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Application of Layered Perovskites Substituted with Co and Ti as Electrodes in SOFCs (Co 및 Ti가 치환된 Layered perovskite의 SOFC 전극에 대한 적용성 연구)

  • Kim, Chan Gyu;Shin, Tae Ho;Nam, Jung Hyun;Kim, Jung Hyun
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.40-49
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    • 2022
  • In this study, the phase and electrochemical properties of Co and Ti substituted layered perovskites SmBaCo2-xTixO5+d (x=0.5, 0.7, 1.0, 1.1, 1.3, and 1.5) were analyzed, and their application as electrodes in solid oxide fuel cells (SOFCs) were evaluated. After calcination at 1300℃ for 6 h, a single phase was observed for two compositions of the SmBaCo2-xTixO5+d oxide system, SmBaCoTiO5+d (x=1.0) and SmBaCo0.9Ti1.1O5+d (x=1.1). However, the phases of SmBaCoTiO5+d (SBCTO) and SmTiO3 coexisted for compositions with x≥1.3 (Ti content). In contrast, for compositions of x≤0.7, the SmBaCo2O5+d phase was observed instead of the SmTiO3 phase. To evaluate the applicability of these materials as SOFC electrodes, the electrical conductivities were measured under various atmospheres (air, N2, and H2). SBCTO exhibited stable semi-conductor electrical conductivity behavior in an air and N2 atmosphere. However, SBCTO showed insulator behavior at temperatures above 600℃ in a H2 atmosphere. Therefore, SBCTO may only be used as cathode materials. Moreover, SBCTO had an area specific resistance (ASR) value of 0.140 Ω·cm2 at 750℃.

Low Temperature Sintering of Lead-Free Bi1/2Na1/2TiO3-SrTiO3 Piezoceramics by Li2CO3-B2O3 Addition (Li2CO3와 B2O3를 첨가한 Bi1/2Na1/2TiO3-SrTiO3 무연 압전 세라믹스의 저온 소성 연구)

  • Lee, Sang Sub;Park, Young-Seok;Duong, Trang An;Devita, Mukhlishah Aisyah;Han, Hyoung-Su;Lee, Jae-Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.1
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    • pp.24-31
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    • 2022
  • This study investigated microstructures, crystal structures, polarization, dielectric and electromechanical properties of 0.76Bi1/2Na1/2TiO3-0.24SrTiO3 (BNT-24ST)-based piezoceramcs by adding Li2CO3 and B2O3 (LB) as sintering aids for low-temperature sintering. All samples were successfully synthesized using conventional solid-state reaction method and sintered at 950, 1,000, 1,050, 1,100 and 1,175℃ for 2 hours. Without LB, specimens required sintering temperatures over 1,175℃ for sufficient densification, while the addition of 0.10-mol LB decreased the sintering temperatures down to 950℃. The average grain size and dielectric properties of BNT-24ST-10LB ceramics were enhanced with increasing sintering temperature. We found that the low-temperature sintered BNT-24ST piezoceramics by adding LB showed the d33*value of 402 pm/V at 4 kV/mm after sintering at 1,050℃, which was better than that of high-temperature fired specimens sintered at 1,175℃ without LB (242 pm/V). We believe that the results of this study promise a candidate for low-cost multilayer ceramic actuator applications.

Roles for α1-adrenoceptors during contractions by electrical field stimulation in mouse vas deferens

  • Alsufyani, Hadeel A.;Docherty, James R.
    • The Korean Journal of Physiology and Pharmacology
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    • v.25 no.6
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    • pp.525-532
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    • 2021
  • We have investigated the relative roles of α1-adrenoceptors and purinoceptors in contractions to low and high frequency stimulation of the mouse vas deferens, in terms of the time course of responses. In separate experiments, isometric contractile responses were obtained to 10 pulses at 1 Hz and 40 pulses at 10 Hz. Responses to 1 Hz stimulation consisted of a series of discrete peaks. The α1A-adrenoceptor antagonist RS100329 (10-9M-10-7M) significantly reduced the response to the first pulse, the α1D-adrenoceptor antagonist BMY7378 (10-7M-10-6M) significantly reduced the response to the first two pulses, and the non-selective α1-adrenoceptor antagonist prazosin (10-8M) reduced the response to the first 4 pulses at 1 Hz. Responses to 10 Hz stimulation consisted of an early peak response and a maintained plateau response. RS100329 significantly reduced the peak response but did not significantly affect the plateau response. Prazosin, significantly reduced both the peak and plateau responses. The α1A-adrenoceptor antagonist RS17053 in high concentrations reduced mainly the plateau response leaving a clear early peak response. The plateau response of contraction was almost abolished by the purinoceptor antagonist suramin. These results suggest that there is a relatively minor early α1D-adrenoceptor and a larger early α1A-adrenoceptor component to stimulationevoked contractions of mouse vas deferens, but the major α1-adrenoceptor component is revealed by prazosin to be α1B-adrenoceptor mediated. α1B-Adrenoceptor activation probably facilitates contractions mediated by other α1-adrenoceptors and by purinoceptors. These results suggest that combined non-selective α1-adrenoceptor blockade, particularly α1B-adrenoceptor blockade, in addition to P2X1-purinoceptor blockade is useful in reducing male fertility.

Characterization and thermophysical properties of Zr0.8Nd0.2O1.9-MgO composite

  • Nandi, Chiranjit;Kaity, Santu;Jain, Dheeraj;Grover, V.;Prakash, Amrit;Behere, P.G.
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.603-610
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    • 2021
  • The major drawback of zirconia-based materials, in view of their applications as targets for minor actinide transmutation, is their poor thermal conductivity. The addition of MgO, which has high thermal conductivity, to zirconia-based materials is expected to improve their thermal conductivity. On these grounds, the present study aims at phase characterization and thermophysical property evaluation of neodymium-substituted zirconia (Zr0.8Nd0.2O1.9; using Nd2O3 as a surrogate for Am2O3) and its composites with MgO. The composite was prepared by a solid-state reaction of Zr0.8Nd0.2O1.9 (synthesized by gel combustion) and commercial MgO powders at 1773 K. Phase characterization was carried out by X-ray diffraction and the microstructural investigation was performed using a scanning electron microscope equipped with energy dispersive spectroscopy. The linear thermal expansion coefficient of Zr0.8Nd0.2O1.9 increases upon composite formation with MgO, which is attributed to a higher thermal expansivity of MgO. Similarly, specific heat also increases with the addition of MgO to Zr0.8Nd0.2O1.9. Thermal conductivity was calculated from measured thermal diffusivity, temperature-dependent density and specific heat values. Thermal conductivity of Zr0.8Nd0.2O1.9-MgO (50 wt%) composite is more than that of typical UO2 fuel, supporting the potential of Zr0.8Nd0.2O1.9-MgO composites as target materials for minor actinides transmutation.

Electrical Characteristics of Piezoelectric Transformer Composition Pb(Sb1/2Nb1/2)-Pb(Ni1/3Nb2/3)O3-Pb(Zr1Ti)O3 Ceramics for Adaptor (Adaptor용 압전트랜스포머조성 Pb(Sb1/2Nb1/2)-Pb(Ni1/3Nb2/3)O3-Pb(Zr1Ti)O3세라믹스의 전기적 특성)

  • 윤광희;오동언;류주현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.6
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    • pp.499-503
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    • 2002
  • In this study, to develop the high power piezoelectric transformer for adaptor, PSN-PNN-PZT system ceramics were formulated as a function of $MnO_2$ addition and its dielectric and piezoelectric characteristics were investigated. Multi-layer piezoelectric transformer using an excellent composition was also fabricated and its electrical properties evaluated. The composition ceramics added to 0.5wt%$MnO_2$ showed the maximum value of $k_p=0.61$ and $Q_m=1.321$. As the output power of piezoelectric transformer is increased, its temperature rise increased. At the fixed 18W output power, the transformer was stably operated.

Thermoluminescence Kinetics of LYGBO Crystal (LYGBO 단결정의 열형광 전자포획준위 인자)

  • Sunghwan, Kim
    • Journal of the Korean Society of Radiology
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    • v.17 no.1
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    • pp.17-23
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    • 2023
  • In this study, the thermoluminescence kinetics of electron trap in Li6Y0.5Gd0.5(BO3)3 (LY0.5G0.5BO) scintillator for neutron detection composed of Li, Gd, and B with a high neutron response cross-section were investigated. The thermoluminescence glow curve of the LY0.5G0.5BO scintillation single crystal was measured and analyzed using the peak shape method, the initial rise method, and the machine learning algorithm to evaluate the physical parameters of the electron trap. The glow curve of the LY0.5G0.5BO scintillation single crystal consisted of a single peak. As a result of analyzing this peak, the activation energy, emission order, and frequency factor of the electron trap were 0.61 eV, 1.1, and 1.7×107 s-1, respectively. In addition, the possibility of thermoluminescence analysis of scintillators using machine learning was confirmed.

On the Metric Dimension of Corona Product of a Graph with K1

  • Mohsen Jannesari
    • Kyungpook Mathematical Journal
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    • v.63 no.1
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    • pp.123-129
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    • 2023
  • For an ordered set W = {w1, w2, . . . , wk} of vertices and a vertex v in a connected graph G, the k-vector r(v|W) = (d(v, w1), d(v, w2), . . . , d(v, wk)) is called the metric representation of v with respect to W, where d(x, y) is the distance between the vertices x and y. A set W is called a resolving set for G if distinct vertices of G have distinct metric representations with respect to W. The minimum cardinality of a resolving set for G is its metric dimension dim(G), and a resolving set of minimum cardinality is a basis of G. The corona product, G ⊙ H of graphs G and H is obtained by taking one copy of G and n(G) copies of H, and by joining each vertex of the ith copy of H to the ith vertex of G. In this paper, we obtain bounds for dim(G ⊙ K1), characterize all graphs G with dim(G ⊙ K1) = dim(G), and prove that dim(G ⊙ K1) = n - 1 if and only if G is the complete graph Kn or the star graph K1,n-1.

Improving Electrochemical Performance of Ni-rich Cathode Using Atomic Layer Deposition with Particle by Particle Coating Method

  • Kim, Dong Wook;Park, DaSom;Ko, Chang Hyun;Shin, Kwangsoo;Lee, Yun-Sung
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.237-245
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    • 2021
  • Atomic layer deposition (ALD) enhances the stability of cathode materials via surface modification. Previous studies have demonstrated that an Ni-rich cathode, such as LiNi0.8Co0.1Mn0.1O2, is a promising candidate owing to its high capacity, but is limited by poor cycle stability. In this study, to enhance the stability of the Ni-rich cathode, synthesized LiNi0.8Co0.1Mn0.1O2 was coated with Al2O3 using ALD. Thus, the surface-modified cathode exhibited enhanced stability by protecting the interface from Ni-O formation during the cycling process. The coated LiNi0.8Co0.1Mn0.1O2 exhibited a capacity of 176 mAh g-1 at 1 C and retained up to 72% of the initial capacity after 100 cycles within a range of 2.8-4.3 V (vs Li/Li+. In contrast, pristine LiNi0.8Co0.1Mn0.1O2 presented only 58% of capacity retention after 100 cycles with an initial capacity of 173 mAh g-1. Improved cyclability may be a result of the ALD coating, which physically protects the electrode by modifying the interface, and prevents degradation by resisting side reactions that result in capacity decay. The electrochemical impedance spectra and structural and morphological analysis performed using electron microscopy and X-ray techniques establish the surface enhancement resulting from the aforementioned strategy.

Estimating the mean number of objects in M/H2/1 model for web service

  • Lee, Yongjin
    • International journal of advanced smart convergence
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    • v.11 no.3
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    • pp.1-6
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    • 2022
  • In this paper, we estimate the mean number of objects in the M/H2/1 model for web service when the mean object size in the M/H2/1 model is equal to that of the M/G/1/PS and M/BP/1 models. To this end, we use the mean object size obtained by assuming that the mean latency of deterministic model is equal to that of M/H2/1, M/G/1/PS, and M/BP/1 models, respectively. Computational experiments show that if the shape parameter of the M/BP/1 model is 1.1 and the system load is greater than 0.35, the mean number of objects in the M/H2/1 model when mean object size of M/H2/1 model is the same as that of M/G/1/PS model is almost equal to the mean number of objects in the M/H2/1 model when the mean object size of M/H2/1 model is the same as that of M/BP/1 model. In addition, as the upper limit of the M/BP/1 model increases, the number of objects in the M/H2/1 model converges to one, which increases latency. These results mean that it is efficient to use small-sized objects in the web service environment.

Determination of vitamin B1 and B3 contents in Korean domestic foods using high performance liquid chromatography (고성능 액체크로마토그래피를 이용한 국내 식품자원의 비타민 B1과 B3 함량 분석)

  • Song-Yee Lee;So-Ra Choi;Eun-Ju Song;Eun-Ju Kim;Hyun-Ah Han
    • Food Science and Preservation
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    • v.30 no.1
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    • pp.98-108
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    • 2023
  • The purpose of this study was to determine the vitamin B1 and B3 contents in 135 Korean domestic foods using high performance liquid chromatography (HPLC). The Standard Reference Material (SRM) 3233 and in-house control (grain, whole wheat and flour mixture) were used for quality control/assurance. As a result, vitamin B1 was only detected in 54 of the 135 foods, ranging from 0.019 mg/100 g to 28.218 mg/100 g. Among the foods tested, the vitamin B1 content was highest in ramen powder (28.218 mg/100 g) and lowest in boiled jjolmyeon (0.019 mg/100 g). In contrast, vitamin B3 was detected in 108 of the 135 foods, ranging from 0.077 mg/100 g to 32.412 mg/100 g. We found that the vitamin B3 content was highest in beef liver (32.412 mg/100 g) and lowest in boiled chicken heart (0.077 mg/100 g). The results of this study will be used as a nutritional database for the update of the Korean food composition table and will hence contribute to improving public health.