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http://dx.doi.org/10.6564/JKMRS.2015.19.1.018

Structural characteristics of [N(CH3)4]2CdCl4 determined by 1H MAS NMR, 13C CP/ MAS NMR, and 14N NMR  

Lee, Seung Jin (Department of Carbon Fusion Engineering, Jeonju University)
Lim, Ae Ran (Department of Science Education, Jeonju University)
Publication Information
Journal of the Korean Magnetic Resonance Society / v.19, no.1, 2015 , pp. 18-22 More about this Journal
Abstract
The structural geometry of $[N(CH_3)_4]_2CdCl_4$ in a hexagonal phase is studied by $^1H$ MAS NMR, $^{13}C$ CP/MAS NMR, and $^{14}N$ NMR. The changes in the chemical shifts for $^{13}C$ and $^{14}N$ in the hexagonal phase are explained by the structural geometry. In addition, the temperature dependencies of the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for $^1H$ MAS NMR and $^{13}C$ CP/MAS NMR are measured.
Keywords
$[N(CH_3)_4]_2CdCl_4$; Magic angle spinning; Static NMR; Nuclear magnetic resonance;
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