• Title/Summary/Keyword: Surface phase change

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Design of a Plasmonic Switch Using Ultrathin Chalcogenide Phase-change Material

  • Lee, Seung-Yeol
    • Current Optics and Photonics
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    • v.1 no.3
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    • pp.239-246
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    • 2017
  • A compact plasmonic switching scheme, based on the phase change of a thin-film chalcogenide material ($Ge_2Sb_2Te_5$), is proposed and numerically investigated at optical-communication wavelengths. Surface plasmon polariton modal analysis is conducted for various thicknesses of dielectric and phase-change material layers, and the optimized condition is induced by finding the region of interest that shows a high extinction ratio of surface plasmon polariton modes before and after the phase transition. Full electromagnetic simulations show that multiple reflections inside the active region may conditionally increase the overall efficiency of the on/off ratio at a specific length of the active region. However, it is shown that the optimized geometrical condition, which shows generally large on/off ratio for any length of active region, can be distinguished by observing the multiple-reflection characteristic inside the active region. The proposed scheme shows an on/off switching ratio greater than 30 dB for a length of a few micrometers, which can be potentially applied to integrated active plasmonic systems.

Effect of pH on the Preparation of Manganese Zinc Ferrite Powder by Alcoholic Dehydration of Citrate/formate Solution (알콜 탈수법에 의한 Mn-Zn Ferrite 분체 제조시 pH의 영향)

  • 김창범;신효순;이대희;김창현;이병교
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1123-1130
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    • 1995
  • In the preparation of manganese zinc ferrite powders by alcoholic dehydration of citrate/formate solution. The effect of pH change on precipitation was investigated. The pH range for obtaining stable precipitates was studied. The glassy phase was obtained when the pH value of solution is higher than 5, and the formation mechanism of glassy phase was suggested. Below pH 5, the stable precipitates were formed, and the optimal pH was 2. Formation of glassy phase was accounted for the change of surface charge by pH change. The change of surface charge is caused by the interparticular agglomeration. The precipitate was redissolved into the water on the surface of precipitate itself and through the polymerization, it agglomerated. This mechanism is tought to be similar to that of viscous flow.

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A Study on the Heat Transfer Characteristics and Performance of the High Temperature Range Heater Plate Using Liquid-Vapor Phase Change Heat Transfer (기-액 상변화 열전달식 고온 히터 플레이트의 작동 특성과 성능에 관한 연구)

  • Kang, Hwan-Kook;Yim, Kwang-Bin
    • Journal of the Korean institute of surface engineering
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    • v.46 no.6
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    • pp.283-289
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    • 2013
  • The experimental study for the temperature uniformity on the wafer using liquid-vapor phase heat transfer mechanism is performed. For the experiment, the heater plate which is consist of stainless steel container, working fluid and electrical heater is designed, manufactured and tested at the range of 600 to $850^{\circ}C$. The results showed that the phase change type heater plate was much more uniform and stable temperature on the heater plate surface and wafer than the uniform heat flux type heater plate at the atmospheric condition. Also, the results of 300 mm outer diameter of heater plate showed that the same temperature uniformity compared with 230 mm.

Effects of Mo Content on Surface Characteristics of Dental Ni-Ti Alloys (치과용 Ni-Ti합금의 표면특성에 미치는 Mo함량의 영향)

  • Han-Cheol Choe;Jae-Un Kim;Sun-Kyun ark
    • Corrosion Science and Technology
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    • v.22 no.1
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    • pp.64-72
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    • 2023
  • Ni-Ti shape memory alloy for dental nerve treatment devices was prepared by adding Mo to Ni-Ti alloy to improve flexibility and fatigue fracture characteristics and simultaneously increase corrosion resistance. Surface properties of the alloy were evaluated. Microstructure analysis of the Ni-Ti-xMo alloy revealed that the amount of needle-like structure increased with increasing Mo content. The shape of the precipitate showed a pattern in which a long needle-like structure gradually disappeared and changed into a small spherical shape. As a result of XRD analysis of the Ni-Ti-xMo alloy, R-phase structure appeared as Mo was added. R-phase and B2 structure were mainly observed. As a result of DSC analysis, phase transformation of the Ti-Ni-Mo alloy showed a two-step phase change of B2-R-B19' transformation with two exothermic peaks and one endothermic peak. As Mo content increased, R-phase formation temperature gradually decreased. As a result of measuring surface hardness of the Ti-Ni-Mo alloy, change in hardness value due to the phase change tended to decrease with increasing Mo content. As a result of the corrosion test, the corrosion potential and pitting potential increased while the current density tended to decrease with increasing Mo content.

Concentration of Liquid-phase in the Surface Region and Microstructural Change in Pressureless Sintered$\beta$-SiC (상압소결 $\beta$-SiC에 있어서 표면부에서의 액상집중과 미세구조의 변화)

  • Lee, Jong-Kook;Yang, Gwon-Seung;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.921-927
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    • 1996
  • The liquid-phase concentration from the interior to the surface region and its influence on the microstructural changes were investigated in pressureless sintered $\beta$-SiC Surface reaction-layer was formed by reaction of packing powder and volatile components on the surface during sintering which was induced the concentration of liquid-phase in the surface regions. The microstructural changes between the surface region and the interior were appeared in sintered specimen which was resulted from the difference of liquid-phase content during sintering. Microstructural changes were observd with the depth of about 250${\mu}{\textrm}{m}$ from he surface. The grain size and aspect ratio of SiC in the interior are larger than those in the surface region and the rate of transforma-tion of $\beta$-to $\alpha$-SiC during sintering is higher in the interior than that in the surface region.

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Effect of Annealing Temperature on Phase-change Characteristics of GeSbTe-based Bilayers (GeSbTe계 이중층의 상변화 특성에 미치는 열처리 온도 효과)

  • Yoon, Hoi Jin;Bang, Ki Su;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.86-90
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    • 2017
  • This work reports the phase-change behavior and thermal stability of doped GeSbTe/GeSbTe bilayers. We prepared the bilayers using RF sputtering, and annealed them at annealing temperature ranging from $100^{\circ}C$ to $400^{\circ}C$. The sheet resistance of the bilayer decreased and saturated with increasing annealing temperature, and the saturated value was close to that of pure GeSbTe film. The surface of the bilayer roughened at $400^{\circ}C$, which corresponds to the surface roughening of doped GeSbTe film. Mixed phases of face-centered cubic and hexagonal close-packed crystalline structures were identified in the bilayers annealed at elevated temperature. These results indicate that the phase-change behavior of the bilayer depends on the concurrent phase-transitions of the two GeSbTe-based films. The dopants in the doped GeSbTe film were diffused out at annealing temperatures of $300^{\circ}C$ or higher, which implies that the thermal stability of the bilayer should be considered for its application in phase-change electronic devices.

Electrical and thermal characteristics of PRAM with thickness of phase change thin film (상변화 박막의 두께에 따른 상변화 메모리의 전류 및 열 특성)

  • Choi, Hong-Kyw;Kim, Hong-Seung;Lee, Seong-Hwan;Jang, Nak-Won
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.162-168
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    • 2008
  • In this paper, we analyzed the heat transfer phenomenon and the reset current variation of PRAM device with thickness of phase change material using the 3-D finite element analysis tool. From the simulation, Joule's heat was generated at the contact surface of phase change material and bottom electrode of PRAM. As the thickness of phase change material was decreased, the reset current was highly increased. In case thickness of phase change material thin film was $200\;{\AA}$, heat increased through top electrode and reset current caused by phase transition highly increased. And as thermal conductivity of top electrode decreased, temperature of unit memory cell was increased.

Melting of Ice Inside a Horizontal Cylinder under the Volume Change (수평원관내 체적변화를 고려한 얼음의 용용시 전열특성에 관한 연구)

  • 조남철;김동춘;이채탈;임장순
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1266-1274
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    • 2001
  • Heat transfer phenomena during melting process of the phase change material (ice) was studied by numerical analysis and experiments. In a horizontal ice storage tube, the natural convection caused an increase in melting rate. However, the reduction of the heating surface area caused a decrease in melting rate. Therefore, during the melting process of ice in a horizontal cylinder, the reduction of the heating surface area should be considered. Under the same heating wall and initial water temperature condition, the melting rate became higher for $V_s/V_tot/=0.545 \;than \;that\; for\; V_s/V_tot$/=1.00 due to the difference in the reduction of heating surface area. A modified melting model considering the equivalent thermal conductivity of liquid phase and volume reduction was proposed. The results of the model were compared with the measured values and found to be in good agreement.

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Analysis of the Phase Change of a Laser Beam in a Laser Doppler Vibrometer Due To the Sound Field Radiated From Structures Vibrating Underwater (수중에서 진동하는 구조물로부터 방사되는 음에 기인한 레이저 도플러 진동측정기 광선의 위상변화에 대한 분석)

  • Kil, Hyun-Gwon;Jarzynski, Jacek
    • The Journal of the Acoustical Society of Korea
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    • v.27 no.4
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    • pp.178-182
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    • 2008
  • In measurements of the vibration of structures underwater with a laser Doppler vibrometer, the surface vibration is measured by means of detecting the phase change of the laser beam due to the structural vibration. The laser beam passes through the sound field radiated from the vibrating structures underwater. It experiences an additional phase change due to the change in refractive index in the radiated sound field. This phase change due to the sound field may cause the error in surface vibration measurements. In this paper, this phase change due to the radiated sound filed has been analyzed. The numerical simulation has been peformed to evaluate the phase change in sound field radiated from an infinite cylindrical structure vibrating underwater.

Enhancement of Surface Hardness of Zirconia Ceramics by Hydroxyapatite Powder Bed Sintering (Hydroxyapatite 분위기 소결을 통한 지르코니아 표면 경도 강화)

  • Choi, Min-Geun;Lim, Ji-Ho;Kong, Kyu-Hwan;Jeong, Dae-Yong;Lee, Wonjoo;Li, Long-Hao;Kong, Young-Min
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.677-681
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    • 2014
  • To increase the mechanical property of zirconia, we have investigated the phase change and the resulting hardness of zirconia ceramics by hydroxyapatite (HA) powder bed sintering. It was observed using X-ray diffraction that the cubic zirconia phase, which has a higher hardness value than that of the tetragonal phase, was obtained at the surface of 3 mol% $Y_2O_3$ doped tetragonal zirconia polycrystal (3Y-TZP) ceramics during the sintering process; in our experimental conditions, the phase change at the surface increased as the sintering time increased. We believe that the observed crystalline phase change originated from the decomposition of HA and the diffusion of CaO, as follows. CaO, which was derived from the decomposition of HA at high temperature ($1400^{\circ}C$), diffused into the surface of 3Y-TZP and acted as a stabilizer. As a result, the Vickers hardness value of the treated specimens was higher than that of the non-treated specimen due to the formation of the cubic phase on the surface of 3Y-TZP.