• Title/Summary/Keyword: Surface modification

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Air Temperature Modification of an Urban Neighborhood Park in Summer - Hyowon Park, Suwon-si, Gyeonggi-do- (여름철 도시근린공원의 기온저감 효과 - 경기도 수원시 효원공원 -)

  • Park, Sookuk;Jo, Sangman;Hyun, Cheolji;Kong, Hak-Yang;Kim, Seunghyun;Shin, Youngkyu
    • Journal of Environmental Science International
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    • v.26 no.9
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    • pp.1057-1072
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    • 2017
  • In order to investigate the effect of air temperature reduction on an urban neighborhood park, air temperature data from five inside locations (forest, pine tree, lawn, brick and pergola) depending on surface types and three outside locations (Suwon, Maetan and Kwonsun) depending on urban forms were collected during the summer 2016 and compared. The forest location had the lowest mean air temperature amongst all locations sampled, though the mean difference between this and the other four locations in the park was relatively small ($0.2-0.5^{\circ}C$). In the daytime, the greatest mean difference between the forest location and the two locations exposed to direct beam solar radiation (brick and lawn) was $0.5-0.8^{\circ}C$ (Max. $1.6-2.1^{\circ}C$). In the nighttime, the mean difference between the forest location and the other four locations in the park was small, though differences between the forest location and locations with grass cover (pine tree and lawn) reached a maximum of $0.9-1.7^{\circ}C$. Comparing air temperature between sunny and shaded locations, the shaded locations showed a maximum of $1.5^{\circ}C$ lower temperature in the daytime and $0.7^{\circ}C$ higher in the nighttime. Comparing the air temperature of the forest location with those of the residential (Kwonsun) and apartment (Maetan) locations, the mean air temperature difference was $0.8-1.0^{\circ}C$, higher than those measured between the forest location and the other park locations. The temperatures measured in the forest location were mean $0.9-1.3^{\circ}C$ (Max. $2.0-3.9^{\circ}C$) lower in the daytime than for the residential and apartment locations and mean $0.4-1.0^{\circ}C$ (Max. $1.3-3.1^{\circ}C$) lower in the nighttime. During the hottest period of each month, the difference was greater than the mean monthly differences, with temperatures in the residential and apartment locations mean $1.0-1.6^{\circ}C$ higher than those measured in the forest location. The effect of air temperature reduction on sampling locations within the park and a relatively high thermal environment on the urban sampling locations was clearly evident in the daytime, and the shading effect of trees in the forest location must be most effective. In the nighttime, areas with a high sky view factor and surface types with high evapotranspiration potential (e.g. grass) showed the maximum air temperature reduction. In the urban areas outside the park, the low-rise building area, with a high sky view factor, showed high air temperature due to the effect of solar (shortwave) radiation during the daytime, while in the nighttime the area with high-rise buildings, and hence a low sky view factor, showed high air temperature due to the effect of terrestrial (longwave) radiation emitted by surrounding high-rise building surfaces. The effect of air temperature reduction on the park with a high thermal environment in the city was clearly evident in the daytime, and the shading effect of trees in the forest location must be most effective. In the nighttime, areas with high sky view factor and surface types (e.g., grass) with evapotranspiration effect showed maximum air temperature reduction. In the urban areas outside the park, the high sky view factor area (low-rise building area) showed high air temperature due to the effect of solar (shortwave) radiation during the daytime, but in the nighttime the low sky view factor area (high-rise building area) showed high air temperature due to the effect of terrestrial (longwave) radiation emitted surrounding high-rise building surfaces.

Osseointegration of zirconia implant in the tibia of pigs (돼지의 경골에 식립된 지르코니아 임플란트의 골유착에 관한 연구)

  • Kim, Lee-Kyoung;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.51 no.3
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    • pp.190-198
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    • 2013
  • Purpose: The purposes of this study were to investigate osseointegration around zirconia implants which had machined or alumina sandblasted surface, and to compare the results with titanium implants. Materials and methods: The study was performed on the tibia of 6 pigs. Three types of implants were investigated: group T-titanium implant, group Z-machined zirconia implant, group ZS-alumina sandblasting treated zirconia implant. Zirconia implants were manufactured from yttria-stabilized tetragonal zirconia polycrystalline (Acucera Inc., Pocheon, Korea). A total of 36 implants were installed in pigs' tibias. After 1, 4 and 12 weeks of healing period, the periotest and the histomorphometric analysis were performed. The data were analyzed using one-way ANOVA and significance was assessed by the Scheffe test (${\alpha}=.05$). Results: In the measurement of surface roughness, highest Ra value was measured in group T with significant difference. No significant differences were found among groups regarding Periotest values. After 1 week, in comparison of bone to implant contact (BIC), group Z showed higher value with significant difference. In comparison of bone area (BA), group T and group Z showed higher value with significant difference than group ZS. After 4 weeks, in comparison of BIC, group T showed higher value with significant difference. Comparison of BA showed no significant difference among each implant. After 12 weeks, the highest mean BIC values were found in group T with significant difference. Group ZS showed higher BIC value with significant difference than group Z. In comparison of BA, group T and group ZS showed higher value with significant difference than group Z. Conclusion: Zirconia implant showed low levels of osseointegration in this experiment. Modification of surface structure should be taken into consideration in designing zirconia implants to improve the success rate.

Frameless Fractionated Stereotactic Radiaton Therapy in Recurrent Head & Neck Cancers (국소재발된 두경부종양의 무고정틀 정위적 분할방사선치료)

  • Kim In-Ah;Choi Ihl-Bhong;Jang Ji-Young;Kang Ki-Mun;Jho Seung-Ho;Kim Hyung-Tae;Lee Kyung-Jin;Choi Chang-Rak
    • Korean Journal of Head & Neck Oncology
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    • v.14 no.2
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    • pp.156-163
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    • 1998
  • Background & Objectives: Frameless fractionated stereotactic radiotherapy(FFSRT) is a modification of stereotactic radiosurgery(SRS) with radiobiologic advantage of fractionation without losing mechanical accuracy of SRS. Local recurrence of head and neck cancer at or near skull base benefit from reirradiation. Main barrier to successful palliation is dose limitation secondary to normal tissue tolerance. We try to evaluate the efficacy and safety of FFSRT as a new modality of reirradaton in these challenging patients. Materials & Methods: Seven patients with recurrent head & neck cancer involving at or near skull base received FFSRT from September 1995 to November 1997. Six patients with nasopharyngeal cancer had received induction chemotherapy and curative radiation therapy. One patient with maxillary sinus cancer had received total maxillectomy and postoperative radiation therapy as a initial treatment. Follow-up ranged from 11 to 32 months with median of 24 months. Three of 7 patients received hyperfractionated radiation therapy(1.1-1.2Gy/fraction, bid, total 19.8-24Gy) just before FFSRT. All patients received FFSRT(3-5Gy/fraction, total 15-30Gy/5-10fractions). Chemotherapy(cis-platin $100mg/m^2$) were given concurrently with FFSRT in four patients. Second course of FFSRT were given in 4 patients with progression or recurrence after initial FFSRT. Because IF(irregularity factor; ratio of surface area of target to the surface area of sphere with same volume as a target) is too big to use conventional stereotactic RT using multiple arc method for protection of radiation damage to critical normal tissue, all patients received FFSRT with conformal method using irregular static ports. Results: Five of 7 patients showed complete remission in follow-up CT &/or MRI. Three of these five patients who developed marginal, in-field, and out-field recurrences, respectively. Another one of complete responders has been dead of G-I bleeding without evidence of local recurrence. One partial responder who showed progressive disease 15 months after initial FFSRT has received additional FFSRT, and then he is well-being with symptomatic improvement. One minmal responder who showed progression of locoregional disease 9 months after $1^{st}$ FFSRT has received 2nd FFSRT, and then he is alive with stable disease. Five of 7 case had showed direct invasion to skull base and had complaint headache and various symptoms of cranial nerve involvement. Four of these five case showed improvement of neurologic symptoms after FFSRT. No significant neurologic complicaltion related to FFSRT was observed during follow-up periods. Tumor volumes were ranged from 3.9 to 50.7 cc and surface area ranged from 16.1 to $114.9cm^2$. IF ranged from 1.21 to 1.74. The average ratio of volume of prescription isodose shell to target volume was 1.02 that indicated the improvement of target coverage and dose distribution with FFSRT with conformal method compared to target coverage with FFSRT with multiple arc method. Conclusion: Our initial experience suggests that FFSRT with conformal method was relatively effective and safe modality in the treatment of recurrent head and neck cancer involving at or near skull base. Treatment benefit included good palliation of symptoms and reasonable radiographic response. However, more experience and additional follow-up are needed to better assess its ultimate role in treating these challenging patients.

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Effects of the Pelvic Compression Belt on Trunk Muscles Activities During Sit-to-Stand, and Stand-to-Sit Tasks (골반압박벨트가 앉아서 일어서기와 일어서서 앉기 동작 시 체간근육 근활성도에 미치는 영향)

  • Jang, Hyun-Jeong;Kim, Suhn-Yeop;Park, Hyun-Ju
    • Physical Therapy Korea
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    • v.20 no.1
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    • pp.1-9
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    • 2013
  • The purpose of this study was to determine the effect of the pelvic compression belt (PCB) on the electromyography (EMG) activities of trunk muscles during sit-to-stand (SitTS), and stand-to-sit (StandTS) tasks. Twenty healthy subjects (7 men and 13 women) were recruited for this study. The subjects performed SitTS, and StandTS tasks, with and without a PCB. Surface EMG was used to record activity of the internal oblique (IO), external oblique (EO), rectus abdominis (RA), erector spinae (ES), and multifidus (MF) of the dominant limb. EMG activity significantly decreased in the RA (without the PCB, $8.34{\pm}6.04$ %maximal voluntary isometric contraction [%MVIC]; with the PCB, $7.64{\pm}5.11$ %MVIC), EO (without the PCB, $14.83{\pm}11.82$ %MVIC; with the PCB, $11.98{\pm}7.60$ %MVIC), MF (without the PCB, $21.74{\pm}7.76$ %MVIC; with the PCB, $18.50{\pm}8.04$ %MVIC), and ES (without the PCB, $18.39{\pm}7.16$ %MVIC; with the PCB, $16.63{\pm}6.31$ %MVIC) during the SitTS task and in the IO (without the PCB, $20.58{\pm}15.60$ %MVIC; with the PCB, $17.27{\pm}12.32$ %MVIlC), RA (without the PCB, $8.04{\pm}5.68$ %MVIC; with the PCB, $7.40{\pm}4.71$ %MVIC), EO (without the PCB, $13.29{\pm}8.80$ %MVIC; with the PCB, $11.24{\pm}6.14$ %MVIC), MF (without the PCB, $18.59{\pm}7.64$ %MVIC; with the PCB, $15.86{\pm}6.48$ %MVIC), and ES (without the PCB, $17.14{\pm}6.44$ %MVIC; with the PCB, $15.46{\pm}5.62$ %MVIC) during the StandTS task when a PCB was used (p<.05). In men the EMG activity of the MF significantly decreased during the SitTS task when a PCB was used (p<.05): in women, the EMG activity of the RA, EO, MF, and ES during the SitTS task and that of the EO, MF, and ES during the SitTS task significantly decreased when a PCB was used (p<.05). In addition, the rates of change in the EMG activity of each muscle differed significantly during the SitTS and StandTS tasks before and after the use of the PCB. However, the EMG activity did not significantly differ between the male and female subjects. These findings suggest that the PCB may contribute to the modification of activation patterns of the trunk muscles during SitTS, and StandTS tasks.

Efficient Cyclization of Substituted Diphenols : Application to the Synthesis of Sulforhodamine B (치환 다이페놀의 효율적 고리화 반응: 설퍼로다민B의 합성에의 응용)

  • Park, Min Kyun;Shim, Jae Jin;Ra, Choon Sup
    • Clean Technology
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    • v.21 no.2
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    • pp.102-107
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    • 2015
  • Rhodamine dyes are widely used as fluorescent probes because of their excellent photophysical properties, such as high extinction coefficients, excellent quantum yields, great photostability, relatively long emission wavelengths. A great synthetic effort has been focused on developing efficient and practical procedures to prepare rhodamine derivatives, because for most applications the probe must be covalently linked to another (bio)molecule or surface. Sulforhodamine B is one of the most used rhodamine dyes for this purpose, because it carries two sulfoxy functions which can be easily utilized for binding with other molecules. Recently, we needed an expedient, practical synthesis of sulforhodamine derivatives. We found the existing procedure for obtaining those compounds unsatisfactory, particularly, with the cyclization process of the dihydroxytriarylmethane (1) to produce the corresponding xanthene derivative (2). We report here our findings, which represent modification of the existing literature procedure and provide access to the corresponding xanthene derivative (2) in a high yield. Use of methanol as a co-solvent was found quite effective to prohibit the water molecule produced during the cyclization reaction from retro-cyclizing back to the starting dihydroxytriarylmethane and the yield of the cyclization was increased (up to 84% from less than 20%). The reaction temperature was significantly lowered (80 vs. 135 ℃). Thus, the reaction proceeds in a higher yield and energy-saving manner where the use of reactants and the production of chemical wastes is minimized.

Evaluation of the stability of sandblasted, large-grit, acid-etched implants with tapered straight body design (테이퍼드 직선형 SLA 임플란트의 안정성 평가)

  • Kim, Yong-Gun;Lee, Kyu-Bok
    • Journal of Dental Rehabilitation and Applied Science
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    • v.34 no.2
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    • pp.80-88
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    • 2018
  • Purpose: Implant surface modification and implant design are the principle targets for achieving successful primary stability. The aim of this study was to measure implant stability quotient (ISQ) values of sandblasted, large-grit, acid-etched (SLA) implants with tapered straight body design during the healing period, and to determine the various factors affecting implant stability. Materials and Methods: To measure implant stability, resonance frequency analysis (RFA) was performed in 26 patients (13 women and 13 men) with 44 SLA implants with tapered straight body design. Implant stability (ISQ values) was evaluated at baseline and healing abutment connection (12 weeks), and the correlations between RFA and insertion torque (IT), bone quality, and jawbone were determined. Results: The mean ISQ value of the implants was $69.4{\pm}10.2$ at the time of implant placement (baseline) and $81.4{\pm}6.9$ at the time of healing abutment connection (P < 0.05). Significant differences were found between RFA and bone quality and between RFA and jawbone (P < 0.05). No significant differences were found between RFA and IT, insertion area, fixture diameter, and implant length (P > 0.05). Conclusion: ISQ values of SLA implants with tapered straight body design were high at baseline and healing abutment connection. It was concluded that SLA implants with tapered straight body design show improved primary and secondary stability, and that immediate or early loading may be applicable.

Weathering Impact for Rock Properties and Material Characteristics of Concretes Used Stone Pagoda of the Mireuksaji Temple Site, Iksan, Korea (익산 미륵사지 석탑에 사용된 콘크리트의 재료학적 특성과 석재의 풍화에 미치는 영향)

  • Lee Dong-Sik;Lee Chan-Hee;Kim Ji-Young
    • Economic and Environmental Geology
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    • v.39 no.3 s.178
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    • pp.285-299
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    • 2006
  • The Mireuksaji stone pagoda in Iksan is the largest stone pagoda existing in Eastern Asia. It was assumed that originally it had been established in the shape of nine-storied pagoda but as time went by only six-storied pagoda remained partially due to collapsing, repair and reconstruction. According to the reference, we can't make sure when its modification happened. The form that the pagoda is having now, was modified with concrete by the Japanese during the 1910s. The materials mixed in concrete were mixture of Portland cement, all sorts of stone, sand, and a little bit of new building stone, additive and compound. And also these materials were applied to cultural assets without any experiment at the time of 1910s as maintenance, which are still used recently. To prevent the change of its shape, the west side, south side and the north side which is partially destructed was rebuilt and reinforced with concrete and some of the deformed parts were also filled. The amounts of concrete used were about 200 tons. Such method had prevented the pagoda from destructing, however, by choosing a wrong repair method, its surface of the stone has secondary contaminants and precipitation caused by concrete. This kind of contamination speeds up the weathering which accelerates the aging mechanism of the stone to make it even harder to revive the absence of historical nature. Therefore, we are to find the best cleaning method to remove the secondary hazard contaminants.

Visible Light Responsive Titanium Dioxide (TiO2) (가시광 감응 산화티탄(TiO2))

  • Shon, Hokyong;Phuntsho, Sherub;Okour, Yousef;Cho, Dong-Lyun;Kim, Kyoung Seok;Li, Hui-Jie;Na, Sukhyun;Kim, Jong Beom;Kim, Jong-Ho
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.1-16
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    • 2008
  • Titanium dioxide ($TiO_2$) is one of the most researched semiconductor oxides that has revolutionised technologies in the field of environmental purification and energy generation. It has found extensive applications in heterogenous photocatalysis for removing organic pollutants from air and water and also in hydrogen production from photocatalytic water-splitting. Its use is popular because of its low cost, low toxicity, high chemical and thermal stability. But one of the critical limitations of $TiO_2$ as photocatalyst is its poor response to visible light. Several attempts have been made to modify the surface and electronic structures of $TiO_2$ to enhance its activity in the visible light region such as noble metal deposition, metal ion loading, cationic and anionic doping and sensitisation. Most of the results improved photocatalytic performance under visible light irradiation. This paper attempts to review and update some of the information on the $TiO_2$ photocatalytic technology and its accomplishment towards visible light region.

An Analysis of the Pseudo-analytical Thought and Analytical Thought that Students Do in the Process of Algebra Problem Solving (대수 문장제 해결 과정에서 나타나는 擬似(의사) 분석적 사고와 분석적 사고에 대한 분석 - 중학생 대상의 사례 연구 -)

  • Park, Hyun-Jeong;Lee, Chong-Hee
    • Journal of Educational Research in Mathematics
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    • v.17 no.1
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    • pp.67-90
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    • 2007
  • The purpose of this study is to understand students' thinking process in the algebra problem solving, on the base of the works of Vinner(1997a, 1997b). Thus, two middle school students were evaluated in this case study to examine how they think to solve algebra word problems. The following question was considered to analyze the thinking process from the similarity-based perspective by focusing on the process of solving algebra word problems; What is the relationship between similarity and the characteristics of thinking process at the time of successful and unsuccessful problem solving? The following results were obtained by analyzing the success or failure in problem solving based on the characteristics of thinking process and similarity composition. Successful problem solving can be based on pseudo-analytical thought and analytical thought. The former is the rule applied in the process of applying closed formulas that is constructed structural similarity not related with the situations described in the text. The latter means that control and correction occurred in all stages of problem solution. The knowledge needed for solutions was applied with the formulation of open-end formulas that is constructed structural similarity in which memory and modification with the related principles or concepts. In conclusion, the student's perception on the principles involved in a solution is very important in solving algebraic word problems.

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Reference values for respiratory system impedance using impulse oscillometry in school-aged children in Korea (학동기 소아에서 impulse oscillometry system로 측정한 폐기능 정상치)

  • Wee, Young Sun;Kim, Hyoung Yun;Jung, Da Wun;Park, Hye Won;Shin, Yoon Ho;Han, Man Yong
    • Clinical and Experimental Pediatrics
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    • v.50 no.9
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    • pp.862-867
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    • 2007
  • Purpose : The impulse oscillometry (IOS) is applicable to young children because it requires minimal cooperation and a non-invasive method to measure the mechanics of respiratory system. This study aimed to develop the reference values in school-aged children in Korea, using IOS which is a modification of forced oscillation technique (FOT). Methods : Measurements were performed in 92 previously untrained healthy children, aged 7 to 12 years old, using IOS. We analyzed the relationships between the data about their age, height, weight, body surface area (BSA), body mass index (BMI) and the result of IOS using the linear regression test. Results : The success rate of IOS was 92.4%. Stepwise multiple regression of resistance of respiratory system (Rrs) and reactance of respiratory system (Xrs) in natural form for age, height, weight, BSA, BMI showed that height was the most significant predictor and altogether of 5 variables explained the Rrs and Xrs most. Our regression equations at multiple frequencys were comparable to published reference values, especially about the Rrs obtained at 5 Hz. Conclusion : IOS is a feasible method to measure the respiratory resistance in untrained children. We got the reference values using IOS and it seems to be useful to diagnose a variety of respiratory diseases.