovery temperature Tre (475℃ to 700℃) and recovery duration time t (0.5 h to 24 h) on the restoration of previously completely lost superconductivity in samples that subsequently received heat treatment in an O2 gas flow space. All samples were fully restored to superconductivity by heat treatment in an O2 gas flow space. The recovery temperatures Tre (475℃ to 700℃) and recovery duration times t (0.5 h to 24 h) were both independent of the superconductivity recovery characteristics.

HYPERCYCLICITY ON INVARIANT SUBSPACES

  • Petersson, Henrik
    • Journal of the Korean Mathematical Society
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    • v.45 no.4
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    • pp.903-921
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    • 2008
  • A continuous linear operator $T\;:\;X{\rightarrow}X$ is called hypercyclic if there exists an $x\;{\in}\;X$ such that the orbit ${T^nx}_{n{\geq}0}$ is dense. We consider the problem: given an operator $T\;:\;X{\rightarrow}X$, hypercyclic or not, is the restriction $T|y$ to some closed invariant subspace $y{\subset}X$ hypercyclic? In particular, it is well-known that any non-constant partial differential operator p(D) on $H({\mathbb{C}}^d)$ (entire functions) is hypercyclic. Now, if q(D) is another such operator, p(D) maps ker q(D) invariantly (by commutativity), and we obtain a necessary and sufficient condition on p and q in order that the restriction p(D) : ker q(D) $\rightarrow$ ker q(D) is hypercyclic. We also study hypercyclicity for other types of operators on subspaces of $H({\mathbb{C}}^d)$.

A Study on pH and Soluble Reactive Phosphorus (SRP) from Litter Using Various Poultry Litter Amendments During Short-Term: A Laboratory Experiment (다양한 깔짚 첨가제 이용이 단 기간 깔짚내 pH와 수용성 인에 미치는 영향에 관한 연구)

  • Choi, In-Hag;Yi, Seong-Joon;Kim, Chang-Mann
    • Journal of Environmental Science International
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    • v.17 no.2
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    • pp.233-237
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    • 2008
  • The objective of this study was conducted to evaluate the effects of poultry litter amendments on pH and soluble reactive phosphorus (SRP) in poultry litter. Two laboratory studies were conducted for 42 d in Exp. 1 and for 10 d in Exp. 2, respectively. The poultry litter was treated with various amendments which included 4 g fly ash and 4 g $AlCl_3\;(AlCl_36H_2O)/100g$ litter in Exp. 1 and 4 g alum$(Al_2(SO_4){_3}\;14H_2O)$, 8 g alum, 8.66 g liquid alum, and 17.3 g liquid alum/100 g litter in Exp. 2; untreated litter served as controls. There were no differences in pH between control and T1(4 g fly ash) and SRP contents between T1(4 g fly ash) and T2(4 g $AlCl_3$) in Exp. 1. A significant difference in pH and SRP contents in Exp. 2 was observed among all treatments(P< 0.05). In experiment 1, T1(4 g fly ash) and T2(4 g $AlCl_3$) at 42 d decreased SRP in litter by 47.1% and 62.6% of that from litter alone, respectively. In experiment 2, T1(4 g alum), T2(8.66 g liquid alum), T3(8 g alum), and T4(17.3 g liquid alum) treatments at 10 days reduced SRP contents by up to 36.2%, 62.9%, 87.0%, and 83.9%, respectively, when compared with the controls. Decrease in SRP contents was chiefly associated with reduction in litter pH. These results indicate that use of various litter amendments to limit P solubility has potential and should be pursued as a means of reducing soluble reative phosphorus during short term.

WEYL@S THEOREMS FOR POSINORMAL OPERATORS

  • DUGGAL BHAGWATI PRASHAD;KUBRUSLY CARLOS
    • Journal of the Korean Mathematical Society
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    • v.42 no.3
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    • pp.529-541
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    • 2005
  • An operator T belonging to the algebra B(H) of bounded linear transformations on a Hilbert H into itself is said to be posinormal if there exists a positive operator $P{\in}B(H)$ such that $TT^*\;=\;T^*PT$. A posinormal operator T is said to be conditionally totally posinormal (resp., totally posinormal), shortened to $T{\in}CTP(resp.,\;T{\in}TP)$, if to each complex number, $\lambda$ there corresponds a positive operator $P_\lambda$ such that $|(T-{\lambda}I)^{\ast}|^{2}\;=\;|P_{\lambda}^{\frac{1}{2}}(T-{\lambda}I)|^{2}$ (resp., if there exists a positive operator P such that $|(T-{\lambda}I)^{\ast}|^{2}\;=\;|P^{\frac{1}{2}}(T-{\lambda}I)|^{2}\;for\;all\;\lambda)$. This paper proves Weyl's theorem type results for TP and CTP operators. If $A\;{\in}\;TP$, if $B^*\;{\in}\;CTP$ is isoloid and if $d_{AB}\;{\in}\;B(B(H))$ denotes either of the elementary operators $\delta_{AB}(X)\;=\;AX\;-\;XB\;and\;\Delta_{AB}(X)\;=\;AXB\;-\;X$, then it is proved that $d_{AB}$ satisfies Weyl's theorem and $d^{\ast}_{AB}\;satisfies\;\alpha-Weyl's$ theorem.

First-principles Calculations on Magnetism of 1H/1T Boundary in Monolayer MoS2 (제일원리계산에 의한 단층 MoS2의 1H/1T 경계 자성)

  • Jekal, Soyoung;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.26 no.3
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    • pp.71-75
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    • 2016
  • Monolayer $MoS_2$ is energetically most stable when it has a 1H phase, but 1H to 1T phase transition ($1H{\rightarrow}1T$) is easily realized by various ways. Even though magnetic moment is not observed during $1H{\rightarrow}1T$, $0.049{\mu}_B/MoS_2$ is obtained in local 1T phase; 75% 2H and 25% 1T phases are mixed in ($2{\times}2$) supercell. Most magnetic moment is originated from the 1T phase Mo atom in the supercell, while the magnetic moments of other atoms are negligible. As a result, magnetic/non-magnetic boundary is created in the monolayered $MoS_2$. Our result suggests that $MoS_2$ can be applied for spintronics such as a spin transistor.

Effect of Feeding-Induced Molting on the Performance and Egg Quality in Laying Hens (급이에 의한 강제 환우 방법이 산란계의 생산성과 계란 품질에 미치는 영향)

  • Na, J.C.;Yu, D.J.;Bang, H.T.;Kim, S.H.;Kim, J.H.;Kang, G.H.;Kim, H.K.;Park, S.B.;Suh, O.S.;Jang, B.G.;Choi, J.T.;Choi, H.S.
    • Korean Journal of Poultry Science
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    • v.35 no.2
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    • pp.171-176
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    • 2008
  • Animal welfare advocates, claim that the induced molting by fasting be avoided. This study was conducted to evaluate the effect of molting induced by various feeding methods on productivity and egg quality in laying hens. We used 400 flocks of 60-week-old leghorn laying hens in four treatments(five replicates of 20 hens each): fasting method (C), feeding single corn grain diet (T1), feeding single wheat bran diet (T2) and feeding single alfalfa meal diet (T3). As the result of the experiment, egg production and daily egg mass significantly decreased only in T1 compared with the control during the $1{\sim}4th$ week after the secondary egg laying (P<0.05). Although the amount of feed intake was significantly less in T1 group during the $1{\sim}4th$ week compared to the control, no significant difference was detected during the total period (P>0.05). In addition, no significant difference of feed conversion was observed between treatment groups. In terms of egg quality, the egg shell thickness was significantly improved in T1 group than the control group by feeding only corn at the 10th and 14th week after the secondary egg laying (P<0.05), but the significant decrease was observed at the corn (T1) and wheat bran (T2) fed treatment groups than the control group at the 26th week of the experiment (P<0.05). The eggshell strength and haugh unit did not show any difference by the molting methods. Egg yolk color was significantly decreased in T1 and T2 group than the control group at the 6th week (P<0.05). However, T1 and T2 group resulted to show significantly high egg yolk color at the 18th week of the experiment (P<0.05). As the result of the experiment, no large difference was observed in the productivity by the feeding molting method and by the fasting induced molting method. In addition, the single diet fed feeding induced molting method by using alfalfa revealed to show more satisfactory trend than the corn or wheat bran single diet fed feeding induced molting methods even if no statistically significant difference was found in terms of egg productivity.

TRIIODTHYRONINE (T3) ENHANCES THE STIMULATORY EFFECT OF 1, 25-DIHYDROXYVITAMIN D3 ON CALBINDIN-D28k mRNA EXPRESSION IN THE KIDNEY AND INTESTINE BUT NOT IN CEREBELLUM OF THE CHICK

  • Sechman, A.;Shimada, K.;Saito, N.;Ieda, T.;Ono, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.1
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    • pp.37-44
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    • 1996
  • The present study was conducted to investigate the role of thyroid hormones in the regulation of gene expression of calbindin-$D_{28k}$ (CaBP-D28K) in the chicken. By employing slot blot and RIA analyses, levels of CABP-D28K mRNA and CaBP-D28K protein in the intestine, kidney, cerebellum and liver were measured 6 and 12 h after i.m. injection of 1, 25-dihydroxyvitamin $D_3$ [1, 25 $(OH)_2D_3$; 250 ng/chick] and 3, 5, 3'-triiodothyronine ($T_3$; 500 ng/chick) in one-day-old chicks. The abundant messages of CaBP-D28K mRNA were detected in the intestine, kidney and cerebellum while there was little message in the liver. After 1, 25 $(OH)_2D_3$ treatment (6 + 12 hours), levels of CaBP-D28K mRNA increased in the intestine, but there was no change in the mRNA levels in the kidney and cerebellum. Although $T_3$ alone had no effect on CaBP-D28K mRNA levels, simultaneous administration of $T_3$ enhanced the 1, 25 $(OH)_2D_3$ effect of levels of CaBP-D28K mRNA in the intestine both 6 and 12 h post-treatment, and in the kidney 12 h post-treatment. At a protein level, co-treatment with 1, 25 $(OH)_2D_3$ and $T_3$ elicited a significant increase in CaBP-D28K expression in the intestine 12 h post-treatment, as compared to treatment with only 1, 25 $(OH)_2D_3$, whereas no differences were observed in the CaBP-D28K protein levels in the kidney and cerebellum. These results suggest that thyroid hormones may play a synergistic role with 1, 25 $(OH)_2D_3$ for CaBP-D28K gene expression in the intestine and kidney in chicks.