• 한국음향학회지
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• 제16권1호
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• pp.47-53
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• 1997

이 논문은 원거리회의 환경에서 음성신호와 같은 광대역 신호를 다룰 수 있는 마이크로폰 어레이의 빔패턴(beam pattern)을 형성하는 효과적인 방법에 대하여 서술한다. 어레이의 변수를 반복적으로 변화시킴으로써, 측면롭의 높이를 조정하여 일정한 수준의 측면롭을 형성하며, 갱신된 측면롭을 대수적으로 찾지 않고 수치적으로 찾는 접근방법을 제안하였다. 어레이 계수나 마이크로폰 간격을 어레이변수로 사용하였으며, 마이크로폰 어레이 가시범위에 공간적으로 균일하게 입력되는 방향성잡음 또는 배경잡음을 효과적으로 줄일 수 있는 Dolph-Chebyshev형태의 최적화패턴을 형성하였다. 어레이 계수보다 마이크로폰 간격을 변화시키는 것이 광대역신호를 더 효과적으로 다룰 수 있는 최적화 패턴을 제공하는 것이 판명되었다. 또한 방향조정(scanning)상황 하에서 측면롭에 강한(robust)패턴을 형성할 수 있는 방법을 제안하였으며, 컴퓨터 실험결과를 제시하였다.

• Membrane and Water Treatment
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• 제7권3호
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• pp.223-240
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• 2016

In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.

• 한국재료학회지
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• 제19권12호
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• pp.667-673
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• 2009

The electrocatalytic characteristics of oxygen reduction reaction of the $PtxM_{(1-x)}$ (M = Co, Cu, Ni) supported on multi-walled carbon nanotubes (MWNTs) have been evaluated in a Polymer Electrolyte Membrane Fuel Cell (PEMFC). The $Pt_xM_{(1-x)}$/MWNTs catalysts with a Pt : M atomic ratio of about 3 : 1 were synthesized and applied to the cathode of PEMFC. The crystalline structure and morphology images of the $Pt_xM_{(1-x)}$ particles were characterized by X-ray diffraction and transmission electron microscopy, respectively. The results showed that the crystalline structure of the Pt alloy particles in Pt/MWNTs and $Pt_xM_{(1-x)}$/MWNTs catalysts are seen as FCC, and synthesized $Pt_xM_{(1-x)}$ crystals have lattice parameters smaller than the pure Pt crystal. According to the electrochemical surface area (ESA) calculated with cyclic voltammetry analysis, $Pt_{0.77}Co_{0.23}$/MWNTs catalyst has higher ESA than the other catalysts. The evaluation of a unit cell test using Pt/MWNTs or $Pt_xM_{(1-x)}$/MWNTs as the cathode catalysts demonstrated higher cell performance than did a commercial Pt/C catalyst. Among the MWNTs-supported Pt and $Pt_xM_{(1-x)}$ (M = Co, Cu, Ni) catalysts, the $Pt_{0.77}Co_{0.23}$/MWNTs shows the highest performance with the cathode catalyst of PEMFC because they had the largest ESA.

• 플랜트 저널
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• 제12권3호
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• pp.24-31
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• 2016

풍진동(Wind-induced vibration)은 바람에 의해 구조물에 진동이 발생하는 현상으로써 세장비가 큰 열기기 Stack 설계시 고려해야 할 중요한 사항이다. 따라서, 국제 규격에는 풍진동에 대한 설계 인자와 각 범위에 대해 필요한 고려 사항을 정의하고 있다. 규격에 의한 설계 검증은 몇몇 인자를 이용하여 간단하게 확인이 가능하다는 장점이 있는 반면, 실제 풍진동에 의한 영향을 정량적으로 평가하지 않기 때문에 실제 필요한 것보다 과도한 설계를 요구할 수 있다는 단점이 있다. 또한 여러 제약조건으로 Code 상의 요구조건을 만족하지 못하는 경우 실제 시스템의 거동을 예측할 수 없다는 단점이 있다. 이러한 점을 보완하기 위해 CFD 와 FEM 등의 수치적 해석 방법을 통해 풍진동이 실제 Stack에 미치는 영향을 해석하여 설계 적정성을 검증하여 Code 상의 요구 조건과 비교하였다.

• 한국통신학회논문지
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• 제30권2A호
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• pp.20-25
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• 2005

본 논문에서는 trace-back 동작 없이 디코딩이 가능한 변형된 레지스터 교환 (MRE) 방식을 블록 디코딩에 적용하여 전송 속도를 높이고 latency를 줄이는 비터비 디코딩 방식을 제안하였다. 변형된 레지스터 교환 방식을 블록 디코딩에 적용함으로써 디코딩 블록의 시작 상태를 결정하기 위해 필요한 동작 사이클을 줄여, 블록 디코딩을 사용하는 기존의 비터비 디코더보다 더 적은 latency를 가지게 되었다. 뿐만 아니라, 메모리를 더 효율적으로 사용할 수 있으면서 하드웨어의 구현에 있어서도 복잡도가 더 감소하게 된다. 또한 시작 상태를 결정하기 위해 필요한 trace-back 동작을 없애고 메모리를 줄여 이에 따른 전력 소모를 줄이는 저전력 동작이 가능하다. 제안된 방식은 같은 하드웨어 복잡도로도 메모리의 감소 또는 latency의 감소에 중점을 둔 설계가 가능하다. 또한, 몇 가지 디자인 파라미터를 변경하여 합성 단계에서 하드웨어 복잡도와 전송 속도를 Dade-off 할 수 있도록 스케일러블한 구조로 설계하였다.

• 방사성폐기물학회지
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• 제16권2호
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• pp.173-182
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• 2018

원자력 시설 내 방사능을 포함하는 물질의 제염을 위한 방법 중 거품제염은 2차폐기기물의 양을 저감시킬 수 있는 장점을 지니고 있다. 본 연구에서는 거품안정성을 증가시킬 수 있는 실리카 나노입자를 여러가지 조건을 달리하여 합성하였다. Cetyltrimethylammonium bromide(CTAB)는 거품제염제의 거품안정성에 많은 영향을 나타내었다. 이러한 거품안정성이 향상된 이유는 제염제 내에 공기와 용액간의 계면에서 실리카 나노입자와 계면활성제의 반응으로 생각된다. 또한, CTAB는 실리카나노입자의 분리특성에서도 우수한 성능을 나타냈었다. 실리카 나노입자 분리시, CTAB의 탄화수소기에 의한 소수성과 전하중성화에 의해서 실리카 나노입자의 응집현상을 향상시켰다.

• 한국전기전자재료학회논문지
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• 제33권6호
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• pp.483-489
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• 2020

BaTiO₃ powder was synthesized by a solid-state reaction using BaCO₃ and TiO₂. Different calcination temperatures (800℃, 850℃, 900℃, and 950℃) were set to investigate their effects on the properties of BaTiO₃ powder. The synthesized BaTiO₃ phase was confirmed to be a single phase by XRD, and the tetragonality (c/a) and crystallite size were calculated. Thereafter, each calcinated BaTiO₃ was sintered at five different sintering temperatures (1,100℃, 1,150℃, 1,200℃, 1,250℃, and 1,300℃), and the tetragonality, density, porosity, dielectric constant, and grain size were measured. As the calcination temperature increased, the tetragonality and crystallite size also increased, to 1.008 and 66 nm, respectively, at 950℃. Moreover, most pellets showed increased density, dielectric constant, and tetragonality as the sintering temperature increased up to 1,250℃; the same parameters slightly decreased at 1,300℃. It is noteworthy that the tetragonality of BaTiO₃ at 1,250℃ exhibits a very high c/a value of 1.0084. In addition, the grain size and dielectric constant measured near the Curie temperature increased as the sintering temperature increased.

• 한국재료학회지
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• 제30권7호
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• pp.376-382
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• 2020

CeO₂ nanoparticles, employed in a lot of fields due to their excellent oxidation and reduction properties, are synthesized through a solvothermal process, and a high specific surface area is shown by controlling, among various process parameters in the solvothermal process, the type of solvent. The synthesized CeO₂ nanoparticles are about 11~13 nm in the crystallite size and their specific surface area is about 65.38~84.65 ㎡/g, depending on the amount of ethanol contained in the solvent for the solvothermal process; all synthesized CeO₂ nanoparticles shows a fluorite structure. The dispersibility and microstructure of the synthesized CeO₂ nanoparticles are investigated according to the species of dispersant and the pH value of the solution; an improvement in dispersibility is shown with the addition of dispersants and control of the pH. Various dispersing properties appear according to the dispersant species and pH in the solution with the synthesized CeO₂ nanoparticles, indicating that improved dispersing properties in the synthesized CeO₂ nanoparticles can be secured by applying dispersant and pH control simultaneously.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.317.2-317.2
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• 2013

Ultrathin oxide encapsulated metal-oxide hybrid nanocatalysts have been fabricated by a soft chemical and facile route. First, SiO2 nanoparticles of 25~30 nm size have been synthesized by modified Stobber's method followed by amine functionalization. Metal nanoparticles (Ru, Rh, Pt) capped with polymer/citrate have been deposited on functionalized SiO2 and finally an ultrathin layer of TiO2 coated on surface which prevents sintering and provides high thermal stability while maximizing the metal-oxide interface for higher catalytic activity. TEM studies confirmed that 2.5 nm sized metal nanoparticles are well dispersed and distributed throughout the surface of 25 nm SiO2 nanoparticles with a 3-4 nm TiO2 ultrathin layer. The metal nanoparticles are still well exposed to outer surface, being enabled for surface characterization and catalytic activity. Even after calcination at $600^{\circ}C$, the structure and morphology of hybrid nanocatalysts remain intact confirm the high thermal stability. XPS spectra of hybrid nanocatalyst suggest the metallic states as well as their corresponding oxide states. The catalytic activity has been evaluated for high temperature CO oxidation reaction as well as photocatalytic H2 generation under solar simulation. The design of hybrid structure, high thermal stability, and better exposure of metal active sites are the key parameters for the high catalytic activity. The maximization of metal-TiO2 interface interaction has the great role in photocatalytic H2 production.

• 한국재료학회지
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• 제18권10호
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• pp.564-570
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• 2008

Nanostructured carbon materials have been found to have applications in fuel cell electrodes, field emitters, electronic devices, sensors and electromagnetic absorbers, etc. Especially, the CNF (carbon nanofiber) can be expected to play an important role in catalyst supporters for fuel cell electrodes and chemical reactions. In this study, we synthesized CNF from a liquid phase carbon source by a solvothermal method. In addition, we studied the parameters for the preparation of CNF by controlling heating and cooling rates, synthesis temperature and time. We characterized the CNF by SEM/TEM, XRD, Raman spectroscopy and EDS. We found that the heating and cooling rate have strong effects on the CNF formation and growth. We were able to prepare the best CNF at the heating rate of $10^{\circ}$/min, at $450^{\circ}$ for 60 minutes, and at the cooling rate of $4^{\circ}$/min. As a result of Raman spectra, we found that the sample showed two characteristic Raman bands at ${\sim}1350cm^{-1}$ (D band) and ${\sim}1600cm^{-1}$ (G band). The G band indicates the original graphite feature, but the D band has been explained as a disorder feature of the carbon structure. The diameter and length of the CNF was about $15{\sim}20nm$, and over $1{\mu}$, respectively.