• 제목/요약/키워드: Surface modification

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마그네토플라즈모닉 나노 자성 입자의 합성과 응용 (Synthesis and Application of Magnetoplasmonic Nanoparticles)

  • 박세정;황시영;정성환;곽주용;이재범
    • 한국분말재료학회지
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    • 제28권5호
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    • pp.429-434
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    • 2021
  • Magnetic nanoparticles have a significant impact on the development of basic sciences and nanomedical, electronic, optical, and biotech industries. The development of magnetic structures with size homogeneity, magnetization, and particle dispersibility due to high-quality process development can broaden their utilization for separation analysis, structural color optics using surface modification, and energy/catalysts. In addition, magnetic nanoparticles simultaneously exhibit two properties: magnetic and plasmon resonance, which can be self-assembled and can improve signal sensitivity through plasmon resonance. This paper reports typical examples of the synthesis and properties of various magnetic nanoparticles, especially magnetoplasmonic nanoparticles developed in our laboratory over the past decade, and their optical, electrochemical, energy/catalytic, and bio-applications. In addition, the future value of magnetoplasmonic nanoparticles can be reevaluated by comparing them with that reported in the literature.

Interfacial Material Engineering for Enhancing Triboelectric Nanogenerators

  • Nguyen, Dinh Cong;Choi, Dukhyun
    • 센서학회지
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    • 제31권4호
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    • pp.218-227
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    • 2022
  • Triboelectric nanogenerators (TENGs), a new green energy, that have various potential applications, such as energy harvesters and self-powered sensors. The output performance of TENGs has been improving rapidly, and their output power significantly increased since they were first reported owing to improved triboelectrification materials and interfacial material engineering. Because the operation of a TENG is based on contact electrification in which electric charges are exchanged at the interface between two materials, its output can be increased by increasing the contact area and charge density. Material surface modification with microstructures or nanostructures has increased the output performance of TENGs significantly because not only does the sharp micro/nano morphology increases the contact area during friction, but it also increases the charge density. Chemical treatment in which ions or functional groups are added has also been used to improve the performance of TENGS by modifying the work functions, charge densities, and dielectric constants of the triboelectric materials. In addition, ultrahigh output power from TENGs without using new materials or treatments has been obtained in many studies in which special structures were designed to control the current release or to collect the charge current directly. In this review, we discuss physical and chemical treatments, bulk modifications, and interfacial engineering for enhancing TENG performance by improving contact electrification and electrostatic induction.

Review, Assessment, and Learning Lesson on How to Design a Spectroelectrochemical Experiment for the Molten Salt System

  • Killinger, Dimitris;Phongikaroon, Supathorn
    • 방사성폐기물학회지
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    • 제20권2호
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    • pp.209-229
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    • 2022
  • This work provided a review of three techniques-(1) spectrochemical, (2) electrochemical, and (3) spectroelectrochemical-for molten salt medias. A spectroelectrochemical system was designed by utilizing this information. Here, we designed a spectroelectrochemical cell (SEC) and calibrated temperature controllers, and performed initial tests to explore the system's capability limit. There were several issues and a redesign of the cell was accomplished. The modification of the design allowed us to assemble, align the system with the light sources, and successfully transferred the setup inside a controlled environment. A preliminary run was executed to obtain transmission and absorption background of NaCl-CaCl2 salt at 600℃. It shows that the quartz cuvette has high transmittance effects across all wavelengths and there were lower transmittance effects at the lower wavelength in the molten salt media. Despite a successful initial run, the quartz vessel was mated to the inner cavity of the SEC body. Moreover, there was shearing in the patch cord which resulted in damage to the fiber optic cable, deterioration of the SEC, corrosion in the connection of the cell body, and fiber optic damage. The next generation of the SEC should attach a high temperature fiber optic patch cords without introducing internal mechanical stress to the patch cord body. In addition, MACOR should be used as the cell body materials to prevent corrosion of the surface and avoid the mating issue and a use of an adapter from a manufacturer that combines the free beam to a fiber optic cable should be incorporated in the future design.

Coating Performance of SiO2 / Epoxy Composites as a Corrosion Protector

  • Rzaij, Dina R.;Ahmed, Nagham Y.;Alhaboubi, Naseer
    • Corrosion Science and Technology
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    • 제21권2호
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    • pp.111-120
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    • 2022
  • To solve the corrosion problem of industrial equipment and other constructions containing metals, corrosion protection can be performed by using coating which provides a barrier between the metal and its environment. Coatings play a significant role in protecting irons and steels in harsh marine and acid environments. This study was conducted to identify an anti-corrosive epoxy coating for carbon steel composite with 0.1, 0.3, and 0.5 wt% concentrations of nanoparticles of SiO2 using the dip-coating method. The electrochemical behavior was analyzed with open circuit potential (OCP) technics and polarization curves (Tafle) in 3.5 wt% NaCl and 5 vol% H2SO4 media. The structure, composition, and morphology were characterized using different analytical techniques such as X-ray Diffraction (XRD), Fourier Transform Infrared spectrum (FT-IR), and Scanning Electron Microscopy (SEM). Results revealed that epoxynano SiO2 coating demonstrated a lower corrosion rate of 2.51 × 10-4 mm/year and the efficiency of corrosion protection was as high as 99.77%. The electrochemical measurement showed that the nano-SiO2 / epoxy coating enhanced the anti-corrosive performance in both NaCl and H2SO4 media.

Estimating the lateral profile of helical piles using modified p-y springs

  • Hyeong-Joo Kim;Hyeong-Soo Kim;Peter Rey Dinoy;James Vincent Reyes;Yeong-Seong Jeong;Jun-Yong Park;Kevin Bagas Arifki Mawuntu
    • Geomechanics and Engineering
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    • 제35권1호
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    • pp.1-11
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    • 2023
  • A growing trend of utilizing helical piles for soft soil strata to support infrastructure projects is currently observed in Saemangeum, South Korea. Recognized mainly due to its ease of installation and reusability proves to be far more superior compared to other foundation types in terms of sustainability. This study applies modified p-y springs to characterize the behavior of a laterally loaded helical pile with a shaft diameter of 89.1 mm affixed with 3 helices evenly spaced along its embedded length of 2.5 m. Geotechnical soil properties are correlated from CPT data near the test bed vicinity and strain gauges mounted on the shaft surface. A modification factor is applied on the p-y springs to adjust the simulated data and match it to the bending moment, soil resistance and deflection values from the strain gauge measurements. The predicted lateral behavior of the helical pile through the numerical analysis method shows fairly good agreement to the recorded field test results.

STO기판에 금 나노입자가 분산된 YBCO 박막의 특성 (Characteristics of $YBa_2Cu_3O_{7-x}$ Thin Films on $SrTiO_3$ substrate with surface modification by Au nanoparticles)

  • 오세권;장건익;;강병원;이초연;현옥배
    • 한국초전도ㆍ저온공학회논문지
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    • 제12권3호
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    • pp.7-11
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    • 2010
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. In this work, we investigated electric characteristic of YBCO films on $SrTiO_3$ (100) substrates whose surfaces were modified by the introduction of Au nanoparticles (AuNPs). Au nanoparticles were uniformly dispersed on STO substrates with one of typical solution techniques, self assembled monolayer. After heating the STO substrates with Au nanoparticles, the size of Au nanoparticles was around 29~32 nm in height and 41~49 nm in diameter. XRD diffraction patterns taken on the YBCO film with Au nanoparticles show the c-axis orientation. The measured $T_c$ of YBCO /AuNPs films was around 89K and the $J_c$ was 0.75 MA/$cm^2$ at 65 K and 1 T.

Effect of joint Details on Fatigue Properties of a Slot Structure

  • Youn, J.G.;Kim, H.S.;Park, D.H.
    • International Journal of Korean Welding Society
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    • 제1권1호
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    • pp.51-57
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    • 2001
  • Effect of the joint details on the stress distribution over a slot structure has been studied in order to improve its fatigue life using a finite element analysis. The joint details of interest are the radius and height of scallop at the stiffener as well as the mis-alignment between the stiffener and longitudinal member. For a slot structure currently used, the stiffener heel is subjected to the maximum stress for a given external load, where is a potential fatigue crack initiation site. The stresses at the stiffener heel and toe decrease both by increasing the scallop radius and more significantly by increasing the mis-alignment while no notable effect of the scallop height on it is appreciated. A proper combination of these factors makes it possible to reduce the stresses at the stiffener heel and In, theoretically, more than 50%. This is attributed to the modification of the stress distribution over the slot structure including the transition of the maximum stressed region from the stiffener heel to the slot surface of the transverse web. Such then results in a g[eat improvement of the fatigue life of the slot structure.

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Performance evaluation of plasma nitrided 316L stainless steel during long term high temperature sodium exposure

  • Akash Singh;R. Thirumurugesan;S. Krishnakumar;Revati Rani;S. Chandramouli;P. Parameswaran;R. Mythili
    • Nuclear Engineering and Technology
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    • 제55권4호
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    • pp.1468-1475
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    • 2023
  • Enhancement of wear resistance of components used in fast reactors is necessary for long service life of the components. Plasma nitriding is a promising surface modification technology to impart high hardness and improved wear resistance of various steel components. This study discusses the characterization of chrome nitrided SS316L casing ring used in secondary sodium pump of fast breeder reactor and its stability under long term sodium exposure. Microstructural and hardness analysis showed that stress relieved component could be chrome nitrided successfully to a thickness of about 100 ㎛. Assessment of in-sodium performance of the chrome nitrided casing ring subjected to long term exposure up to 5000h at 550℃, showed retention of chrome nitrided layer with a case depth almost similar to that before sodium exposure. A slight decrease in the hardness was observed due to prolonged high temperature sodium exposure. Tribological studies indicate very low coefficient of friction indicating the retention of good wear resistance of the coating even after long term sodium exposure.

초임계 CO2를 활용한 콘크리트의 최적 탄산화양생기법 개발에 관한 기초적 연구 (A Basic Study on the Development of Optimum Carbonation Curing Techniques for Concrete Using Supercritical CO2)

  • 홍성준;류동우
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2022년도 봄 학술논문 발표대회
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    • pp.91-92
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    • 2022
  • This study is a basic study on carbonation curing technology of concrete using supercritical CO2, and carbonation curing was carried out by exposing concrete to supercritical CO2 for a certain period of time. In the case of conventional carbonation curing, long-term curing was performed for several weeks by controlling the concentration of CO2, but by using supercritical CO2, more rapid carbonation curing was carried out using constant temperature and pressure conditions to improve durability through surface modification of concrete. This experiment was conducted with the goal of deriving the optimal carbonation curing conditions by measuring the carbonation depth by exposing concrete for a certain period of time to conditions above the supercritical level. As a result, it was confirmed that the carbonation depth increased as the curing time increased, and the curing time could be shortened compared to the carbonation curing according to the existing CO2 concentration.

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Defect Detection of Steel Wire Rope in Coal Mine Based on Improved YOLOv5 Deep Learning

  • Xiaolei Wang;Zhe Kan
    • Journal of Information Processing Systems
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    • 제19권6호
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    • pp.745-755
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    • 2023
  • The wire rope is an indispensable production machinery in coal mines. It is the main force-bearing equipment of the underground traction system. Accurate detection of wire rope defects and positions exerts an exceedingly crucial role in safe production. The existing defect detection solutions exhibit some deficiencies pertaining to the flexibility, accuracy and real-time performance of wire rope defect detection. To solve the aforementioned problems, this study utilizes the camera to sample the wire rope before the well entry, and proposes an object based on YOLOv5. The surface small-defect detection model realizes the accurate detection of small defects outside the wire rope. The transfer learning method is also introduced to enhance the model accuracy of small sample training. Herein, the enhanced YOLOv5 algorithm effectively enhances the accuracy of target detection and solves the defect detection problem of wire rope utilized in mine, and somewhat avoids accidents occasioned by wire rope damage. After a large number of experiments, it is revealed that in the task of wire rope defect detection, the average correctness rate and the average accuracy rate of the model are significantly enhanced with those before the modification, and that the detection speed can be maintained at a real-time level.