• Elastomers and Composites
• /
• v.44 no.4
• /
• pp.455-465
• /
• 2009

In this study, Organo-montmorillonite(MMT) was synthesized by intercalation of various amine(Octylamine, Dodecylamine, Dimethyldodecylamine, Octadecylamine) compounds into layered silicate. Natural Rubber(NR)/MMT nanocomposites were prepared by reinforcement of Organo-MMT. X-ray diffraction(XRD) and Scanning electron microscope(SEM) were employed to characterize the layer distance of Organo-MMT and the morphology of the NR/MMT nanocomposites. The structures of the synthesized Organo-MMTs were analyzed by the measurement of FT-IR. Cure characteristics, surface free energy and mechanical properties such as tensile strength, modulus and hardness of NR/MMT nanocomposites were carefully studied by contact angle meter, ODR, UTM, and hardness tester. FT-IR analysis showed a insertion of the alkyl and amine chains into the interlayers of the MMT. It was shown that the cure time of the organo-MMT was more decreased than that of $Na^+$-MMT. Surface free energy and tensile strength of the NR/DDA-MMT nanocomposite were the highest. NR/ODA-MMT nanocomposite was the highest in hardness.

• Polymer(Korea)
• /
• v.24 no.3
• /
• pp.326-332
• /
• 2000

The effects of sizing agent on the final mechanical properties of the glass fiber/unsaturated polyester composites were investigated by contact angle measurements at room temperature. In this work, glass fibers were coated by poly(vinyl alcohol), polyester, and epoxy type sizing agent and each property was compared. Contact angles of the sized glass fiber were measured by the wicking method based on Washburn equation using deionized water and diiodomethane as testing liquids. As an experimental result, the surface free energy calculated from contact angle showed the highest value in case of the glass fiber coated by epoxy sizing agent. From measurements of interlaminar shear strength (ILSS) and fracture toughness ( $K_{IC}$ ) of the composites, it was found that the sizing treatment on fibers could improve the fiber/matrix interfacial adhesion, resulting in growing the final mechanical properties. This was due to the enhanced surface free energy of glass fibers in a composite system.

• Korean Journal of Metals and Materials
• /
• v.46 no.9
• /
• pp.572-576
• /
• 2008

Elastostatic compression tests were carried out on amorphous alloys to evaluate their energy absorption capability during homogeneous deformation at room temperature. Experiments demonstrated that a compressive stress below the global yield imposed on amorphous alloys for extended periods causes homogeneous plastic strain associated with the irreversible structural disordering. During the disordering process, free volume was created, dissipating the externally applied strain energy and the rate of creation was found to converge to a saturated value. We evaluated the capability of energy absorption of amorphous alloys during homogeneous deformation using recent theories on the evolution of the structural state.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.61-61
• /
• 2011

Using ab initio calculations, we study the MgO(001) and Fe/MgO(001) surface phases and the effects of interface structure on the Fe/MgO magnetic anisotropy. The surface phase diagrams of MgO(001) and Fe/MgO(001) show that the most stable surface structures are either defect-free surface or the surfaces with oxygen vacancies in c($2{\times}1$) periodicity for the systems. By the formations of the oxygen vacancy rows on MgO(001) surface, the in-plane magnetic anisotropy energy of Fe overlayer is reduced while the perpendicular magnetic anisotropy energy is increased from 0.1 to 0.5 meV per Fe atom.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2005.07a
• /
• pp.254-255
• /
• 2005

In this work, the effects of plasma treatment on surface properties of semi conductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, semiconductive silicone rubber surfaces treated with plasma discharge led to and increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. these results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semi conductive silicone rubber.

• Structural Engineering and Mechanics
• /
• v.76 no.1
• /
• pp.141-151
• /
• 2020

This manuscript tends to investigate influences of nanoscale and surface energy on a static bending and free vibration of piezoelectric perforated nanobeam structural element, for the first time. Nonlocal differential elasticity theory of Eringen is manipulated to depict the long-range atoms interactions, by imposing length scale parameter. Surface energy dominated in nanoscale structure, is included in the proposed model by using Gurtin-Murdoch model. The coupling effect between nonlocal elasticity and surface energy is included in the proposed model. Constitutive and governing equations of nonlocal-surface perforated Euler-Bernoulli nanobeam are derived by Hamilton's principle. The distribution of electric potential for the piezoelectric nanobeam model is assumed to vary as a combination of a cosine and linear variation, which satisfies the Maxwell's equation. The proposed model is solved numerically by using the finite-element method (FEM). The present model is validated by comparing the obtained results with previously published works. The detailed parametric study is presented to examine effects of the number of holes, perforation size, nonlocal parameter, surface energy, boundary conditions, and external electric voltage on the electro-mechanical behaviors of piezoelectric perforated nanobeams. It is found that the effect of surface stresses becomes more significant as the thickness decreases in the range of nanometers. The effect of number of holes becomes significant in the region 0.2 ≤ α ≤ 0.8. The current model can be used in design of perforated nano-electro-mechanical systems (PNEMS).

• Journal of Wetlands Research
• /
• v.23 no.3
• /
• pp.234-241
• /
• 2021

This paper contributes to the understanding of the effect of pulley on the performance of the vortex turbine in free water surface. The experimental work was to analyze the rotation, voltage and current of the turbine due to physical factors (vortex height, velocity, effective head, etc.) at flow rates ranging from 0.0069 to 0.0077 m³/s in the inlet channel. As a result, the experimental values showed that voltage, current and rotational speed of the vortex turbine decreased with increasing the pulley ratio regardless of the blade type. The efficiency of straight blade and twisted blade was 52 % at the gear ratio of 0.45, whereas the efficiency of small twisted blade was 54 % at the pulley ratio of 0.21. The highest amount of the energy generated by the water free vortex turbine occurred within a pulley ratio of 0.5. The efficiency of this vortex turbine was observed at 0.2 ~ 58 % depending on the pulley ratio.

• Journal of Wetlands Research
• /
• v.24 no.3
• /
• pp.196-203
• /
• 2022

This paper contributed to the understanding of the effect of the blade relative position on performance of micro gravitational vortex turbine in free water surface. In a constant vortex flow, the rotation, voltage and current of micro vortex water turbine were measured according to the position change of the blade installed at the relative vortex height (y/h_v) ranging from 0 to 0.778 below the free water surface. The flow rate ranged from 0.0063 to 0.00662 m³/s. The results of the experiments showed that relative positions of the blade affected the performance of vortex water turbine because the distributions of incoming flow velocity and turbulence intensity were changed. The highest amount of the energy generated by the vortex water turbine occurred in the relative vortex height ranging from 0.111 to 0.222. The output power at the relative vortex height of 0.111 was about 2.4 times larger than the relative vortex height of 0.588 below the free water surface.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.6
• /
• pp.794-799
• /
• 2011

In order to reduce the oil consumption for a 2 stroke free piston hydrogen fueled engine, the behaviors of residual lubricant oil of the cylinder wall surface were visualized and oil mass emitted into exhaust port was measured by using research engine with cross-head and eccentric crankshaft. As the results, it was shown that characteristics of residual lubricant oil such as oil thickness and distribution were remarkably different from a conventional 4 stroke engine. It was also analyzed that these tendencies relied on the configuration and installed position of the exhaust port, piston pin boss and so on.

• Applied Chemistry for Engineering
• /
• v.34 no.4
• /
• pp.365-382
• /
• 2023

A lithium metal anode with high energy density has the potential to revolutionize the field of energy storage systems (ESS) and electric vehicles (EVs) that utilize rechargeable lithium-based batteries. However, the formation of lithium dendrites during cycling reduces the performance of the battery while posing a significant safety risk. In this review, we discuss various strategies for achieving dendrite-free lithium metal anodes, including electrode surface modification, the use of electrolyte additives, and the implementation of protective layers. We analyze the advantages and limitations of each strategy, and provide a critical evaluation of the current state of the art. We also highlight the challenges and opportunities for further research and development in this field. This review aims to provide a comprehensive overview of the different approaches to achieving dendrite-free lithium metal anodes, and to guide future research toward the development of safer and more efficient lithium metal anodes.