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Annealing and In Interlayer Effects on the Photovoltaic Properties of CBD-In2S3/CIGS Solar Cells (열처리와 In 중간층 적용에 의한 CBD-In2S3/CIGS 태양전지의 특성 향상)

  • Kim, Hee-Seop;Kim, Ji-Hye;Shin, Dong-Hyeop;Ahn, Byung-Tae
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.432-438
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    • 2011
  • In this study, chemical bath deposited (CBD) indium sulfide buffer layers were investigated as a possible substitution for the cadmium sulfide buffer layer in CIGS thin film solar cells. The performance of the $In_2S_3$/CIGS solar cell dramatically improved when the films were annealed at $300^{\circ}C$ in inert gas after the buffer layer was grown on the CIGS film. The thickness of the indium sulfide buffer layer was 80 nm, but decreased to 60 nm after annealing. From the X-ray photoelectron spectroscopy it was found that the chemical composition of the layer changed to indium oxide and indium sulfide from the as-deposited indium hydroxide and sulfate states. Furthermore, the overall atomic concentration of the oxygen in the buffer layer decreased because deoxidation occurred during annealing. In addition, an In-thin layer was inserted between the indium sulfide buffer and CIGS in order to modify the $In_2S_3$/CIGS interface. The $In_2S_3$/CIGS solar cell with the In interlayer showed improved photovoltaic properties in the $J_{sc}$ and FF values. Furthermore, the $In_2S_3$/CIGS solar cells showed higher quantum efficiency in the short wavelength region. However, the quantum efficiency in the long wavelength region was still poor due to the thick buffer layer.

High Temperature Creep Properties of Al-Al4C3-Al2O3 Alloy by Mechanical Alloying

  • Han, Chang-Suk;Seo, Han-Byeol
    • Korean Journal of Materials Research
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    • v.26 no.7
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    • pp.370-375
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    • 2016
  • Tensile tests and creep tests were carried out at high temperatures on an Al-$Al_4C_3$ alloy prepared by mechanical alloying technique. The material contains about 2.0% carbon and 0.9% oxygen in mass percent, and the volume fractions of $Al_4C_3$ and $Al_2O_3$ particles are estimated at 7.4 and 1.4%, respectively, from the chemical composition. Minimum creep rate decreased steeply near two critical stresses, ${\sigma}_{cl}$ (the lower critical stress) and ${\sigma}_{cu}$ (the upper critical stress), with decreasing applied stress at temperatures below 723 K. Instantaneous plastic strain was observed in creep tests above a critical stress, ${\sigma}_{ci}$, at each test temperature. ${\sigma}_{cu}$ and ${\sigma}_{ci}$ were fairly close to the 0.2% proof stress obtained by tensile tests at each test temperature. It is thought that ${\sigma}_{cl}$ and ${\sigma}_{cu}$ correspond to the microscopic yield stress and the macroscopic yield stress, respectively. The lower critical stress corresponds to the local yield stress needed for dislocations to move in the soft region within subgrains. The creep strain in the low stress range below 723 K arises mainly from the local deformation of the soft region. The upper critical stress is equivalent to the macroscopic yield stress necessary for dislocations within subgrains or in subboundaries; this stress can extensively move beyond subboundaries under a stress above the critical point to yield a macroscopic deformation. At higher temperatures above 773 K, the influence of the diffusional creep increases and the stress exponent of the creep rate decreases.

Empirical Modeling of the Global Distribution of Magnetosonic Waves with Ambient Plasma Environment using Van Allen Probes

  • Kim, Kyung-Chan
    • Journal of Astronomy and Space Sciences
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    • v.39 no.1
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    • pp.11-22
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    • 2022
  • It is suggested that magnetosonic waves (also known as equatorial noise) can scatter radiation belt electrons in the Earth's magnetosphere. Therefore, it is important to understand the global distribution of these waves between the proton cyclotron frequency and the lower hybrid resonance frequency. In this study, we developed an empirical model for estimating the global distribution of magnetosonic wave amplitudes and wave normal angles. The model is based on the entire mission period (approximately 2012-2019) of observations of Van Allen Probes A and B as a function of the distance from the Earth (denoted by L*), magnetic local time (MLT), magnetic latitude (λ), and geomagnetic activity (denoted by the Kp index). In previous studies the wave distribution inside and outside the plasmasphere were separately investigated and modeled. Our model, on the other hand, identifies the wave distribution along with the ambient plasma environment-defined by the ratio of the plasma frequency (fpe) to the electron cyclotron frequency (fce)-without separately determining the wave distribution according to the plasmapause location. The model results show that, as Kp increases, the dayside wave amplitude in the equatorial region intensifies. It thereby propagates the intense region towards the wider MLT and inward to L* < 4. In contrast, the fpe/fce ratio decreases with increasing Kp for all regions. Nevertheless, the decreasing aspect differs between regions above and below L* = 4. This finding implies that the particle energy and pitch angle that magnetosonic waves can effectively scatter vary depending on the locations and geomagnetic activity. Our model agrees with the statistically observed wave distribution and ambient plasma environment with a coefficient of determination of > 0.9. The model is valid in all MLTs, 2 ≤ L* < 6, |λ| < 20°, and Kp ≤ 6.

Disentangling Evolutionary Pattern and Haplotype Distribution of Starch Synthase III-1 (SSIIIb) in Korean Rice Collection

  • Bhagwat Nawade ;Yong-Jin Park
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.214-214
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    • 2022
  • Soluble starch synthases (SSs) elongate α-glucans from ADP-Glc to the glucan nonreducing ends and play a critical role in synthesizing resistant starch in the rice. A total of 10 SSs isoforms were reported in rice, including granules-bound starch synthase I (GBSSI), GBSSII, starch synthase I (SSI), SSIIa (SSII-3), SSIIb (SSII-2), SSIIc (SSII-1), SSIIIa (SSIII-2), SSIIIb (SSIII-1), SSIVa (SSIV-1), and SSIVb (SSIV-2). SSIII proteins are involved in forming the B chain and elongating cluster filling chains in amylopectin metabolism. The functions of SSIIIb (SSIII-1) are less clear as compared to SSs. Here, we sought to shed light on the genetic diversity profiling of the SSIII-1 gene in 374 rice accessions composed of 54 wild-type accessions and 320 bred cultivars (temperate japonica, indica, tropical japonica, aus, aromatic, and admixture). In total, 17 haplotypes were identified in the SSIII-1 coding region of 320 bred cultivars, while 44 haplotypes were detected from 54 wild-type accessions. The genetic diversity indices revealed the most negative Tajima's D value in the temperate-japonica, followed by the wild type, while Tajima's D values in other ecotypes were positive, indicating balancing selection. Nucleotide diversity in the SSIII-1 region was highest in the wild group (0.0047) while lowest in temperate-japonica. Lower nucleotide diversity in the temperate-japonica is evidenced by the negative Tajima's D and suggested purifying selection. The fixation index (FST) revealed a very high level of gene flow (low FST) between the tropical-japonica and admixture groups (FST=-0.21) followed by admixture and wild groups (-0.04), indica and admixture groups (0.02), while low gene flow with higher FST estimates between the temperate-japonica and aus groups (0.72), tropical-japonica and aromatic groups (0.71), and temperate-japonica and admixture groups (0.52). Taken together, our study offers insights into haplotype diversity and evolutionary fingerprints of SSIII-1. It provides genomic information to increase the resistant starch content of cooked rice.

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Preparation and Characterization of Planar-type Artificial Calamine Powder with a High Aspect Ratio for the Application to Ultraviolet and Blue Band Protection Cosmetics (자외선 및 블루영역 차단 화장품 응용을 위한 박막 판형 인공 칼라민 소재의 합성 및 특성 평가 연구)

  • Lee, Jung-Hwan;Lee, Gun-Sub;Jo, Dong-Hyeon;Hong, Da-Hee;Yu, Jae-Hoon;Gwack, Ji-Yoo;Lee, Hee-Chul
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.3
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    • pp.227-235
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    • 2021
  • In this study, we have prepared pure planar-type ZnO and calamine powder containing both ZnO and Fe2O3 components as a raw material for cosmetics with UV and blue band blocking functions. The planar-type ZnO ceramic powder having a high aspect ratio in the range of 20:1 to 50:1 was synthesized by precipitation method in a zinc acetate and sodium citrate mixed solution with the electrolyte obtained by power generation with a zinc-air battery. The content of Fe2O3 in the artificial calamine ceramic powder could be increased by increasing the amount of iron chloride solution added, and in this case, some of the blue region of visible light and ultraviolet light were remarkably absorbed. When potassium acetate was added, the decomposition of the Zn(OH)42- anion in the solution was promoted to facilitate the growth of ZnO crystal in the form of a barrier wall in the vertical direction on the (0001) plane, which could increase UV absorption by providing more opportunities. By controlling the amount of iron chloride solution and potassium acetate solution added, the composition and shape of the thin film plate-shaped artificial calamine ceramic powder can be optimized, and when applied to cosmetic formulations, the light transmittance of the blue region can be greatly reduced.

Green Generation and Investigation of Optical Properties of Amorphous BaTiO3 by Poling (폴링에 의한 비정질 BaTiO3 박막의 광학적 특성 조사 및 녹색광 발생)

  • Kim, Eung-Soo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.1
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    • pp.39-44
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    • 2020
  • BaTiO3 thin films was deposited on the slide glass by RF sputter. We have investigated the optical properties of BaTiO3 film after corona poling process. The transmission characteristics was very good over 80% in visible region and second order nonlinear optical coefficient depends on the poling conditions. The nonlinear optical coefficient of poled BaTiO3 films was about 1.15pm/V. The relaxation of second order nonlinear optical was remained around 60% of the initial value for a long time. In addition we have observed the green light generation from BaTiO3 films.

Dissolution Properties of K2O-CaO-MgO-SiO2-P2O5 Glasses (K2O-CaO-MgO-SiO2-P2O5계 유리의 제조 및 용출특성)

  • 이용수;윤태민;강원호
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1132-1137
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    • 2003
  • For the application of environment conscious glass-fertilizer, dissolution characteristics of phosphate glass was investigated. In 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/ glass system, the compositions were designed according to variation of CaO & MgO contents, and glass formation region was confirmed. From the glass composition, the confirmed glasses were investigated to figure out thermal and dissolution properties. It was detected that glass transition & softening temperature of the glasses increased with increasing MgO contents. The dissolution properties of the glasses was affected by CaO and MgO content ratio.

SEMICLASSICAL ASYMPTOTICS OF INFINITELY MANY SOLUTIONS FOR THE INFINITE CASE OF A NONLINEAR SCHRÖDINGER EQUATION WITH CRITICAL FREQUENCY

  • Aguas-Barreno, Ariel;Cevallos-Chavez, Jordy;Mayorga-Zambrano, Juan;Medina-Espinosa, Leonardo
    • Bulletin of the Korean Mathematical Society
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    • v.59 no.1
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    • pp.241-263
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    • 2022
  • We consider a nonlinear Schrödinger equation with critical frequency, (P𝜀) : 𝜀2∆v(x) - V(x)v(x) + |v(x)|p-1v(x) = 0, x ∈ ℝN, and v(x) → 0 as |x| → +∞, for the infinite case as described by Byeon and Wang. Critical means that 0 ≤ V ∈ C(ℝN) verifies Ƶ = {V = 0} ≠ ∅. Infinite means that Ƶ = {x0} and that, grossly speaking, the potential V decays at an exponential rate as x → x0. For the semiclassical limit, 𝜀 → 0, the infinite case has a characteristic limit problem, (Pinf) : ∆u(x)-P(x)u(x) + |u(x)|p-1u(x) = 0, x ∈ Ω, with u(x) = 0 as x ∈ Ω, where Ω ⊆ ℝN is a smooth bounded strictly star-shaped region related to the potential V. We prove the existence of an infinite number of solutions for both the original and the limit problem via a Ljusternik-Schnirelman scheme for even functionals. Fixed a topological level k we show that vk,𝜀, a solution of (P𝜀), subconverges, up to a scaling, to a corresponding solution of (Pinf ), and that vk,𝜀 exponentially decays out of Ω. Finally, uniform estimates on ∂Ω for scaled solutions of (P𝜀) are obtained.

Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media (CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.249-251
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    • 2014
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4//oxygen$ mixture using two-section porous media combustor. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. $H_2/CO$ ratio and module M from concentration of flue gas measured by Gas Chromatography was similar to those calculated by equilibrium. But it was made sure that the heat loss effect becomes more influential than heat recirculation effect as the mixture gets richer. To generate synthesis gas appropriate for methanol production, insulated pressurized porous media combustor will be designed and built in the future.

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Fabrication of LTCC Multi-layer Circuit Board made of Glass-Al2O3 Composites (Glass-Al2O3 복합소재를 원료로 한 LTCC 다층회로 기판의 제조)

  • Kwak, Hun;Jeon, Hyung-Do;Kim, Hwan;Lee, Won-Jae;Shin, Byoung-Chul;Kim, Il-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.509-516
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    • 2008
  • Multi-layer circuit card for semiconductor inspection was fabricated by LTCC technology. After a proper impedance design without electrical interference, ceramic tapes with the composition of $CaO-Al_2O_3-SiO_2-B_2O_3$ glass and $Al_2O_3$ were prepared. The electrode with silver paste printed on the tape. Printed ceramic sheets were then laminated and sintered. Densities and dielectric properties were measured. The microstructure, fracture surface of the region of via and matching state of substrate-electrode were observed. The durability of plated outside electrode were examined by hardness and scratch test.