• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.54-63
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• 1993

Some emulsified 1, 2-disubstituted imidazolinium salts were synthesized by quaternization of 1, 2-disubstituted imidazoline which had been prepared by the reaction of dodecanoic acid with tetraethylenepentamine. 2-Docosamido-2'-docosanoyloxydiethylamine was prepared by the reaction of docosanoic acid with hydroxylethylethylenediamine. Then, some emulsified fatty carbamide salts were also synthesized by quaternization of fatty carbamide which had been prepared by the reaction of urea with the 2-docosamido-2'-docosanoyloxydiethylamine. Some softners were prepared by blending of these salts mentioned above. These softners were treated on acrylic fiber, then several properties were measured. As the results, softening and lubricating properties are good and a little antistatic property was observed. The synthesized softners were also proved as a durable softner by means of the several experiments : bending resistance test and measurements of feeling change with washing according to the pH changes. The surface structure of acrylic fibers treated with the softner were characterized by SEM.

• Korean Journal of Materials Research
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• v.30 no.8
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• pp.426-434
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• 2020

The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO₃·4H₂O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

• Journal of Welding and Joining
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• v.32 no.2
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• pp.48-53
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• 2014

This study was carried out to investigate the effect of postweld heat treatment(PWHT, 930, 1080, $1230^{\circ}C$) on the microstructure, phase formation, pitting corrosion and mechanical properties such as hardness, tensile strength and impact values of super duplex stainless steel(UNS S32750) multipass welds. Based on the microstructural examination and X-ray diffraction analysis, it was found that the ${\sigma}$ phase was formed in the welds heat treated at $930^{\circ}C$ in which the ferrite content greatly decreased into 5~10% in the welds. The secondary austenite was formed in the reheated zone of welds and redissolved into ferrite with increasing heat treatment temperatures. The tensile strength and impact values of welds heat treated at $930^{\circ}C$ were the lowest and revealed the brittle fracture surface. The weight loss by pitting corrosion increased with test temperatures. It was confirmed that pitting corrosion occurred mainly in secondary austenite of reheated zones. The postweld heat treatment temperature is recommended to be in the range of $1050{\sim}1150^{\circ}C$.

• Fire Science and Engineering
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• v.28 no.2
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• pp.76-81
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• 2014

Structural stability of structural beams at high temperature had been evaluated though a horizontal furnace and a standard fire curve. If a structural method and a material are satisfied with the fire test, those are seemed to be guaranteed the safety of residences, fire services men, and properties of the buildings. However, that requires not only longer period but higher cost for making and testing of each structural element. That restrained from developing new methods and new fire protective materials. In this study, an analytic method was executed to demonstrate whether the analytic method using mechanical properties of structural steel at high temperature with heat transfer theory works is working. In this paper, the surface temperature rising and variance of structural stability of a simple H-section beam with a standard fire curve were evaluated and structural stabilities of H-section beam according to differences from length of beam were suggested.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.101-104
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• 2008

The cost of repairing the deterioration of concrete structures due to corrosion of the reinforcement steel has been the prominent figure in the maintenacne of the reinforced-concrete infrastructures. As an alternative material to steel reinforcement, the use of Fiber Reinforced Polymer (FRP) bar in concrete is being actively studied for the high resistance of chemical environment and high strength to weight ratio properties of FRP. However, there remain various aspects of FRP properties that still need to be studied before the standard design criteria can be established. One of the imminent issues is the bond between FRP and concrete. In this study, the bond-behavior of FRP bars in concrete is investigated via the pullout test with three varying parameters: surface condition of FRP bars, concrete compression strength, and cyclic loading patterns. As a result of experiment, the bond strength of GFRP increased with the concrete compression strength increasing and decreased with applying cyclic load.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.569-578
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• 2011

The $SiO_2$ membranes for polymer electrolyte membrane fuel cell (PEMFC) are preapared by electrospinning method. It leads to high porosity and surface area of membrane to accommodate the proton conducting materials. The composite membrane was prepared by impregnating of Nafion ionomer into the pores of electrospun $SiO_2$ membranes. The $SiO_2$:heteropolyacid (HPA) nano-particles as a inorganic proton conductor were prepared by microemulsion process and the particles are added to the Nafion ionomer. The characterization of the membranes was confirmed by field emission scanning electron microscope (FE-SEM), thermogravimetry analysis (TGA), and single cell performance test for PEMFC. The Nafion impregnated electrospun $SiO_2$ membrane showed good thermal stability, satisfactory mechanical properties and high proton conductivity. The addition of the $SiO_2$:HPA nano-particle improved proton conductivity of the composite membrane, which allow further extension for operation temperature in low humidity environments. The composite membrane exhibited a promising properties for the application in high temperature PEMFC.

• Korean journal of applied entomology
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• v.31 no.2
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• pp.182-189
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• 1992

The influnces of 9 kinds of solvents on the toxicities against several insect species, phytotoxicity and solubility of compounds were evaluated by means of leaf dipping and spray methods. In case of the spray application, density and vapor pressure seemed to be a contributing factor to lethal toxicity against brown planthopper and diamond-back moth, respectively; the bigger the property of density and the smaller the vapor pressure gave the stronger toxicity. It appeared that the toxicity of solvents was not correlated with anyone of physical properties such as boiling point, dipole moment, dielectric constant, surface tension and viscosity. Spray treatment gave more toxicity to insects than leaf dipping treatment. Although dielectric constant and dipole moment seemed to be contributing factors to phytotoxic damage to rice seedling and bean plants, respectively, no general correlation between phytoxicity and the other physical properties was found. Leaf dipping application caused stronger phytotoxicity than spray application. It is concluded that 5% acetone solution may be most suitable to test chemicals because of its favorable solubility of compounds, lower toxicity to insects, and lower phytotoxicity.

• Food Science and Preservation
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• v.10 no.4
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• pp.574-583
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• 2003

There have been a lot of research efforts on development of active food packaging structures and materials in the form of plastic films and containers, along with investigating novel polymers and bioactive compounds for packaging purpose, in order to improve storage stability and safety of foods during distribution and sale. Recently, great interests focus on antimicrobial package films, as an active packaging system, made from synthetic plastic polymer% and natural biopolymers containing various antimicrobial substances for food packaging applications. In this active system, substances are slowly released onto the food surface. However, antimicrobial activity as well as physical properties of the films can be significantly influenced by several factors such as polymer matrix, antimicrobial compounds, and interactions between polymers and compounds. Thus, this study reviews present status of antimicrobial food packaging films in overall performance aspects including types of polymers and active substances, test for antimicrobial activity, and changes in mechanical and antimicrobial properties by preparation method.

• Polymer(Korea)
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• v.37 no.6
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• pp.677-684
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• 2013

Zinc alginate films were prepared by a film maker from sodium alginate solutions of different weight ratios and then they solidified into 3 wt% content $ZnCl_2$ coagulation solution and washed and dried at a $60^{\circ}C$ oven for 20 min. The characteristics were measured by several methods (antimicrobial activity, viscosity, FTIR, TGA, SEM, EDS, contact angle, tensile strength and solubility) and the film properties were investigated. The antimicrobial test showed that the zinc alginate films result in excellent antimicrobial activity in the two strains (Klebsiella pneumonia, Staphylococcus). The surface of zinc alginate film from the solution of 9 wt% sodium alginate showed more uniform shape than any other films and the cross-section were hard and rough when the films were well-solidified by the $ZnCl_2$ solution. The tensile strength of zinc alginate films increased along with the concentration of sodium alginate solution due to the cross-linking, and the initial thermal decomposition temperature increased gradually.

• Korean Journal of Materials Research
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• v.18 no.1
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• pp.32-37
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• 2008

The electrical, optical, structural and surface properties of an indium tin oxide (ITO) film grown on a flexible PET substrate using a specially designed roll-to-roll (R2R) sputtering system as a function of the DC power, $Ar/O_2$ flow ratio, and rolling speed is reported. It was observed that both the electrical and optical properties of the ITO film on the PET substrate were critically dependent on the $Ar/O_2$ flow ratio. In addition, x-ray diffraction examination results showed that the structure of the ITO film on the PET substrate was an amorphous structure regardless of the DC power and the $Ar/O_2$ flow ratio due to a low substrate temperature, which was maintained constant by a main cooling drum. Under optimized conditions, ITO film with resistivity of $6.44{\times}10^{-4}{\Omega}-cm$ and transparency of 86% were obtained, even when prepared at room temperature. Furthermore, bending test results exhibited that R2R-grown ITO film had good flexibility which would be applicable to flexible displays and solar cells.