• Title/Summary/Keyword: Surface phase diagram

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Phase Transformation and Misconstruct of REBa2Cu3O7-x (RE=Nd, Gd, Dy) Superconductor during Heat treatment (REBa2Cu3O7-x (RE=Nd, Gd, Dy) 초전도체의 열처리에 따른 상변태와 미세구조)

  • 오용택;한용희;한병성;한상철;성태현;홍광준;신동찬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1278-1285
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    • 2003
  • This study investigated the phase transformation of the REBa$_2$Cu$_3$$O_{7-x}$ (RE=Nd, Gd, Dy) superconductor, and CCT (Continuous-Cooling-Transformation) along with the TTT (Time-Temperature-Transformation) diagrams are suggested according to the isothermal and continuous cooling heat-treatments. The peritectic temperature of the 123 phases decreased approximately 3$0^{\circ}C$ when the ionic radius of the rare-earth elements was reduced. The optimum cooling rate where BC and Cu-free phases do not exist was 0.001$^{\circ}C$/s. At this cooling late, the 123 phase grew with a c-axis Perpendicular to the surface and had a well-distributed 211 phase. When the oxygen partial pressure was reduced Outing isothermal heat-treatment, the formation temperature of the 211 phase decreased. In addition, the formation temperature of the 123 phases decreased from 100$0^{\circ}C$ (Nd-123) to 9$25^{\circ}C$ (Gd-123), and finally 875$^{\circ}C$ (Dy-123) according to the decrease in the ionic radius of the tare-earth elements. Compared to Nd-123, Gd- and Dy-123 had a better texture with a well-distributed 211 phase.e.

An Analysis of Similarities that Students Construct in the Process of Problem Solving (중학생들이 수학 문장제 해결 과정에서 구성하는 유사성 분석)

  • Park Hyun-Jeong;Lee Chong-Hee
    • Journal of Educational Research in Mathematics
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    • v.16 no.2
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    • pp.115-138
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    • 2006
  • The purpose of this paper is to investigate students' constructing similarities in the understanding the problem phase and the devising a plan phase of problem solving. the relation between similarities that students construct and how students construct similarities is researched through case study. Based on the results from the research, authors reached a conclusion as following. All of two students constructed surface similarities in the beginning of the problem solving process and responded to the context of the problem information sensitively. Specially student who constructed the similarities and the difference in terms of a specific dimension by using diagram for herself could translate the equation which used to solve the base problem or the experienced problem into the equation of the target problem solution. However student who understood globally the target problem being based on the surface similarity could not translate the equation that she used to solve the base problem into the equation of target problem solution.

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A study on solidification of silicon by floating technique (부상응고법에 의한 실리콘 응고에 관한 연구)

  • 이근희;이진형
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.30-35
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    • 2000
  • A floating solidification technique is a process applied extensively to the production of glass plates. We used the technique for fabrication of Si plate. We used the proper liquid substrate material of 50 wt% $SiO_2$- 21 wt% $A1_2$$O_3$-29 wt% MnO, after studying ternary phase diagram of various oxides systems. The liquid substrate material has proper properties in the aspects of temperature, density and reactivity. But results showed some problems in fluidity and surface tension of the liquid substrate material.

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Near-infrared Subwavelength Imaging and Focusing Analysis of a Square Lattice Photonic Crystal Made from Partitioned Cylinders

  • Dastjerdi, Somayeh Rafiee;Ghanaatshoar, Majid;Hattori, Toshiaki
    • Journal of the Optical Society of Korea
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    • v.17 no.3
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    • pp.262-268
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    • 2013
  • We study the focusing properties of a two-dimensional square-lattice photonic crystal (PC) comprising silica and germanium partitioned cylinders in air background. The finite difference time domain (FDTD) method with periodic boundary condition is utilized to calculate the dispersion band diagram and the FDTD method incorporating the perfectly matched layer boundary condition is employed to simulate the image formation. In contrast to the common square PCs in which the negative refraction effect occurs in the first photonic band without negative phase propagation, in our suggested model system, the frequency with negative refraction exists in the second band and in near-infrared region. In this case, the wave propagates with a negative phase velocity and the evanescent waves can be supported. We also discuss the dependency of the image resolution and its location on surface termination, source location, and slab thickness. According to the simulation results, spatial resolution of the proposed PC lens is below the radiation wavelength.

Effect of Isothermal Transformation Heat-treatment Time on Cold Workability of STS 430 Stainless Steel after High Temperature Gas Nitriding (고온 가스질화 된 STS 430 스테인리스강의 냉간 가공성에 미치는 항온변태 열처리 시간 변화의 영향)

  • Kim, J.M.;Hyun, Y.K.;Song, S.W.;Kim, G.D.;Son, Y.H.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.1
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    • pp.15-22
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    • 2014
  • This study is to investigate the phase changes and cold workability after isothermal transformation at $780^{\circ}C$ by using the high temperature gas nitrided (HTGN) STS 430 ferritic stainless steel specimens. The phase diagram of STS 430 steel obtained by calculation showed that the phase appeared at $1100^{\circ}C$ showed as ${\alpha}+{\gamma}{\rightarrow}{\gamma}{\rightarrow}{\gamma}+Cr_2N{\rightarrow}{\gamma}+Cr_2N+CrN$ with increasing nitrogen concentration. Also, the transformation of ${\gamma}{\rightarrow}Cr_2N$ during heat treatment isothermally at $780^{\circ}C$, nitrogen pearlite with lamellar type was fully formed at the nitrogen permated surface layer for 10 hrs. However, this transformation was not completed for 1 hr, resulting nitrogen pearlite plus martensite. The cold rolled specimen of isothermally transformed at $780^{\circ}C$ for 10 hrs after high temperature gas nitriding decreased the layer thickness of nitrogen pearlite inducing the deformation of hard $Cr_2N$ phase. the dissolution rate of $Cr_2N$ phase increased rapidly with increasing cold rolling ratio. Specimens with the microstructure of nitrogen pearlite (isothermally transformed at $780^{\circ}C$ for 10 hrs) were possible to cold rolling without crack formation. However, the mixed structures of nitrogen pearlite + martensite (isothermally transformed at $780^{\circ}C$ for 1 hr) were impossible to cold deformation without cracking.

Formation of Thicker hard Alloy Layer on Aluminum Alloy by PTA Overlaying with Metal Powders (플라스마 아크 紛體肉盛法에 의한 Al 合金의 硬化厚膜 合金化層의 形成)

  • ;;中田一博;松田福久
    • Journal of Welding and Joining
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    • v.11 no.2
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    • pp.74-85
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    • 1993
  • Effect of Si metal powders addition with the plasma transferred arc(PTA) overlaying process on characteristics of the alloyed layer in aluminum alloy(A5083) has been investigated. The overlaying conditions were 175-250A in plasma arc current, 500mm/min in travel speed, the 5-20g/min in powder feeding rate. Main results obtained are summarized as follows. 1)Sufficient size of molten pool on surface of base metal was required for forming an alloyed layer; in a fixed travel, the formation of alloyed layer with clear and beautiful surface depend upon the plasma arc current and powder feeding rate; the greater plasma arc current and the smaller powder feeding rate were, the better bead was formed. Optimum alloyed conditions by which an excellent alloyed bead obtained was 225A in plasma arc current. PTA process made it possible to form an alloyed layer with up to 67wt% Si. 2)Microstructure in the alloyed layer was in accord with prediction from the Al-Si phase diagram 3)The hardness of the alloyed layer increased in proportion to Si content. 4)As volume fraction of primary Si increased, the specific wearness of the alloyed layer was significantly improved. However, no further improvement was found when the volume fraction was greater than about 30%. 5)Utilizing the PTA process, a crack free alloyed layer with maximum hardness of about Hv 310 could be obtained.

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Joining Characteristics of Plasma Sprayed BSCCO Superconducting Coatings (플라즈마 용사 BSCCO(Bismuth Strontium Calcium Copper Oxide) 초전도 피막의 접합 특성)

  • Park, Jung-Sik;Cho, Chang-Eun;Ko, Young-Bong;Park, Kwang-Soon;Park, Kyeung-Chae
    • Journal of the Korean institute of surface engineering
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    • v.46 no.5
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    • pp.181-186
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    • 2013
  • We performed plasma spraying for 2001 (Bi:Cu = 2:1), 0212 (Sr:Ca:Cu = 2:1:2) oxide powders. $Bi_2Sr_2CaCu_2Ox$ (2212) superconductor has been prepared by PMP-AT (partial melting process-annealing treatment). The 2212 phase is synthesized between Sr-Ca-Cu oxide coating layer (0212) and Bi-Cu oxide coating layer (2001) by movement of partial melted Bi on 2001 layer and the diffusion reaction (Cu, Sr, Ca) after PMP-AT. There are two different coating layers on joining process. The one is ABAB coating layers and the other is BAAB coating layers by arrangement of 2001 (A), 0212 (B) layers. We performed heat treatment these two different coating layers processes under same PMP-AT conditions. We obtained Bi-2212 superconducting layers at each experimental condition, and the result of MPMS, the critical temperature was showed about 78 K. But the microstructure images and result of EDS as each experimental variable were showed about the qualitatively different Bi-2212 superconducting phases. We also deduced the generation mechanism of Bi-2212 superconducting layer as a result of these experimental data, microstruc ture images, EDS data and phase diagram.

Skarn-Ore Associations and Phase Equilibria in the Yeonhwa-Keodo Mines, Korea (태백산광화대(太白山鑛化帶) 연화(蓮花)-거도광산(巨道鑛山)에 있어서의 스카른과 광석광물(鑛石鑛物)의 수반관계(隨伴關係) 및 상평형(相平衡))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.16 no.1
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    • pp.1-10
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    • 1983
  • The Yeonhwa (I, II) and Keodo mines, neighboring in the middle part of the Taebaegsan mineral belt, contain three distinct classes of skarn deposits: the zinc-lead skarn at Yeonhwa (I, II), the iron skarn at Keodo south (Jangsan orebodies), and the copper skarn at Keodo north (78 orebodies). The present study characterizes the three classes of skarn deposits mainly in terms of skarn/ore associations examined from chemical compositional point of view, and applies existing quantitative phase diagrams to some pertinent mineral assemblages in these mines. At Yeonhwa I the Wolam I orebody shows a vertical variation in skarn minerals ranging from clinopyroxene/garnet zone on the lower levels through clinopyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite veins on the upper levels and surface. Ore minerals, sphalerite and galena, associate most closely with the intermediate clinopyroxene zone. At Keodo, the Jangsan iron skarn hosted in quartz monzodiolite as a typical endoskarn, shows a skarn zoning, from center of orebody to outer side, magnetite zone, magnetite/garnet zone, garnet clinopyroxene zone, and clinopyroxene/epidote/plagioclase zone. The 78 copper skarn in the Hwajeol limestone indicates a zoning, from quartz porphyry side toward limestone side, orthoclase/epidote zone, epidote/clinopyroxene zone, and clinopyroxene/garnet zone; chalcopyrite and other copper sulfides tend to be in clinopyroxene/garnet zone. Mioroprobe analyses of clinopyroxenes and garnets from the various skarn zones mentioned above revealed that the Yeonhwa zinc/lead skarns are characterized by johansenitic clinopyroxene (Hd 25-78, Jo 15-23) and manganoan andraditic garnet (Ad 13-97, Sp 1-24), whereas the Jangsan iron skarn at Keodo by Mn-poor diopsidic clinopyroxene (Di 78-93, Jo 0.2-1.0) and Mn-poor grossularitic grandite (Gr 65-77, Sp 0.5-1.0). The 78 copper skarn at Keodo is characterized by Mn-poor diopsidic-salite (Di 66-91, Jo 0.2-1.1) and Mn-poor andraditic grandite(Ad 40-74, Sp 0.5-1.1). The compositional charateristics of iron, copper, and zinc-lead skarns in the Yeonhwa-Keodo mines are in good correlations with those of the foreign counterparts. Compiling a $T-XCO_2$ phase diagram for the Jangsan endoskarns, a potential upper limit of temperature of the main stage of skarn formation is estimated to be about $530^{\circ}C$, and a lower limit to be $400^{\circ}C$ or below assuming $XCO_2=0.05$ at P total=1kb. Applying a published log $fS_2$-log $fo_2$ diagram to the Keodo 78 and Yeonhwa exoskarns, it is revealed that copper sulfides and zinc-lead sulfides do not co-exist stably below log $fS_2=-4$ and log $fO_2=-23$ at $T=400^{\circ}C$ and ${\times}CO=1$ atm.

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Dispersion Characteristics of Cylindrical Shells Submerged in the Fluid (유체에 잠긴 원통형 실린더의 파동 분산 특성)

  • Jung, Byung-Kyoo;Hong, Chinsuk;Ryue, Jungsoo;Jeong, Weui-Bong;Shin, Ku-Kyun
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.25 no.8
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    • pp.575-582
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    • 2015
  • This paper deals with the dispersion relation of the waves sustained in a cylindrical shell submerged in the fluid. The waveguide finite method and the boundary element method are used to predict the dispersion characteristic of the cylindrical shell. The dispersion diagram of the cylinder is estimated from the eigenvalue problem and the forced vibration response. It follows that the water-loading leads to the decrease of the cut-on frequencies and the phase speeds of the bending waves. On the contrary, the longitudinal waves and the torsional waves are hardly affected by the fluid, and therefore the order of the cut-on frequencies of the waves is changed. The acoustic dispersion diagram is also estimated from the forced acoustic response to identify the characteristics of the wave radiated to the fluid. It follows that the acoustic waves on and near the surface of the cylinder are the same as those in the structure. But at the far field the acoustic waves caused by subsonic waves e.g., the bending waves disappear as the increase of the distance. Conclusively, the characteristics of waves in cylindrical shells are significantly affected by water-loading in terms of the cut-on frequency, the wave speed, the order of the cut-on and radiation.

Microstructure and Hardness of Surface Melting Hardened Zone of Mold Steel, SM45C using Yb:YAG Disk Laser

  • Lee, Kwang-Hyeon;Choi, Seong-Won;Yoon, Tae-Jin;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.34 no.1
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    • pp.75-81
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    • 2016
  • This study applied laser surface melting process using CW(Continuous wave) Yb:YAG laser and cold-work die steel SM45C and investigated microstructure and hardness. Laser beam speed, power and beam interval are fixed at 70 mm/sec, 2.8 kW and $800{\mu}m$ respectively. Depth of Hardening layer(Melting zone) was a minimum of 0.8 mm and a maximum of 1.0 mm that exceeds the limit of minimum depth 0.5 mm applying trimming die. In all weld zone, macrostructure was dendrite structure. At the dendrite boundary, Mn, Al, S and O was segregated and MnS and Al oxide existed. However, this inclusion didn't observe in the heat-affected zone (HAZ). As a result of interpreting phase transformation of binary diagram, MnS crystallizes from liquid. Also, it estimated that Al oxide forms by reacting with oxygen in the atmosphere. The hardness of the melting zone was from 650 Hv to 660 Hv regardless of the location that higher 60 Hv than the hardness of the HAZ that had maximum 600 Hv. In comparison with the size of microstructure using electron backscatter diffraction(EBSD), the size of microstructure in the melting zone was smaller than HAZ. Because it estimated that cooling rate of laser surface melting process is faster than water quenching.