• Title/Summary/Keyword: Surface color change

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Degradation of Lead-based Pigments by Atmospheric Environment (납계열 안료의 대기환경에 따른 열화특성)

  • Park, Ju Hyun;Lee, Sun Myung;Kim, Myoung Nam
    • Economic and Environmental Geology
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    • v.55 no.3
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    • pp.281-293
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    • 2022
  • We examined degradation characteristics of lead based pigments(white lead, Red lead, Litharge) according to atmospheric environmet condition, for example atmospheric gas(CO2, NO2) and soluble salt. Painted samples not changed material compositions but were occured the color change(𝚫E 4~31) after exposed UV irradiation. All sample were not affected by CO2 gas not only color but chemical composition. However, samples were remakably changed color exposed NO2 gas and it was formed secondary product like as lead nitrate. Such as red lead and white lead samples' color difference were 𝚫E 2 and 𝚫 10 respectively and became dark, along with litharge became bright and color difference was 𝚫E 5 after react with NO2 gas. It confirm that NO2 was influential factor than CO2 in the case of same concentration. Furthermore salt spray test was taken to figure out soluble salt influence in fine dust. The result showed noticeable color change and secondary product was formed on samples' surface. The glue film peeled off or hole, and color changed around the secondary products. After salt spray, XRD pattern showed decrease peak intensity and lower crystalinity. As a result of salt spray test, white lead was formed new product litharge and litharge was formed litharge and minium. According to the results, influential atmospheric factors for conservation of paint pigments were UV, NO2, soluble salt, and litharge was most weakness throughout lead base pigments.

Water utilities vulnerability assessment and adaption strategies for climate change in Jeju province (제주도 기후변화 관련 상수도시설 취약성 평가 및 적응대책)

  • Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.6
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    • pp.517-526
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    • 2018
  • Climate adaptation strategies for water utilities including 16 water treatment plants(WTPs) in Jeju were investigated. Drought, heat wave, and heavy rain were among the most significant climate factors affecting water utilities in Jeju. Heat wave increases water temperature, which in turn increases the concentration of algae, color, and odor materials. Some adaption strategies for the heat wave can be strengthening water monitoring and introducing advanced water treatments. Heavy rain increases raw water turbidity in surface water. The 7 WTPs that take raw water from streams or springs had a maximum turbidity of less than 50 NTU under heavy rain. However, due to concerns of turbidity spike in treated water, some WTPs discontinued intaking raw water when raw water turbidity increased more than 2 NTU. They instead received treated water from other WTPs which took groundwater for water supply. This happens because of the low skills of employees. Thus, there needs to be an increase in operator competency and upgrade of water facilities for the adaption of heavy rain. To improve adaption for the drought, there should be an increase in the capacity of intake facilities of surface water as well as a decrease in water loss. In addition, water consumption per person should be decreased.

Changes of tooth color in adults by aging (증령에 따른 치아색조 변화)

  • Lee, Jung-Jun;Kim, Kil-Su;Min, Kwan-Sik;Ahn, Seung-Geun;Park, Chan-Woon
    • Journal of Dental Rehabilitation and Applied Science
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    • v.19 no.2
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    • pp.69-74
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    • 2003
  • The purpose of this study was to obtain the color change information for natural tooth of all age groups. Fifty Korean subjects(25 men and 25 women) were randomly selected for this study. They were ranged in age from 24 to 67 years old and were classified into 5 age groups for each sex: 20 to 29, 30 to 39, 40 to 49, 50 to 59, 60 to 69 years. Maxillary central incisor of each subject free from obvious discoloration and restorations on the sites to be measured was selected. Three sites on the labial surface, incisal, middle, cervical area were measured and a circular area of 1.0mm in diameter was measured at each site by the spectrophotometer. The obtained results of this study were as follows: 1) Natural tooth color showed a significant decrease in linghtness($L^*$) at the cervical site(P<0.05). 2) Red/green chromaticity($a^*$) showed a significant increase at all sites(P<0.01). But it was not enough to have a statistic significance among three sites by aging. 3) Yellow/blue chromaticity($b^*$) showed an increase at all sites(P<0.05). But it didn't change significantly among three sites by aging.

Fabrication of High-Performance Colorimetric Fiber-Type Sensors for Hydrogen Sulfide Detection (황화수소 가스 감지를 위한 고성능 변색성 섬유형 센서의 제작 및 개발)

  • Jeong, Dong Hyuk;Maeng, Bohee;Lee, Junyeop;Cho, Sung Been;An, Hee Kyung;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.31 no.3
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    • pp.168-174
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    • 2022
  • Hydrogen sulfide(H2S) gas is a high-risk gas that can cause suffocation or death in severe cases, depending on the concentration of exposure. Various studies to detect this gas are still in progress. In this study, we demonstrate a colorimetric sensor that can detect H2S gas using its direct color change. The proposed nanofiber sensor containing a dye material named Lead(II) acetate, which changes its color according to H2S gas reaction, is fabricated by electrospinning. The performance of this sensor is evaluated by measuring RGB changes, ΔE value, and gas selectivity. It has a ΔE value of 5.75 × 10-3 ΔE/s·ppm, showing improved sensitivity up to 1.4 times that of the existing H2S color change detection sensor, which is a result of the large surface area of the nanofibers. The selectivity for H2S gas is confirmed to be an excellent value of almost 70 %.

Use of Freshness Indicator for Determination of Freshness and Quality Change of Chicken during Storage (신선도표시계를 이용한 계육의 저장 중 신선도 측정 및 품질변화)

  • Shin, Hee-Young;Ku, Kyoung-Ju;Park, Sang-Kyu;Song, Kyung-Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.6
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    • pp.761-767
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    • 2006
  • To determine freshness and quality change of chicken products during storage, we manufactured freshness indicator and monitored the surface pH, volatile basic nitrogen (VBN), thiobarbituric acid reacted substance (TBARS), total bacterial counts, electronic nose analysis, and sensory evaluation. All chicken products (drum, wing, thigh) had a change in color of freshness indicator after storage of 3 days at $4^{\circ}C$, indicating poor quality at the time. VBN, TBARS values, and total bacterial counts reached the decay point at the time of color change of freshness indicator attached to the surface of chicken samples. The sensory evaluation also indicated sample was not acceptable by off-odor at day 4 of storage. According to electronic nose analysis to examine off-odor, there were significant differences in terms of principal component analysis values among chicken samples of day 0, day 3, and day 5 of storage. These results suggest that freshness indicator should be useful in determining expiration date of chicken products during marketing by indicating the microbial safety as well as physicochemical and sensory change.

A Study of Aging Characteristic of EPDM by High-temperature Treatment (고온 열처리에 의한 EPDM의 열화 특성에 대한 연구)

  • Choi, N.H.;Han, S.I.;Han, S.O.;Yoon, J.Y.;Park, K.S.;Kim, J.S.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1465-1468
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    • 1997
  • In this study we investigated the aging characteristic such as leakage current, dielectric loss, contact angle, of EPDM for outdoor use by thermal treatment. And also observed the color change of surface, changing of chemical ingredient of the marterials by optical microscope. SEMI, FTIR and EDX at the section and surface. The test result show that leakage current is increased with thermal aging time. contact angle and dielectric loss is slightly decreased. Moreover, micro-void or crack in bulk is severely increased with aging time. However, the result affect to the tan $\delta$ at bulk of EPDM. It seems that carrier sources are removed by degassing with heat treatment.

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Electrohemical and optical properties of Ta$_2$O$_5$ thin film electrolyte EC windows (Ta$_2$O$_5$ 박막전해질 EC 창의 전기화학 및 광학적 특성에 관한 연구)

  • 김용혁;백지흠;조원일;윤경석;박인철;주재백
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.231-238
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    • 1997
  • Tantalum oxide thin filme has an amorphous structure and a high resistivity. Its stoichiometric structure was $Ta_2O_{5.3}$ and the transmission ratio was 80%. The high resistivity of $Ta_2O_{5.3}$ thin film electrolyte made an EC windows without electrical shottness, but the bleached/colored cur rent was very low because of the low ion conductivith. Upon adding moisture into the system, the $\Delta$T increased upto 25 %. proton concentration increase was the main cases to improve optical property. The influence of adding precious or transition metal film(~100 $\AA$ thickness) in $Ta_2O_5$layer on the color change performance was observed. The metal insertion layers had formed hydroxide and they behaved as a stable proton source. The transmission diffrnece and cycle life were greatly enhanced in the case of Ti inssertion.The $\Delta$T was 50% and the cycle life was 18, 000.

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Surface Modification of Ag Coated Cu Conductive Metal Powder for Conductive Silicone Sealant Gasket Paste

  • Park, Seong-Yong;Yoon, Tae-Won;Lee, Chung-Ho;Jeong, In-Bum;Hyun, Sang-Hoon
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1076-1077
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    • 2006
  • Conductive pastes consist of conductive fillers( Au, Ag, Ni, Cu etc.), organic binders, solvents and additives. Meanwhile, there are some metal powders such as copper, nickel etc that are used for pastes which have serious surface corrosion problems. This problem leads to change of the color and decrease in conductivity and affect storage stability of conductive pastes. By using silane coupling agent and dispersion agent, we can ensure both the corrosion stability and long term storage stability, and enhance the high performance electrical and mechanical properties of EMI shielding silicone sealant.

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Process condition and color change of coatings by dc magnetron sputtering (DC magnetron sputtering을 이용한 착색 코팅의 색상변화와 공정조건에 대한 연구)

  • Song, Yeong-Sik;Gang, Yeong-Hun;Kim, Jong-Ryeol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.53-53
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    • 2008
  • 기존의 Al 합금 소재의 단점을 보완한 Al-Mg 합금 소재를 이용해 다이캐스팅으로 만들어진 핸드폰 케이스에 적용하고자 titanium 타겟을 사용한 반응성 스퍼터링 공정을 연구하였다. 코팅특성은 스펙트로포토 미터를 이용하여 색상분석을 하였고, 미세표면이미지는 FE-SEM을 이용하였다. DC 마그네트론 스퍼터링에 의한 착색코팅은 산소유량이 많은 경우 밝기 L*값이 더 커졌다. 색상의 편차와 재현성을 나타내주는 ${\Delta}E^*ab$ 값을 비교해보면, 모든 경우 ${\Delta}E^*ab^*$<1로 매우 우수한 색상균일성을 보여준다. FE-SEM에 의한 표면이미지는 전반적으로 산소유량이 많은 0.8SCCM에서 코팅한 경우보다 산소유량이 적은 0.375SCCM에서 코팅한 경우가 결정립계의 구별이 확실하고 결정립 모양이 선명하고 결정립크기도 증가함을 확인할 수 있다.

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Development of a High Value Added Knit Structure for Middle-aged Women (중년여성을 위한 고부가가치 니트 조직 개발)

  • Lee, Insuk;Kim, Jiyoung
    • Journal of Fashion Business
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    • v.18 no.2
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    • pp.148-165
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    • 2014
  • The purpose of this study is to establish a theory about the necessary structure for knitwear design, and to propose it with the practical data through the actual development of a high value added knit structure. For this study, the market was conducted along with literature reviews on the existing studies and the relevant books about knit structures. The market research aimed at the products released in the spring/summer and fall/winter seasons of 2012-2013, focusing on brand for middle aged women. The utilization of the structure by item and the characteristics of knit design were studied. The research was conducted on S/S products in May and July, and F/W products in October and December. As a result of the market research, it was shown that the lightweight structures with permeability such as plain, lace, links and links, this is repeated and rib structure were frequently utilized during the S/S season, while double structures with good shape stability were greatly utilized during the F/W season. Also, during the F/W season, a cable structure and tubular jacquard that emphasized the volume or cubic effect were frequently used, and there were many jacquard structures where a change of color sense and motive were added. Concerning the knit structures development, the researcher designed the knit structure at the actual production site of the knit fashion. A total of 5 pieces of knit structures were developed by asking a professional for programming and knitting. To the developed structures, the study added a multi-gauged effect, herringbone transformation effect, 3-dimensional surface effect, color effects, geometric patterns, lace penetration effect, and soft surface effect in a water-drop shape. In addition, the structures had differences in the added values by mixing various structures and diversely expressing color sense on the knitting line. This study proposes the direction for 21st century knitwear product design, through the development of a high value added knit structure.