• Title/Summary/Keyword: Sub-resonance

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Nondestructive bending Strength Evaluation of Woodceramics Using Resonance Frequency Mode (I) - Carbonizing Temperature -

  • Byeon, Hee-Seop;Ahn, Sang-Yeol;Oh, Seung-Won;Piao, Jin-Ji
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.3
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    • pp.8-14
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    • 2004
  • Nondestructive evaluation (NDE) technique method using a resonance frequency mode was carried out for woodceramics produced at different carbonizing temperatures (600℃, 800℃, 1000℃, 1200℃, 1500℃) at the phenol resin impregnation rate of 70%, for three kinds of species (Pinus densifora, Pinus koraiensis, Larix leptolepis), respectively. There was a poor relationship between density and static bending MOR. However, close correlations were found between dynamic MOEd and static bending MOR, and between static MOEs and MOR. Especially, the correlation coefficient was highest between MOEd and static bending MOR. Therefore, the MOEd using the resonance frequency mode is useful as a NDE method for predicting the MOR of woodceramics produced at different carbonizing temperatures.

^1H NMR Relaxation Study of Molecular Motion in the Paraelectric Phase of (NH4)2Cd2(SO4)3 Single Crystals

  • Lim, Ae-Ran;Jung, Won-Ki
    • Journal of the Korean Magnetic Resonance Society
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    • v.14 no.1
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    • pp.18-27
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    • 2010
  • The NMR spectrum and spin-lattice relaxation times, $T_1$, of the $^{1}H$ nuclei in $(NH_{4})_{2}Cd_{2}(SO_{4})_{3}$ single crystals were obtained. The two minima in $T_1$ in the paraelectric phase are attributed to the reorientational motions of the $NH_{4}^{+}$ groups. The $^{1}H\;T_1$ of the $(NH_{4})_{2}Cd_{2}(SO_{4})_{3}$ crystals can be described with Bloembergen- Purcell-Pound (BPP) theory. The experimental value of $T_1$ can be expressed in terms of an isotropic correlation time ${\tau}_H$ for molecular motions by using the BPP theory, and determine the role of protons in these processes.

Molecular Motions of [N(C2H5)4]+ and [N(CH3)4]+ ions by 1H Nuclear Magnetic Resonance Relaxation in [N(C2H5)4]2CoCl4 and [N(CH3)4]2CoCl4 Single Crystals

  • Yoon, Su-A;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.15 no.2
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    • pp.146-156
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    • 2011
  • The line widths and spin-lattice relaxation times of protons in $[N(C_2H_5)_4]_2CoCl_4$ and $[N(CH_3)_4]_2CoCl_4$ single crystals were investigated in the temperature range 160-400 K. The temperature dependences of the spin-lattice relaxation times are attributed to the molecular motions of the ethyl and methyl groups in the $[N(C_2H_5)_4]^+$ and $[N(CH_3)_4]^+$ ions respectively. The NMR line widths indicate that the ethyl groups in $[N(C_2H_5)_4]_2CoCl_4$ have one more degree of freedom than the methyl groups in $[N(CH_3)_4]_2CoCl_4$. The experimental results are interpreted in terms of the reorientations of the methyl and ethyl groups.

High Resolution 3D Magnetic Resonance Fingerprinting with Hybrid Radial-Interleaved EPI Acquisition for Knee Cartilage T1, T2 Mapping

  • Han, Dongyeob;Hong, Taehwa;Lee, Yonghan;Kim, Dong-Hyun
    • Investigative Magnetic Resonance Imaging
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    • v.25 no.3
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    • pp.141-155
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    • 2021
  • Purpose: To develop a 3D magnetic resonance fingerprinting (MRF) method for application in high resolution knee cartilage PD, T1, T2 mapping. Materials and Methods: A novel 3D acquisition trajectory with golden-angle rotating radial in kxy direction and interleaved echo planar imaging (EPI) acquisition in the kz direction was implemented in the MRF framework. A centric order was applied to the interleaved EPI acquisition to reduce Nyquist ghosting artifact due to field inhomogeneity. For the reconstruction, singular value decomposition (SVD) compression method was used to accelerate reconstruction time and conjugate gradient sensitivity-encoding (CG-SENSE) was performed to overcome low SNR of the high resolution data. Phantom experiments were performed to verify the proposed method. In vivo experiments were performed on 6 healthy volunteers and 2 early osteoarthritis (OA) patients. Results: In the phantom experiments, the T1 and T2 values of the proposed method were in good agreement with the spin-echo references. The results from the in vivo scans showed high quality proton density (PD), T1, T2 map with EPI echo train length (NETL = 4), acceleration factor in through plane (Rz = 5), and number of radial spokes (Nspk = 4). In patients, high T2 values (50-60 ms) were seen in all transverse, sagittal, and coronal views and the damaged cartilage regions were in agreement with the hyper-intensity regions shown on conventional turbo spin-echo (TSE) images. Conclusion: The proposed 3D MRF method can acquire high resolution (0.5 mm3) quantitative maps in practical scan time (~ 7 min and 10 sec) with full coverage of the knee (FOV: 160 × 160 × 120 mm3).

27Al and 87Rb Nuclear Magnetic Resonance Study of the Relaxation Mechanisms of RbAl(CrO4)2·2H2O Single Crystals

  • Kim, Jae Sung;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.16 no.2
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    • pp.111-121
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    • 2012
  • The spin-lattice relaxation times, $T_1$, and spin-spin relaxation times, $T_2$, of the $^{27}Al$ and $^{87}Rb$ nuclei in $RbAl(CrO_4)_2{\cdot}2H_2O$ crystals were investigated. The presence of only one resonance line for the $^{27}Al$ nuclei indicates that the results in a dynamical averaging of the crystal electric field that produces a cubic symmetry field. The changes in the temperature dependence of $T_1$ are related to variations in the symmetry of the octahedra of water molecules surrounding $Al^+$ and $Rb^+$. The $T_1$ values for the $^{27}Al$ and $^{87}Rb$ nuclei are different due to differences in the local environments of these ions. We also compared these $^{27}Al$ and $^{87}Rb$ NMR results with those obtained for $RbAl(CrO_4)_2{\cdot}2H_2O$ crystals. The relaxation mechanisms of $RbAl(XO_4)_2{\cdot}nH_2O$ (X=Cr and S) crystals are characterized by completely different NMR behaviors.

Structural characteristics of [N(CH3)4]2CdCl4 determined by 1H MAS NMR, 13C CP/ MAS NMR, and 14N NMR

  • Lee, Seung Jin;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.19 no.1
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    • pp.18-22
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    • 2015
  • The structural geometry of $[N(CH_3)_4]_2CdCl_4$ in a hexagonal phase is studied by $^1H$ MAS NMR, $^{13}C$ CP/MAS NMR, and $^{14}N$ NMR. The changes in the chemical shifts for $^{13}C$ and $^{14}N$ in the hexagonal phase are explained by the structural geometry. In addition, the temperature dependencies of the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for $^1H$ MAS NMR and $^{13}C$ CP/MAS NMR are measured.

A Review on the RF Coil Designs and Trends for Ultra High Field Magnetic Resonance Imaging

  • Hernandez, Daniel;Kim, Kyoung-Nam
    • Investigative Magnetic Resonance Imaging
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    • v.24 no.3
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    • pp.95-122
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    • 2020
  • In this article, we evaluated the performance of radiofrequency (RF) coils in terms of the signal-to-noise ratio (S/N) and homogeneity of magnetic resonance images when used for ultrahigh-frequency (UHF) 7T magnetic resonance imaging (MRI). High-quality MRI can be obtained when these two basic requirements are met. However, because of the dielectric effect, 7T magnetic resonance imaging still produces essentially a non-uniform magnetic flux (|B1|) density distribution. In general, heterogeneous and homogeneous RF coils may be designed using electromagnetic (EM) modeling. Heterogeneous coils, which are surface coils, are used in consideration of scalability in the |B1| region with a high S/N as multichannel loop coils rather than selecting a single loop. Loop coils are considered state of the art for their simplicity yet effective |B1|-field distribution and intensity. In addition, combining multiple loop coils allows phase arrays (PA). PA coils have gained great interest for use in receiving signals because of parallel imaging (PI) techniques, such as sensitivity encoding (SENSE) and generalized autocalibrating partial parallel acquisition (GRAPPA), which drastically reduce the acquisition time. With the introduction of a parallel transmit coil (pTx) system, a form of transceiver loop arrays has also been proposed. In this article, we discussed the applications and proposed designs of loop coils. RF homogeneous coils for volume imaging include Alderman-Grant resonators, birdcage coils, saddle coils, traveling wave coils, transmission line arrays, composite right-/left-handed arrays, and fusion coils. In this article, we also discussed the basic operation, design, and applications of these coils.

The Effects of Additives on Microstructure and Magnetic Properties of Ni0.8Zn0.2Fe2O2 (첨가제 변화에 따른 Ni0.8Zn0.2Fe2O2 의 미세구조와 자기적 특성)

  • 오영우;이선학;이해연;김현식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.406-411
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    • 2002
  • Ni-Zn ferrite is required to have predominant and stable characteristics in the range of high frequency for the power line communication, so that microstructures and magnetic properties such as power loss and initial permeability in $Ni_{0.8}Zn_{0.2}Fe_2O_4$ were investigated in terms of variable $Bi_2O_3,CaO$ and $V_2O_5$ contents. $Bi_2O_3$ and $V_2O_5$ liquid phase created during sintering process promoted sintering and grain growth but much of the closed pore existed in the grains. The grain size of the specimens with $V_2O_5$ of over 0.5 wt% decreased as the result of "pinning effect"and the resonance frequency increased with CaO of 0.3we%. The high initial permeability of 81.52%, resonance frequency of 17.05 MHz and low power loss of 17,858 kW/$\textrm{m}^3$ were obtained from the samples with $Bi_2O_3$ of 0.5, CaO of 0.3, and $V_2O_5$ of 0.7 wt%.

ESR detection of optically-induced hyperpolarization of nitrogen vacancy centers in diamond

  • An, Min-Gi;Shim, Jeong Hyun;Kim, Kiwoong;Oh, Sangwon;Jeong, Keunhong
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.1
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    • pp.9-15
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    • 2020
  • Nitrogen vacancy center (NV center) in diamond has recently been appeared as a promising candidate for hyperpolarization applications due to its optical pumping property by laser. Optically Detected Magnetic Resonance (ODMR) has been used as a conventional method to obtain the resonance spectrum of NV centers. ODMR, however, has a shortcoming of sensitivity and a limitation of subjects, such that the degree of hyperpolarization can hardly be estimated, and that the spins other than NV centers are invisible. In contrast, Electron Spin Resonance (ESR) spectroscopy is known to proportionally reflect the degree of spin polarization. In this work, we successfully observed the optically-induced hyperpolarization of NV spins in diamond through CW-ESR spectroscopy with an X-band system. All the NV peaks were identified by calculating the eigenvalues of NV spin Hamiltonian. The intensities of NV peaks were enhanced over 240 times after optical pumping. The enhanced peaks corresponding to the transition from |ms=0> to |ms=-1> revealed inverted phases, while other peaks remained in-phase. The optically-induced hyperpolarization on NV spins can be a useful polarization source, leading to 13C nuclear hyperpolarization in diamond.

Fuzzy Control Strategy for Damping Sub-Synchronous Resonance

  • Qader, M.R.
    • Journal of Electrical Engineering and Technology
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    • v.13 no.5
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    • pp.1791-1797
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    • 2018
  • Sub-Synchronous Resonance (SSR) is a phenomenon that harms turbine generator shafts because the phenomenon induces sub-synchronous wavering in the system. In the study presented in this paper, a dynamic resistance bank is used to mitigate the occurrence of sub-synchronous phenomenon. A fuzzy logic controller using rotor speed deviation and its derivative as inputs is implemented to damp sub-synchronous oscillations more efficiently. An eigenvalue technique is used to analyse the stability of the system, and a simulation in MATLAB is conducted, based on the IEEE Second Benchmark, to validate the effectiveness of the proposed method under a 3-phase fault condition at an infinite bus. The time-domain simulation and eigenvalues are used to observe the proposed method's superior ability to damp sub-synchronous oscillation.